The document investigates the effect of divergent exit curvature on the nozzle pressure ratio (NPR) of supersonic convergent-divergent nozzles using computational fluid dynamics (CFD). It presents a detailed analysis of shock wave behavior in these nozzles at varying pressure ratios, highlighting the challenges of flow separation and shock formation at NPR values above 1.63. The study aims to modify nozzle geometries to improve performance by reducing back pressure effects and enhancing NPR capabilities.