LEAN AMINE (Ucarsol HS 101)
Flammable Limits: LEL: UEL: Not available Not available
SECTION ONE: PRODUCT IDENTIFICATION
Product Identifier: Lean Amine (Ucarsol HS 101) Use: Sweetening of sour natural gas
WHMIS Classification:
WHMIS Class B: Division 2: Flammable Liquid Class D: Division 2: Subdivision A: Very Toxic Material Class E: Corrosive
TDG Identification:
TDG Shipping Name: TDG Class: TDG PIN: TDG PG: Flammable Liquids, n.o.s. (waste amine contaminated with petroleum hydrocarbons) 3 1993 II
Burlington Resources Canada Ltd.
2100, 250 - 6th Avenue S.W. Calgary, AB T2P 3H7
Emergency/Information Phone No.:
(403) 260-8000
Auto Ignition Temperature: Not available Extinguishing Media: Dry chemical, foam, CO2 using manufacturers recommended technique. Special Fire Fighting Procedures: Water may be ineffective at extinguishing fire, but should be used to keep fire exposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapours and to protect personnel attempting to stop a leak. Water spray may be used to flush spills from exposure. Use self-contained breathing apparatus (SCBA). Sensitivity to Mechanical Impact: Not sensitive Sensitivity to Static Discharge: Material may build up a static charge. Vapours may ignite if exposed to static discharge. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain CO, CO2, nitrogen oxides, and possibly SO2 and H2S. Flammable liquid/vapour may ignite explosively. Do not enter enclosed or confined spaces without proper protective equipment, including SCBA.
SECTION TWO: HAZARDOUS INGREDIENTS
Hazardous % Ingredients Volume Alkanol95-100 amines Hexanes Benzene Hydrogen Sulphide 0.5-5 0.1-1 <0.01 C.A.S. Number Not available 110-54-03 71-43-02 7783-06-04 LD50 of Ingredient Not available 28,710 mg/kg rat, oral 4,894 mg/kg rat, oral Not available LC50 of Ingredient Not available 35,00040,000 ppm, mouse 16,000 ppm rat, 4 hr 444 ppm rat, 4 hr
SECTION FIVE: REACTIVITY DATA
Stability: Unstable Stable X Incompatibility (materials to avoid): Strong oxidizers Hazardous Decomposition or By-Products: Burning may give off nitrogen oxides, smoke, carbon monoxide, carbon dioxide, and possibly hydrogen sulphide, sulphur dioxide and sulphur trioxide. Hazardous Polymerization: May Occur Will Not Occur X Conditions to Avoid: Sources of ignition
Formula: Mixture of alkanolamines with small amounts of petroleum hydrocarbons. Contains n-hexane, benzene and possibly small amounts of hydrogen sulphide due to contact with sour natural gas.
SECTION SIX: HEALTH HAZARD DATA
Route(s) of Entry: Skin Inhalation Contact Yes Yes Skin Absorption Yes
SECTION THREE: PHYSICAL/CHEMICAL DATA
Physical State: Liquid Freezing Point: -59oC Specific Gravity (H2O-1): Vapor Pressure (mm Hg): Boiling Point: 148oC pH: Not available 1.0 (approx.)
2.8 mm @ 20 C. (Dissolved H2S and hydrocarbons may cause higher vapour pressure than shown.)
o
Ingestion Yes
Eye Yes
Vapor Density (AIR=1): 3.2-4.0 at 20oC Varies with product composition Evaporation Rate: Solubility in Water: 95 to 100% Volatile, % by Volume: approx. 5% Coefficient of Water/Oil Distribution: Not available Rotten eggs/hydrocarbon odour Appearance and Odour:
SECTION FOUR:
FIRE AND EXPLOSION HAZARD DATA
Flash Point Closed Cup: May be below -40oC. (Depends on petroleum hydrocarbon content.)
Health Hazards (acute and chronic): Inhalation of high vapour concentrations may have results ranging from eye and respiratory irritation, dizziness, and headaches to unconsciousness, depending on concentrations and length of exposure. Liquid contact with skin may cause irritation and possible damage. Eye contact likely to cause severe pain and damage. May contain small amounts of hydrogen sulphide gas, which can build up in tank or vessel headspaces. Breathing may stop after a few seconds of exposure to hydrogen sulphide concentrations greater than 600 ppm, with immediate loss of consciousness and possible death. Residual effects after exposure to hydrogen sulphide can include shortness of breath and wheezing. Research on animals has shown effects on the respiratory, nervous and reproductive systems at concentrations above 10 [Link] benzene and nhexane. Benzene may cause leukemia and other blood diseases after prolonged or repeated exposures at high concentrations. Repeated exposure to high concentrations of n-hexane may cause nervous system damage, leading to loss of sensation and impaired movement in arms and legs. MATERIAL SAFETY DATA SHEET PAGE 1
BURLINGTON RESOURCES CANADA LTD.
