Safety Data Sheet

Issue Date 14-Jan-2020 Revision Date 22-May-2019 Revision Number 7

1. IDENTIFICATION

Product identifier
Product Code N69FP-OOWHA
Product Name HB EPOXOLINE TNEMEC WHITE

Other means of identification

Common Name SERIES N69FN69F, PART A
UN/ID no. 1263
Synonyms None

Recommended use of the chemical and restrictions on use

Recommended Use industrial paint.
Uses advised against Consumer use, For professional use only. Not for residential use.

Details of the supplier of the safety data sheet

Manufacturer Address Distributor
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO Tnemec Company, Inc. 86 Boul, des Entreprises, Ste. 203,
64120-1372 816-474-3400 Boisbriand, Quebec Canada J7G 2T3
Emergency telephone number
Company Phone Number Tnemec Regulatory Dept: 816-474-3400
24 Hour Emergency Phone Number 800-535-5053 (lnfotrac)

2. HAZARDS IDENTIFICATION

Classification

OSHA Regulatory Status

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

!Acute toxicity - Oral Category 4

!Acute toxicity - Inhalation (Dusts/Mists) Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Skin sensitization Categorv 1
Carcinooenicitv Cateoory 2
Reproductive Toxicitv Category 18
Specific target organ toxicity (single exposure) Categorv 3
Specific target oroan toxicitv (repeated exposure) Category 1
Flammable Liquids Category 3

Label elements

EMERGENCY OVERVIEW
Danger

Hazard statements
Causes skin irritation
Causes serious eye damage
May cause an allergic skin reaction
May cause cancer
May damage fertility or the unborn child

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May cause respiratory irritation. May cause drowsiness or dizziness

Causes damage to organs through prolonged or repeated exposure
Flammable liquid and vapor

Ph sical state Ii uid Odor aromati

Precautionary Statements
Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Use only outdoors or in a well-ventilated area
Contaminated work clothing should not be allowed out of the workplace
Wear protective gloves
Do not breathe dust/fume/gas/mist/vapors/spray
Keep away from heaUsparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Keep cool
Use explosion-proof electrical/ventilatin()/liohting/P.f111irmfmt

Response
IF exposed or concerned : Get medical advice/attention
specific treatment
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor/physician
If skin irritation or rash occurs: Get medical advice/attention
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
In case of fire: Use C02 , dry chemical, or foam for extinction

Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Keep away from children

Disposal
Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Other information
Harmful to aquatic life with long lasting effects
SEE SAFETY DATA SHEET
Acute Toxicity 8.73700041 % of the mixture consists of ingredient(s) of unknown toxicity.

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3. COMPOSITION/IN FORMATION ON INGREDI ENTS

Chemical name CAS No. Weiaht-%

BARIUM SULFATE (TOTAL DUST) 7727-43-7 10 - <30%
TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 10 - <30%
TALC IRESPIRABLE DUST) 14807-96-6 10 - <30%
XYLENE 1330-20-7 1 - <10%
MODIFIED CYCLOALIPHATIC POLYAMINE 68953-36-6 1 - <10%
BENZYL ALCOHOL 100-51-6 1 - <10%
N-BUTANOL (SKIN) 71-36-3 1 - <10%
ETHYL BENZENE 100-41-4 1 - <10%
ISOPHORONE DIAMINE 2855-13-2 1 - <10%
MODIFIED ALIPHATIC AMINE 90-72-2 1 - <10%
AMORPHOUS SILICA 7631-86-9 1 - <10%
TETRAETHYLENEPENTAMINE 112-57-2 0.1 - <1%
P-P'-ISOPROPYLIDENEDIPHENOL 80-05-7 0.1 - <1%

*The exact percentage (concentration) of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

Description of first aid measures

General advice If symptoms persist, call a physician .

Eye contact Rinse thoroughly with plenty of water for at least 15 minutes.

Skin contact Wash off immediately with soap and plenty of water.

Inhalation Remove to fresh air. Oxygen or artificial respiration if needed.

Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.

Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing .

Most important symptoms and effects. both acute and delayed

Notes to physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Carbon dioxide. Foam. Dry chemical.

Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.

Specific hazards arising from the chemical

Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe
fumes

Hazardous combustion products Hazardous combustion products may include: A complex mixture of airborne solid and
liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic
compounds. Aldehydes. Carbon oxides. Hydrocarbons. Oxides of nitrogen.

Protective equipment and precautions for firefighters

Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from
heat/sparks/open flames/hot surfaces. MAY CAUSE HEAT AND PRESSURE BUILD-UP IN CLOSED CONTAINERS. Solvent
vapors are heavier than air and may spread along floors. Flash back possible over considerable distance.

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6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with eyes, skin and clothing. Use personal protective equipment. Remove all
sources of ignition.

Environmental Precautions

Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or
sanitary sewer system.

Methods and material for contain ment and cleaning up

Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for
proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate
ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer
absorbent material to suitable containers for proper disposal.

Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated
absorbent, container and unused contents in accordance with local, state and federal
regulations.

7. HANDLING AND STORAGE

Precautions for safe handling

Handling Close container after each use. Avoid contact with eyes, skin and clothing. Do not eat, drink
or smoke when using this product. If splashes are likely to occur, wear goggles. Wear
protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum. When
used in a mixture, read the labels and safety data sheets of all components. Wash
thoroughly after handling.

Conditions for safe storage, including any Incompatibilities

Storage Keep away from heat, sparks and flame. VAPORS MAY CAUSE FLASH FIRE. Use only in
an area containing flame proof equipment. Extinguish all flames and pilot lights, and turn off
stoves, heaters, electric motors and other sources of ignition during use and until all vapors
are gone. Prevent build-up of vapors by opening all windows and doors to achieve cross
ventilation.

