IUPAC & NOMENCLATURE

BY VINEET KHATRI SIR

CLASS-XI TIME : 35 MIN. DPP. NO.1

Single Choice Questions :

1. Which of following is 3° (tertiary alcohol)

OH OH OH
(A) (B) (C) (D) All

IR
2. Which of following is 1° amine ?

NH2 CH3

IS
(A) (B) CH3 – C – NH2 (C) CH3 – NH2 (D) All
CH3

R
3. Which of following is 3° amine ?

CH3
(A) CH – N
3
(B) CH3 – NH – Et
AT (C) CH3 – NH – CH3 (D) CH3 – NH2

CH3
H
4. and
K

Number of secondary carbon atoms present in the above compounds are respectively:
(A) 6, 4, 5 (B) 4, 5, 6 (C) 5, 4, 6 (D) 6, 2, 1
T

5. Number of 1°, 2° and 3° hydrogen in isooctane is:

EE

(A) 9,8,1 (B) 12,5,1 (C) 15,2,1 (D) None of these

Multiple Choice Question :

6. Which of the following compound contain only 1 type of carbon atom

N
VI

(A) (B) (C) (D)

7. Which of the following compound contain only 2 types of carbon atom

N N

(A) (B) N N (C) (D)

N N
8. Classify the following alcohols as primary, secondary, or tertiary:
(a) (CH3)3CCH2OH (b) CH3CH(OH)CH(CH3)2

(c) (CH3)2C(OH)CH2CH3 (d)

(e)

9. Classify the following amines as primary, secondary, or tertiary:

(a) CH3NHCH(CH3)2 (b) CH3CH2CH(CH3)CH2NH2
(c) (CH3CH2)3N (d) (C6H5)2CHCH2NHCH3

IR
(e) (f)

IS
“A positive attitude brings much gratitude! Think positive,

R
be positive, speak positive and stay positive!
AT
Do it every day and DO IT BIG!!!”
H
K
T
EE
N
VI
 IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.2

O
CH3
CH–2 CH=CH – C – Cl

1. N
O
CH–2 CH3

IR
(a) Find out the total number of 1° hydrogen. (b) Find out the total number of 2° hydrogen.
(c) Find out the total number of 3° hydrogen. (d) Find out the total number of 1° carbon.
(e) Find out the total number of 2° carbon. (f) Find out the total number of 3° carbon.

IS
(g) Find out the total number of 4° carbon.
(h) Find out the total number of functional groups.
(i) Find out the number of degree of unsaturation.

R
OH
H
2.
OO AT
NH2 NH2
NH
O
H
(a) Find out the total number of 1° hydrogen. (b) Find out the total number of 2° hydrogen.
K

(c) Find out the total number of 3° hydrogen. (d) Find out the total number of 1° carbon.
(e) Find out the total number of 2° carbon. (f) Find out the total number of 3° carbon.
(g) Find out the total number of 4° carbon. (h) Find out the total number of functional groups.
T

(i) Find out the number of degree of unsaturation.

EE

3.
I IV
II III
N

Find out the number of 1°, 2° & 3° carbon atoms in the above compounds.
VI

4. Match the column :

Column I Column II
CH3
(A) CH3—CH2—N (P) 1° Carbon
H
(B) CH2 = CH – CH3 (Q) 2° Carbon

(C) (R) 3° Carbon

OH
(D) (S) 4° Carbon

“Follow your dreams; they will give meaning to every step that you take.”
 IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.3

Calculate DBE value -

–
COO

1. 2. 3.

IR
COOH
H OH
4. 5. 6. H OH

IS
COOH

R
O
||
7.
||
NH 8. AT 9.

O
H
10. 11. .. 12.
N
K

H
T

CN
CH3
EE

H Br
13. 14. 15.
H Br
|| CH3
O
N

O O
VI

OH
16. 17. 18.

19. 20. 21. C9H16 NOCl

COOH
COOH

“Set your goals where the sky is the beginning and if

you land anywhere in between, you are doing Great”
 IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.4

Calculate DBE value -

1. 2. N 3. HCOO

IR
H2C
H3C

IS
4. 5.