LEAN AMINE (Ucarsol HS 101)
Carcinogenicity: National Testing IARC OSHA Substance Program Monographs Regulated Benzene Yes Yes Yes Sign and Symptoms of Exposure: Irritation to eyes, nose, throat, lungs or skin. Drowsiness, disorientation, headache and nausea may also occur. Hydrogen sulphide can cause pulmonary edema and respiratory paralysis at high concentrations. Medical Conditions Generally Aggravated by Exposure: Any condition causing impaired function of the respiratory, cardiovascular, or nervous systems.
TLVTWA ( ppm) 50 500 400 300 200 0.5 50 100 25 300 400 10 TLVSTEL ( ppm) 1000 500 375 2.5 150 15 TLV-C ( ppm) 8 Hr OEL ( ppm) 50 500 400 300 200 1 50 100 25 300 400 10 15 Min OEL ( ppm) 75 625 500 375 250 5 150 35 375 500 Ceiling OEL ( ppm) 15
Ingredients Alkanolamines n-Hexane Other Hexanes Heptanes Octanes Nonanes Benzene Toluene Xylene 1,2,4 Trimethyl Benzene Cyclohexane Methyl Cyclohexane Hydrogen Sulphide
impounding. Advise authorities if product has entered or may enter sewers, watercourses, or extensive land areas. Federal and provincial regulations must be followed. Waste Disposal Method: Recycle as much of the recoverable product as possible. Dispose of absorbed materials at an approved disposal site or facility. Assure conformity with applicable disposal regulations. Precautions to be Taken in Handling and Storing: Do not inhale vapour and avoid contact with skin. Observe precautions for volatile, flammable vapours from absorbed materials. Toxic quantities of gases and vapours may be present in storage tanks and vessels which contain or have contained the material. Persons opening or entering these compartments should first determine if H2S is present. Do not attempt to rescue without wearing SCBA. Other Precautions: Wash thoroughly after contact. Avoid ignition sources.
SECTION EIGHT: EMERGENCY AND FIRST AID PROCEDURES
Inhalation: In emergency situations, assess situation. Ensuring own safety use approved respiratory protection to remove the affected victim immediately from exposure. Administer artificial respiration or CPR as required. Keep at rest. Call for medical attention immediately. Skin Contact and Absorption: Wash with large amounts of water. Remove contaminated clothing. Get medical attention. Eyes: Flush with water for at least 20 minutes, lifting upper and lower eyelids at intervals. Get immediate medical attention. Ingestion: DO NOT induce vomiting. If conscious, give 1-2 glasses of milk or water to drink. (Note: Never give anything by mouth to a person who is unconscious or convulsing.) Notes to Physician: High aspiration risk. For large amounts, use careful gastric lavage. Eructation and gastroenteritis may be a complication. Aspiration may cause chemical pneumonitis or lipoid pneumonia.
SECTION SEVEN: PRECAUTIONS FOR SAFE HANDLING AND USE
Respiratory Protection (specify type): Determine the need for (and wear if necessary) respiratory protection where airborne exposures may exceed regulatory limits (for example, during amine filter changes, maintenance and other operations where significant airborne exposure to the amine/hydrocarbons can occur). Local Exhaust Ventilation: Provide where possible to capture vapours at source, minimize worker exposure and avoid accumulation of explosive vapours. Otherwise, provide effective general ventilation. Use explosion-proof motor and non-sparking fan in areas where explosive vapours may form. Special: No smoking, open lights or other ignition sources. Use non-sparking tools in areas where explosive vapours may form Protective Gloves: Use chemical resistant gloves to avoid skin contact (e.g. viton or butyl rubber preferable - neoprene suitable for light duty work). Eye Protection: Goggles and face shield if splashing is possible (unless full face piece respirator worn). Other Protective Clothing/Equipment: Use chemicalresistant apron or fire-retardant clothing as required by clothing policy. Work/Hygienic Practices: Keep containers closed when not in use. Wash before eating or drinking. Soiled clothing should be removed and laundered. Steps to be Taken in Case Material is Released or Spilled: Wear suitable respiratory and personal protection. Test area for H2S and combustible gas/vapour. Remove all ignition sources. Keep people away. Recover free liquid. Add absorbent (sand, earth, sawdust, etc.) to spill area. Minimize breathing vapours. Ventilate confined spaces. Open windows and doors. Keep out of sewers and watercourses by dyking or
SECTION NINE: PREPARATION INFORMATION
The information supplied on this Material Safety Data Sheet is supplied in accordance with the provisions of the Hazardous Products Act, Occupational Health and Safety Act, Controlled Products Regulations, and Occupational Health and Safety Regulations, and its dissemination and use is limited to persons protected thereunder. Burlington Resources Canada Ltd. and its affiliates assume no responsibility for any liability to persons not within the protection of the above named legislation. PREPARED BY: DATE REVISED: Burlington Resources Canada Ltd. EHS Department (403) 260-8000 2003 November 12
BURLINGTON RESOURCES CANADA LTD.
MATERIAL SAFETY DATA SHEET
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