Incompatible products Strong oxidizing agents. Acids . Bases. Cleaning solutions such as Chromerge and Aqua
Regia.

8. EXPOSURE CONTRO LS/PERSONAL PROTECTION

Control parameters

Exposure QUI·d ermes

Chemical name ACGIHTLV OSHA PEL NIOSH IOLH
BARIUM SULFATE (TOTAL DUST) TWA: 5 mglm' TWA: 10 mg/m3
7727-43-7 TWA: 5 mg/m 3
TWA: 15 mg/m 3

TITANIUM DIOXIDE (TOTAL TWA: 10 mg/m' TWA: 1O mg/m3 5000 mg/m 3

DUST) TWA: 15 mg/m 3
13463-67-7
TALC (RESPIRABLE DUST) TWA: 2 mg/m 3 TWA: 2 mg/m 3 1000 mg/m 3
14807-96-6
XYLENE TWA: 100 ppm TWA: 100 ppm
1330-20-7 STEL: 150 ppm TWA: 435 mg/m 3
STEL: 150 ppm
STEL: 655 mg/m3

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N-BUTANOL (SKIN) TWA: 20 ppm Skin 1400 ppm

71-36-3 Ceiling : 50 ppm
Ceiling : 150 mg/m3
TWA: 100 ppm
TWA: 300 mq/m3
ETHYL BENZENE TWA: 20 ppm TWA: 100 ppm 800 ppm
100-41 -4 TWA: 435 mg/m 3
STEL: 125 ppm
STEL: 545 mg/m3

AMORPHOUS SILICA - TWA: 6 mg/m 3 3000 mg/m 3

7631-86-9
Appropri ate engineering controls

Engineering measures Sufficient ventilation, in volume and pattern , should be provided through both local and
general exhaust to keep the air contaminant concentration below current applicable OSHA
Permissible Exposure Limits (PEL} and ACGIH"s Threshold Limit Values (TLV).
Appropriate ventilation should be employed to remove hazardous decomposition products
formed during welding or flame cutting operations of surfaces coated with this product.

Individual protection measures, such as personal protective equipment

Eye/face protection Goggles If splashes are likely to occur, wear face-shield.

Skin and body protection Wear protective clothing , including boots, gloves, lab coat, apron or coveralls, as
appropriate, to prevent skin contact.

Respiratory protection Use only with adequate ventilation . Do not breathe vapors, spray mist, or dust. Ensure fresh
air entry during application and drying. If you experience eye watering, headache or
dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable
limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and
after application. Follow respirator manufacturer's directions for respirator use.

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
Avoid breathing dust created by cutting, sanding, or grinding.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state liquid

Appearance opaque Odor aromatic
Color No information available Odor threshold No information available

Property Values Remarks

pH
Melting point I freezing point No data available
Boiling point I boiling range 116 °C I 241.0 °F
Flash point 26 °C I 78.0 °F Pensky Martens - Closed Cup
Evaporation rate
Flammability (solid, gas) No data available
Flammability Limit in Air
Upper flammability limit N/A
Lower flammability limit 1.0
Vapor pressure
Vapor density
Specific gravity 1.81486 g/cm3
Water solubility Insoluble in cold water
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature No data available

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Decomposition temperature No information available

Kinematic viscosity No information available
Dynamic viscosity 1100 centipoises approx

Other Information

Molecular weight No information available

Density 1o.1 ~o~3 lbs/gal
Volatile organic compounds (VOC) 2.50651 lbs/gal
content
Total volatiles weight percent 16.56 %
Total volatiles volume percent 35.02 %
Bulk density No information available

10. STABILITY AND REACTIVITY

Reactivity
No data available

Chemical stability
Stable under recommended storage conditions.

Possibility of hazardous reactions

None under normal processing .

Conditions to avoid
Heat, flames and sparks. Epoxy constituents.

Incompatible materials
Strong oxidizing agents, Acids, Bases, Cleaning solutions such as Chromerge and Aqua Regia

Hazardous de ~om osition roducts

Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke).
Carbon monoxide. Unidentified organic and inorganic compounds . Oxides of nitrogen. Aldehydes. Hydrocarbons. Carbon oxides.

11. TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure

Inhalation Vapors may irritate throat and respiratory system. May cause central nervous system
depression with nausea, headache, dizziness, vomiting , and incoordination.

Eye contact Causes serious eye damage.

Skin contact Irritating to skin. May cause sensitization by skin contact.

Ingestion Harmful if swallowed .

Chemical name LOSO Oral LOSO Dermal LCSO Inhalation

13ARIUM SULFATE (TOTAL DUST)
7727-43-7
= 307000 mg/kg ( Rat ) - -
rr1TANIUM DIOXIDE (TOTAL
DUST)
> 1DODO mg/kg ( Rat ) - -
13463-67-7
XYLENE = 3500 mg/kg ( Rat ) > 1700 mg/kg ( Rabbit ) > 4350 = 29 .08 mg/L (Rat) 4 h = 5000
1330-20-7 mo/ko ( Rabbit ) ppm (Rat) 4 h
BENZYL ALCOHOL = 1230 mg/kg ( Rat ) = 2 g/kg ( Rabbit ) = 8.8 mg/L ( Rat) 4 h
100-51-6
N-BUTANOL (SKIN) = 700 mg/kg ( Rat ) = 790 mg/kg ( = 3400 mg/kg ( Rabbit ) = 3402 > 8000 ppm ( Rat ) 4 h
71 -36-3 Rat) mo/ko ( Rabbit )
ETHYL BENZENE = 3500 mg/kg ( Rat ) = 15400 mg/kg ( Rabbit ) =17.4mg/L (Rat)4h
100-41-4

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ISOPHORONE DIAMINE = 1030 mg/kg (Rat) > 2000 mg/kg (Rat) -

2855-13-2
MODIFIED ALIPHATIC AMINE = 1200 mg/kg ( Rat ) = 1280 mg/kg ( Rat ) -
90-72-2
~MORPHOUS SILICA = 7900 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 2.2 mg/L ( Rat ) 1 h
7631-86-9
ITETRAETHYLENEPENTAMINE = 3990 mg/kg ( Rat ) = 660 µUkg ( Rabbit ) -
112-57-2
P-P'-ISOPROPYLIDENEDIPHENO = 3300 mg/kg ( Rat ) = 3 mUkg ( Rabbit ) > 170 mg/m 3 (Rat) 6 h
L
80-05-7

Information on toxicological effects

Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting .
Skin disorders. Irritating to eyes and skin.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Chronic Toxicity NOTICE: Reports have associated repeated and prolonged occupational overexposure to
solvents with permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents may be harmful or fatal. Skin sensitizer.
Substances known to be carcinogenic to man. Substances known to impair fertility.
Sensitization May cause sensitization of susceptible persons .
Mutagenicity No information available.
Carcinogentc
. . Itv Th e t a bl e beow
I . d"1cat es w heth ereac h aQency h as I'1st e d any in ~ re d'1en t as a carcin ogen.
in
Chemical name ACGIH IARC NTP OSHA
jTITANIUM DIOXIDE Group 28 - x
(TOTAL DUST)
13463-67-7
jfALC (RESPIRABLE DUST) Group 3 -
14807-96-6
XYLENE Group 3 -
1330-20-7
ETHYL BENZENE A3 Group 28 - x
100-41-4
AMORPHOUS SILICA Group 3 Known
7631-86-9
Reproductive effects May damage fertility or the unborn child.
STOT - single exposure Eyes, Central Nervous System (CNS), Skin
STOT- repeated exposure Causes damage to organs through prolonged or repeated exposure
Target organ effects blood, Central nervous system , Central Vascular System (CVS), Gastrointestinal tract,
Eyes, kidney, liver, Lungs, respiratory system, Skin.
Aspiration hazard No information available.

Acute Toxicity 8.73700041 % of the mixture consists of ingredient(s) of unknown toxicity.

12. ECOLOGICAL INFORMATION

Ecotoxicity

Harmful to aquatic life with long lasting effects

10.90523 % of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical name Toxicity to alaae Toxicitv to fish Toxicitv to daphnia
TALC (RESPIRABLE DUST) - 100: 96 h Brachydanio rerio g/L -
14807-96-6 LC50 semi-static
XYLENE - LC50= 13.4 mg/L Pimephales EC50 = 3.82 mg/L 48 h LC50 = 0.6
1330-20-7 promelas 96 h LC50 2.661 - 4.093 mg/L 48 h
mg/L Oncorhynchus mykiss 96 h
LC50 13.5 - 17.3 mg/L
Oncorhynchus mykiss 96 h LC50
13.1 - 16.5 mg/L Lepomis
macrochirus 96 h LC50= 19 mg/L
Lepomis macrochirus 96 h LC50

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7.711 - 9.591 mg/L Lepom is

macrochirus 96 h LC50 23.53 -
29.97 mg/L Pimephales promelas
96 h LC50= 780 mg/L Cyprinus
carpio 96 h LC50> 780 mg/L
Cyprinus carpio 96 h LC50 30.26 -
40.75 mg/L Poecilia reticulata 96 h
BENZYL ALCOHOL 35: 3 h Anabaena variabilis mg/L 460: 96 h Pimephales promelas 23: 48 h water flea mg/L EC50
100-51 -6 EC50 mg/L LC50 static 10: 96 h Lepomis
macrochirus mg/L LC50 static
N-BUTANOL (SKIN) 500: 72 h Desmodesmus 1740: 96 h Pimephales promolas 1983: 48 h Daphnia magna mg/L
71-36-3 subspicatus mg/L EC50 500 : 96 h mg/L LC50 flow-through 1730 - EC50 1897 - 2072: 48 h Daphnia
Desmodesmus subspicatus mg/L 1910: 96 h Pimephales promelas magna mg/L EC50 Static
EC50 mg/L LC50 static 1910000: 96 h
Pimephales promelas µg/L LC50
static 100000 - 500000: 96 h
Lepomis macrochirus µg/L LC50
static
ETHYL BENZENE 2.6 - 11 .3: 72 h Pseudokirchneriella 11.0 - 18.0: 96 h Oncorhynchus 1.8 - 2.4: 48 h Daphnia magna mg/L
100-41-4 subcapitata mg/L EC50 static 4.6: mykiss mg/L LC50 static 4.2: 96 h EC50
72 h Pseudokirchneriella Oncorhynchus mykiss mg/L LC50
subcapitata mg/L EC50 1.7 - 7.6: 96 semi-static 7.55-11 : 96 h
h Pseudokirchneriella subcapitata Pimephales promelas mg/L LC50
mg/L EC50 static 438: 96 h flow-through 9.1 - 15.6: 96 h
Pseudokirchneriella subcapitata Pimephales promelas mg/L LC50
mg/L EC50 static 9.6: 96 h Poecilia reticulata
mg/L LC50 static 32 : 96 h Lepomis
macrochirus mg/L LC50 static
ISOPHORONE DIAMINE 37 : 72 h Desmodesmus subspicatus 110: 96 h Leuciscus idus mg/L 42: 24 h Daphnia magna mg/L
2855-13-2 mg/L EC50 LC50 semi-static EC50 14.6 - 21 .5: 48 h Daphnia
maana mg/L EC50 semi-static
AMORPHOUS SILICA 440: 72 h Pseudokirchneriella 5000 : 96 h Brachydanio rerio mg/L 7600: 48 h Ceriodaphnia dubia
7631-86-9 subcapitata mg/L EC50 LC50 static mo/L EC50
TETRAETHYLENEPENTAMINE 2.1: 72 h Pseudokirchneriella 420: 96 h Poecilia reticulata mg/L 24.1: 48 h Daphnia magna mg/L
112-57-2 subcapitata mg/L EC50 LC50 static EC50
P-P'-ISOPROPYLIDENEDIPHENO 2.5: 96 h Pseudokirchneriella 4.0 - 5.5: 96 h Pimephales promelas 3.9: 48 h Daphnia magna mg/L
L subcapitata mg/L EC50 mg/L LC50 static 3.6 - 5.4: 96 h EC50 10 2: 48 h Daphnia magna
80-05-7 Pimephales promelas mg/L LC50 mg/L EC50 9.2 - 11.4: 48 h Daphnia
flow-through 4: 96 h Oncorhynchus magna mg/L EC50 Static
mykiss mg/L LC50 9.9: 96 h
Brachvdanio rerio mo/L LC50 static

Persistence and degradability

No information available.

Bioaccumulation
No information available.

11tv i n Env ronmenta IMe d.1a

Mo bT
Chemical name loo Pow
XYLENE 2.77
1330-20-7
BENZYL ALCOHOL 1.1
100-51-6
N-BUTANOL (SKIN) 0.785
71-36-3
ETHYL BENZENE 3.118
100-41-4
ISOPHORONE DIAMINE 0.79
2855-13-2
MODIFIED ALIPHATIC AMINE 0.219
90-72-2
TETRAETHYLENEPENTAMINE .99
112-57-2
P-P'-ISOPROPYLIDENEDIPHENOL 2.2
80-05-7

Other Adverse Effects No information available

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13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, conta iner and unused contents in
accordance with local, state and federal regulations .

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or
disposal.

US EPA Waste Number

Chemical name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
XYLENE Included in waste stream: U239
1330-20-7 F039
N-BUTANOL (SKIN) Included in waste stream: U031
71-36-3 F039
ETHYL BENZENE Included in waste stream:
100-41-4 F039
FORMALDEHYDE U122 Included in waste streams : U122
50-00-0 K009, K010, K038,K040,
K156. K157

California Hazardous Waste Status

Chemical name CAWAST

XYLENE Toxic
1330-20-7 l~initable
N-BUTANOL (SKIN) Toxic
71 -36-3
ETHYL BENZENE Toxic
100-41-4 lonitable

14. TRANSPORT INFORMATION

DOT
UN/ID no. 1263
Proper Shipping Name PAINT
Hazard Class 3
Packing Group Ill
Emergency Response Guide 128
Number

Additional information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes
of Transportation .

15. REGULATORY INFORMATION

International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Does Not Comply
IECSC Complies
KECL Does Not Comply
PICCS Does Not Comply
AICS Complies

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TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSUNDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Cxisting and [valuated Chcmicol Subi;tonoc~
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

The following chemical{s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61 ):
Chemical name HAPS Data
XYLENE
ETHYL BENZENE

SARA 313
Section 313 of Title 111 of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part
372:
Chemical name SARA 313 - Threshold Values
BARIUM SULFATE (TOTAL DUST) - 7727-43-7 1.0
XYLENE - 1330-20-7 1.0
N-BUTANOL (SKIN) - 71-36-3 1.0
ETH YL BENZENE - 100-41-4 0.1
P-P'-ISOPROPYLIDENEDIPHENOL - 80-05-7 1.0

SARA 311/312 Hazardous

Categorization
Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No

Clean Water Act

Chemical name CWA - Reportable CWA - Toxic Pollutants CWA- Priority Pollutants CWA - Hazardous
Quantities Substances
XYLENE 100 lb x
1330-20-7
ETHYL BENZENE 1000 lb x x x
100-41-4

CERCLA

Chemical name Hazardous Substances RQs CERCLA EHS RQs RQ

XYLENE 1001b RQ 100 lb final RQ
1330-20-7 RQ 45.4 kg final RQ
N-BUTANOL (SKIN) 5000 lb RO 5000 lb final RO
71-36-3 RQ 2270 kg final RQ
ETHYL BENZENE 10001b RQ 1000 lb final RO
100-41-4 RQ 454 kg final RQ

California Prop. 65

WARNING: This product can expose you to the following chemicals which are known to the State of California to cause cancer.
in orma fion go to www.P65Warnings.ca.gov.
For more "f .
Chemical name California Prop. 65
TITANIUM DIOXIDE (TOTAL DUST) - 13463-67-7 Carcinoaen
ETHYL BENZENE - 100-41 -4 Carcinogen
AMORPHOUS SILICA - 7631-86-9 Carcinooen
P-P'-ISOPROPYLIDENEDIPHENOL - 80-05-7 Female Reproductive
FORMALDEHYDE - 50-00-0 Carcinogen
CRYSTALLINE SILICA (QUARTZ) - 14808-60-7 Carcinogen

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California SCAQMD Rule 443

Contains Photochemically Reactive Solvent

State Right-to-Know

Chemical name NewJersev Massachusetts Pennsylvania

BARIUM SULFATE (TOTAL DUST) x x x
7727-43-7
TITANIUM DIOXIDE (TOTAL x x x
DUST)
13463-67-7
TALC (RESPIRABLE DUST) x x x
14807-96-6
XYLENE x x x
1330-20-7
BENZYL ALCOHOL x x
100-51-6
N-BUTANOL (SKIN) x x x
71-36-3
ETHYL BENZENE x x x
100-41-4
ISOPHORONE DIAMINE x
2855-13-2
AMORPHOUS SILICA x x
7631-86-9
TETRAETHYLENEPENTAMINE x x x
112-57-2
P-P'-ISOPROPYLIDENEDIPHENO x x x
L
80-05-7

16. OTHER INFORMATION

NFPA Health 2 Flammability 3 Instability 1 Physical hazard •

HMIS (Hazardous Health 2* Flammability 3 Reactivity 1
Material Information
System)

Prepared By Tnemec Regulatory Dept: 816-474-3400

Revision Date 22-May-2019
Revision Summary
141151113
Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the Information contained herein is accurate. However, neit her the Tnemec Company or
any of Its subsidiaries assume any liability wh atsoever for the accuracy of completeness of the informat ion contained
herein. Flnal determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards which exist.

En d of SOS

Page 11/11
 Safety Data Sheet

Issue Date 24-Jul-2015 Revision Date 24-Jul-2015 Revision Number 7

1. IDENTIFICATION

Product identifier
Product Code 1074P-35GRA
Product Name ENDURA-SHIELD II BLACK

Other means of identification

Common Name SERIES 1074, PART A
UN/ID no. 1263

Recommended use of the chemical and restrictions on use

Recommended Use industrial paint.
Uses advised against Consumer use, For professional use only. Not for residential use.

Details of the supplier of the safety data sheet

Manufacturer Address Distributor
Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO Tnemec Company, Inc. 86 Boul, des Entreprises, Ste. 203
64120-1372 Boisbriand, Quebec Canada J7G 2T3

Emergency telephone number

Company Phone Number Tnemec Regulatory Dept: 816-474-3400
24 Hour Emergency Phone Number 800-535-5053 (lnfotrac)

2, HAZARDS IDENTIFICATION

Classification

OSHA Regulatory Status

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Acute toxicity - Oral Category 4

!Acute toxicity - Dermal Category 4
Acute toxicity - Inhalation (Vapors) Category 4
Serious eye damage/eye irritation Category 2A
Germ cell mutagenicity Category 18
Carcinogenicity Category 1A
Specific taraet organ toxicity (single exposure) Category 3
Specific target organ toxicity (repeated exposure) Category 1
Flammable Liquids Category 3

Label elements

EMERGENCY OVERVIEW
!Danger

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1074P-35GRA ENDURA-SHIELD II BLACK Revision Date 24-Jul-2015

Hazard statements
Harmful if swallowed
Harmful in contact with skin
Harmful if inhaled
Causes serious eye irritation
May cause genetic defects
May cause cancer
May cause respiratory irritation . May cause drowsiness or dizziness
Causes damage to organs through prolonged or repeated exposure
Flammable liquid and vapor

ppearance o aque Physical state liquid Odor aromati

Precautionary Statements
Prevention
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Use only outdoors or in a well-ventilated area
Do not breathe dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/mixing/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Keep cool

Response
IF exposed or concerned: Get medical advice/attention
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Call a POISON CENTER or doctor/physician if you feel unwell
Wash contaminated clothing before reuse
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
In case of fire: Use C02, dry chemical, or foam for extinction

Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Keep away from children

Disposal
Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classifi ed (HNOCl

Other information

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1074P-35GRA ENDURA-SHIELD II BLACK Revision Date 24-Jul-2015

Cancer hazard. Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure).
Respirable crystalline silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs
SEE SAFETY DATA SHEET
Acute Toxicity 71 .77048 % of the mixture consists of ingredient(s) of unknown toxicity .

3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No Wei aht-%

TITANIUM DIOXIDE {TOTAL DUST} 13463-67-7 10- 30%
PROPYLENE GLYCOL MONOMETHYL ETHER 108-65-6 10 - 30%
ACETATE
N-BUTYL ACETATE 123-86-4 10- 30%
CRYSTALLINE SILICA (QUARTZ) 14808-60-7 1 -10%
METHYL N-AMYL KETONE 110-43-0 1 -10%
TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 1 -10%
IRON OXIDE FUME 1309-37-1 1 -10%
MINERAL SPIRITS (STODDARD SOL VENT} 8052-41-3 1 -10%
PROPRIETARY BL038 1 -10%
PROPYLENE GLYCOL MONOMETHYL ETHER 108-65-6 1 -10%
ACETATE
PROPRIETARY - 1 -10%
CARBON BLACK DUST & FUME 1333-86-4 1 -10%
AMORPHOUS SILICA 7631-86-9 1 -10%
PROPYLENE GLYCOL MO 108-65-6 1 -10%
PETROLEUM DISTILLATES, 64742-80-9 0.1 - 1%
HYDROSULFURIZED MIDDLE
ETHYL BENZENE 100-41-4 0.1 -1%

*The exact percentage (concentration) of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

Description of first aid measures

General advice If symptoms persist, call a physician.

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If
symptoms persist, call a physician.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. If symptoms persist, call a physician.

Inhalation If inhaled, remove to fresh air. If not breathing , give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention immediately.

Ingestion If swallowed, do not induce vomiting. Get medical attention immediately.

Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing.

Most important symptoms and effects, both acute and delayed

Notes to physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Carbon dioxide. Foam . Dry chemical.

Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire .

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1074P-35GRA ENDURA-SHIELD II BLACK Revision Date 24-Jul-2015

Specific hazards arising from the chemical

Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe
fumes

Hazardous combustion products Hazardous combustion products may include: A complex mixture of airborne solid and
liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic
compounds. Carbon oxides. Hydrocarbons. Oxides of nitrogen.

Protective equipment and precautions for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions. protective equipment and emergency procedures

Personal precautions Use personal protective equipment. Avoid contact with eyes, skin and clothing. Remove all
sources of ignition. Ensure adequate ventilation.

Environmental Precautions

Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or
sanitary sewer system.

Methods and material for containment and cleaning up

Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for
proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate
ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer
absorbent material to suitable containers for proper disposal.

Methods for cleaning up Pick up and transfer to properly labelled containers.

7. HANDLING AND STORAGE

Precautions for safe handling

Handling Wear personal protective equipment. Avoid contact with eyes, skin and clothing. Handle in
accordance with good industrial hygiene and safety practice. Remove and wash
contaminated clothing before re-use. Keep away from open flames, hot surfaces and
sources of ignition. Do not breathe vapours or spray mist. Take necessary action to avoid
static electricity discharge {which might cause ignition of organic vapours). Do not ingest.
Ensure adequate ventilation. Do not eat, drink or smoke when using this product. Wash
thoroughly after handling.

Conditions for safe storage, Including any incompatibilities

Storage Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of
children .

Incompatible products Strong oxidizing agents. Water, alcohols, amines, strong bases, metal components, surface
active materials. caustic. Bases. Alkalis.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Ex
ACGIH TLV OSHA PEL NIOSH IDLH

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1074P-35GRA ENDURA-SHIELD II BLACK Revision Date 24-Jul-2015

TITANIUM DIOXIDE (TOTAL TWA: 1O mg/m3 TWA: 1O mg/m3 5000 mg/m 3

DUST) TWA: 15 mg/m3
13463-67-7
N-BUTYL ACETATE TWA: 150 ppm TWA: 150 ppm 1700 ppm
123-86-4 STEL: 200 ppm TWA: 710 mg/m3
STEL: 200 ppm
STEL: 950 mg/m3

CRYSTALLINE SILICA (QUARTZ) TWA: 0.025 mg/m3 TWA: 0.1 mg/mJ 50 mg/m 3
14808-60-7
METHYL N-AMYL KETONE TWA: 50 ppm TWA: 100 ppm 800 ppm
110-43-0 TWA: 465 mg/m3

TITANIUM DIOXIDE (TOTAL TWA: 10 mg/m 3 TWA: 1O mg/m3 5000 mg/m 3

DUST) TWA: 15 mg/m3
13463-67-7
IRON OXIDE FUME TWA: 5 mg/m 3 TWA: 1O mg/m3 2500 mg/m 3
1309-37-1 TWA: 5 mg/m 3

TWA: 15 mg/m 3

MINERAL SPIRITS (STODDARD TWA: 100 ppm TWA: 100 ppm 20000 mg/mJ
SOLVENT) TWA: 525 mg/mJ
8052-41-3 TWA: 500 ppm
TWA: 2900 mg/m3
CARBON BLACK DUST & FUME TWA: 3 mg/m 3 TWA: 3.5 mg/m 3 1750 mg/m 3
1333-86-4
AMORPHOUS SILICA - TWA: 6 mg/m 3 3000 mg/m 3
7631-86-9
ETHYL BENZENE TWA: 20 ppm TWA: 100 ppm 800 ppm
100-41-4 TWA: 435 mg/m3
STEL: 125 ppm
STEL: 545 mg/m 3

A ppropriate engi neering controls

Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and
general exhaust to keep the air contaminant concentration below current applicable OSHA
Permissible Exposure Limits (PEL) and ACGIH"s Threshold Limit Values (TLV).
Appropriate ventilation should be employed to remove hazardous decomposition products
formed during welding or flame cutting operations of surfaces coated with this product.

Individual protection measures, such as personal protective equipment

Eye/face protection Use chemical resistant splash type goggles.

Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls,
as appropriate, to prevent skin contact.

Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn . Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations. Respirable crystalline silica (quartz)
can cause silicosis, a fibrosis (scarring) of the lungs.

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
Avoid breathing dust created by cutting, sanding, or grinding.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic phys ical and chemical properties

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1074P-35GRA ENDURA-SHIELD II BLACK Revision Date 24-Jul-2015

Physical state liquid

Appearance opaque Odor aromatic
Color No information available Odor threshold No information available

Property Values Remarks

pH No data available
Melting point I freezing point No data available
Boiling point I boiling range 118 °C I 244.0 °F
Flash point 37 °C I 98.0 °F Pensky Martens - Closed Cup
Evaporation rate No data available
Flammability (solid, gas) Not applicable
Flammability Limit in Air No data available
Upper flammability limit N/A
Lower flammability limit 1.1
Vapor pressure No data available
Vapor density No data available
Specific gravity 1.35387 g/cm3
Water solubility Insoluble in cold water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition temperature No data available
Decomposition temperature No data available
Kinematic viscosity No data available
Dynamic viscosity 700 centipoises approx

Other Information

Density 11 .26620 lbs/gal

Volatile organic compounds (VOC) 2.688 lbs/gal
content
Total volatiles weight percent 23.8580 %
Total volatiles volume percent 37.2873 %

10. STABILITY AND REACTIVITY

Reactivity
No data available

Chemical stability
Stable under recommended storage conditions.

Possibility of hazardous reactions

None under normal processing .

Conditions to avoid
Heat, flames and sparks. Reacts with air to form peroxides.

Incompatible materials
Strong oxidizing agents, Water, alcohols, amines, strong bases, metal components, surface active materials, caustic, Bases,
Alkalis

Hazardous decomposition products

Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke).
Carbon monoxide. Unidentified organic and inorganic compounds. Oxides of nitrogen. Carbon oxides. Hydrocarbons.

11. TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure

Inhalation May cause central nervous system depression with nausea, headache, dizziness, vomiting,
and incoordination. IRRITATING TO RESPIRATORY SYSTEM. Respirable crystalline silica
(quartz) can cause silicosis, a fibrosis (scarring) of the lungs.

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1074P-35GRA ENDURA-SHIELD II BLACK Revision Date 24-Jul-2015

Eye contact Severely irritating to eyes.

Skin contact Irritating to skin.

Ingestion Harmful if swallowed.

Component LD50 Oral LD50 Dermal LC50 Inhalation

TITANIUM DIOXIDE (TOTAL > 10000 mg/kg ( Rat )
DUST)
13463-67-7
PROPYLENE GLYCOL = 8532 mg/kg ( Rat ) > 5 g/kg ( Rabbit )
MONOMETHYL ETHER ACETATE
108-65-6
N-BUTYL ACETATE = 10768 mg/kg (Rat)= 14.13 > 17600 mg/kg (Rabbit ) = 390 ppm ( Rat ) 4 h
123-86-4 mg/kg (Rat)
CRYSTALLINE SILICA (QUARTZ) = 500 mg/kg ( Rat )
14808-60-7
METHYL N-AMYL KETONE = 1600 mg/kg ( Rat ) = 1670 mg/kg = 12.6 ml/kg (Rabbit)= 12600 > 2000 ppm ( Rat ) 4 h
110-43-0 (Rat) µL/kg ( Rabbit )
TITANIUM DIOXIDE (TOTAL > 10000 mg/kg ( Rat )
DUST)
13463-67-7
IRON OXIDE FUME > 10000 mg/kg ( Rat )
1309-37-1
PROPYLENE GLYCOL = 8532 mg/kg ( Rat ) > 5 g/kg ( Rabbit )
MONOMETHYL ETHER ACETATE
108-65-6
CARBON BLA.CK DUST & FUME > 15400 mg/kg ( Rat ) > 3 g/kg ( Rabbit )
1333-86-4
AMORPHOUS SILICA > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 2.2 mg/L ( Rat ) 1 h
7631-86-9
PROPYLENE GLYCOL MO = 8532 mg/kg ( Rat ) > 5 g/kg ( Rabbit )
108-65-6
PETROLEUM DISTILLA.TES, > 5000 mg/kg (Rat) > 2000 mg/kg ( Rabbit ) = 4600 mg/m 3 ( Rat ) 4 h
HYDROSULFURIZED MIDDLE
64742-80-9
ETHYL BENZENE = 3500 mg/kg (Rat) = 15400 mg/kg ( Rabbit ) =17.2mg/L (Rat)4h
100-41-4

Information on toxicological effects

Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting .
Irritating to eyes and skin.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Chronic Toxicity Avoid repeated exposure. Substances known to be mutagenic to man. Cancer hazard.
Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration
and level of exposure).
Sensitization No information available.
Mutagenicity May cause genetic defects.
carcinoaenrc1
. . 'ttv . d.1cates wheth ereac h aaencv has r1se
Th e t abl e beowm
I t d anv me re d'1ent as a carcmoQen.
Component ACGIH IARC NTP OSHA
!TITANIUM DIOXIDE Group 28 x
(TOTAL DUST)
13463-67-7
CRYSTALLINE SILICA A2 Group 1 Known x
(QUARTZ)
14808-60-7
rnTANIUM DIOXIDE Group 2B x
(TOTAL DUST)
13463-67-7
IRON OXIDE FUME Group 3
1309-37-1

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1074P-35GRA ENDURA-SHIELD II BLACK Revision Date 24-Jul-2015

CARBON BLACK DUST & A3 Group 2B x

FUME
1333-86-4
~MORPHOUS SILICA Group 3
7631-86-9
ETHYL BENZENE A3 Group 2B x
100-41 -4
Reproductive effects No 1nformatron ovmlablo .
STOT - single exposure Central Nervous System (CNS), Eyes
STOT - repeated exposure Causes damage to organs throu~h prolonged or repeated exposure
Target organ effects Central nervous system, Eyes, Peripheral Nervous System (PNS), respiratory system , Skin.
Aspiration hazard No information available.

Acute Toxicity 71.77048 % of the mixture consists of ingredient(s) of unknown toxicity.

12. ECOLOGICAL INFORMATION

Ecotoxicity

Component Toxicity to algae Toxicity to fish Toxicity to daphnia

PROPYLENE GLYCOL 161: 96 h Pimephales promelas 500: 48 h Daphnia magna mg/L
MONOMETHYL ETHER ACETATE mg/L LC50 static EC50
108-65-6
N-BUTYL ACETATE 674.7: 72 h Desmodesmus 62: 96 h Leuciscus ictus mg/L LC50 72 .8: 24 h Daphnia magna mg/L
123-86-4 subspicatus mg/L EC50 static 100: 96 h Lepomis EC50
macrochirus mg/L LC50 static 17 -
19: 96 h Pimephales promelas mg/L
LC50 flow-through
METHYL N-AMYL KETONE 126 - 137: 96 h Pimephales
110-43-0 promelas mg/L LC50 flow-through
PROPYLENE GLYCOL 161: 96 h Pimephales promelas 500: 48 h Daphnia magna mg/L
MUNOMI:: I HYL I: IHl::KAGETATE 111y/L LCGO static EC50
108-65-6
CARBON BLACK DUST & FUME 5600: 24 h Daphnia magna mg/L
1333-86-4 EC50
AMORPHOUS SILICA 440: 72 h Pseudokirchnerlella 5000: 96 h Brachydaniu •~ r io rng/L 7600: 48 h Ceriodaphnia dubia
7631-86-9 subcapitata mg/L EC50 LC50 static mg/L EC50
PROPYLENE GLYCOL MO 161: 96 h Pimephales promelas 500: 48 h Daphnia magna mg/L
108-65-6 mg/L LC50 static EC50
PETROLEUM DISTILLATES, 35: 96 h Pimephales promelas mg/L
HYDROSULFURIZED MIDDLE LC50 flow-through
64742-80-9
ETHYL BENZENE 4.6: 72 h Pseudokirchneriella 11 .0 - 18.0: 96 h Oncorhynchus 1.8 - 2.4: 48 h Daphnia magna mg/L
100-41-4 subcapitata mg/L EC50 438: 96 h mykiss mg/L LC50 static 32 : 96 h EC50
Pseudokirchneriella subcapitata Lepomis macrochirus mg/L LC50
mg/L EC50 2.6 - 11.3: 72 h static 4.2: 96 h Oncorhynchus
Pseudokirchneriella subcapitata mykiss mg/L LC50 semi-static 7 .55 -
mg/L EC50 static 1.7 - 7.6: 96 h 11 : 96 h Pimephales pro me las mg/L
Pseudokirchneriella subcapitata LC50 flow-through 9.6: 96 h Poecilia
mg/L EC50 static reticulata mg/L LC50 static 9.1 -
15.6: 96 h Pimephales promelas
mg/L LC50 static

Persistence and degradablllty

No information available.

Bioaccumulation
No information available.

Mobility in Environmental Media

Component log Pow

PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE 0.43
108-65-6
N-BUTYL ACETATE 1.81
123-86-4

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METHYL N-AMYL KETONE 1.98

110-43-0
PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE 0.43
108-65-6
PROPYLENE GLYCOL MO 0.43
108-65-6
ETHYL BENZENE 3.118
100-41 -4

Other Adverse Effects No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal Methods It must undergo special treatment, e.g. at suitable disposal site, to comply with local
regulations.

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or
disposal.

Component RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes
ETHYL BENZENE Included in waste stream :
100-41-4 F039

Component CA WAST
N-BUTYL ACETATE Toxic
123-86-4
ETHYL BENZENE Toxic
100-41-4 Ignitable

14. TRANSPORT INFORMATION

DOT
UN/ID no. 1263
Proper Shipping Name paint
Hazard Class 3
Packing Group Ill
Emergency Response Guide 128
Number

IATA
. UN/ID no. 1263
Proper Shipping Name paint
Hazard Class 3
Packing Group Ill
ERG Code 366

Additional information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes
of Transportation .

15. REGULATORY JNFORMATION

International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Does not comply
ENCS Does not comply
IECSC Complies
KECL Does not comply
PICCS Does not comply

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1074P-35GRA ENDURA-SHIELD II BLACK Revision Date 24-Jul-2015

AICS Does not comply

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
11::csc - China Inventory of Existing Che111i1;al Suu~la11ce&
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

Component HAPS Data

ETHYL BENZENE

United States of America

SARA 313
Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 {SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part
372:
Com onent SARA 313 -Threshold Values
ETHYL BENZENE -100-41-4 0.1

SARA 311/312 Hazardous

Categorization
Acute Health Hazard Yes
Chronic Health Hazard Yes
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No

Component CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
N-BUTYL ACETATE 50001b x
123-86-4
ETHYL BENZENE 1000 lb x x x
100-41-4

CERCLA

Component Hazardous Substances RQs CERCLA EHS RQs RQ

N-BUTYL ACETATE 50001b RQ 5000 lb final RQ
123-86-4 RQ 2270 kg final RQ
ETHYL BENZENE 1000 lb RQ 1000 lb final RQ
100-41-4 RQ 454 kg final RQ

United States of America

California Prop. 65
W AR NING IThis product contains a c hem1cal known in the State of california to cause cancer
Component California Prop. 65
TITANIUM DIOXIDE {TOTAL DUSl) - 13463-67-7 Carcinogen
CRYSTALLINE SILICA (QUARTZ) - 14808-60-7 Carcinogen
TITANIUM DIOXIDE (TOTAL DUST) - 13463-67-7 Carcinogen
CARBON BLACK DUST & FUME - 1333-86-4 Carcinogen
ETHYL BENZENE - 100-41-4 Carcinogen

California SCAQMD Rule 443

Contains Photochemically Reactive Solvent

State Right-to-Know

Component New Jersey Massachusetts Pennsylvania

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1074P-35GRA ENDURA-SHIELD II BLACK Revision Date 24-Jul-2015

TITANIUM DIOXIDE (TOTAL x x x

DUST)
13463-67-7
N-BUTYL ACETATE x x x
123-86-4
CRYSTALLINE SILICA (QUARTZ) x x x
14808-60-7
METHYL N-AMYL KETONE x x x
110-43-0
TITANIUM DIOXIDE (TOTAL x x x
DUST)
13463-67-7
IRON OXIDE FUME x x x
1309-37-1
MINERAL SPIRITS (STODDARD x x x
SOLVENT)
8052-41-3
CARBON BLACK DUST & FUME x x x
1333-86-4
AMORPHOUS SILICA x x x
7631-86-9
ETHYL BENZENE x x x
100-41-4

16. OTHER INFORMATION

NFPA Health 2 Flammability 3 Instability 1 Physical hazard *
HMIS (Hazardous Health 2* Flammability 3 Reactivity 1
Material Information
System)

Prepared By Tnemec Regulatory Dept: 816-474-3400

Revision Date 24-Jul-2015
Revision Summary
156710891114"15
Disclaimer
For specific information regarding occupational safety and health standards, please refer to the Code of Federal
Regulations, Title 29, Part 1910.
To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or
any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained
herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards which exist.

End of MSDS

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