CH2

R
CH3
AT
O
O
H
O OH
HO
HO N(CH3)2
K

OH

6. 7. O O
T

O
O O
O
EE

O OCH3
O
erythromycin
N
VI

8. 9.

“The future is my canvas. Now I

have to paint the right picture”
 IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.5

1. How many ether is/are possible for molecular formula C4H10O.

(A) 1 (B) 2 (C) 3 (D) 4
2. How many ketone is/are possible for molecular formula C4H8O
(A) 1 (B) 2 (C) 3 (D) 4
3. How many alcohol is/are possible for Molecular farmula C4H10O (only structural)
(A) 2 (B) 3 (C) 4 (D) 5

IR
O
O–H
4.

IS
O

Number of Functional group in above compound is

(A) 3 (B) 4 (C) 5 (D) 6

R
5. The functional groups in Cortisone are : HOH2C
(A) Ether, alkene, alcohol CH3 OCH3
AT O
(B) Alcohol, ketone, alkene, ether
(C) Alcohol, ketone, amine
(D) Ether, amine ketone
H
O O Cortisone
O
K

O–H
6. H SH
OH
OH
T

How many types of functional groups are present in given compound.

EE

(A) 6 (B) 5 (C) 4 (D) 7

CH3 O

7. Present functional group is

N

O CH3
VI

(A) ketone (B) ester (C) ether (D) alcohol

8. Present functional group is/ are
O O
||
OCCH3

O
(A) ketone (B) ester (C) ether (D) A and B both

"Histroy tells stories about great men from the past so

write your story now."
 IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.6

1. Circle the functional group & also find out the degree of unsaturation
O
H
N H
N
O H
(i) (ii) O
N O
Me

IR
OH O
O
O Cl
(iii) (iv)

IS
H
H
O O O O
OH O

R
O
O O HO
AT O
O
(v) (vi)
N
O
NH2
H
O O O NH2
O
K

2. Which of following is phenol ?

OH OH OH
T

(A) (B) (C) (D)

EE

OH

O
N

NH2 OH
3. OH
VI

O
H
O NH2

(i) Which functional group is not present in above compound ?

(A) Ketone (B) Carboxylic acid (C) Amine (D) Alcohol
(ii) Which functional group is present in above compound ?
(A) Ester (B) 2° amine (C) Alkyne (D) Amide
(iii) Types of functional group is present in above compound
(A) 5 (B) 6 (C) 7 (D) 8
(iv) Degree of unsaturation in above compound is
(A) 5 (B) 6 (C) 7 (D) 8
(v) Above compound is Bicyclo (A) Yes (B) No

(vi) Above compound is spiro (A) Yes (B) No

 O O

C–NH2

4.

NH2 OH

H O
(i) Which functional group is not present in above compound ?
(A) Ketone (B) Carboxylic acid (C) Amine (D) Alcohol

IR
(ii) Which functional group is present in above compound ?
(A) Ester (B) 2° amine (C) Alkyne (D) Amide
(iii) Types of functional group is present in above compound

IS
(A) 5 (B) 6 (C) 7 (D) 8
(iv) Degree of unsaturation in above compound is
(A) 5 (B) 6 (C) 7 (D) 8

R
(v) Above compound is Bicyclo (A) Yes (B) No
(vi) Above compound is spiro (A) Yes (B) No

b
NH2 c
Me
AT
N S
5.
H
O N
H a– O
d Me O–H
e
K

(i) Which functional group is not present in above compound ?

(A) Ketone (B) Phenol (C) Amine (D) Alcohol
(ii) Which functional group is present in above compound ?
T

(A) Ester (B) 2° amine (C) Alkyne (D) Amide

EE

(iii) Types of functional group is present in above compound

(A) 5 (B) 6 (C) 7 (D) 8
(iv) Degree of unsaturation in above compound is
(A) 5 (B) 6 (C) 7 (D) 8
N

(v) Above compound is Bicyclo (A) Yes (B) No

(vi) Above compound is spiro (A) Yes (B) No
VI

Observe following compound and answer questions given below.

OH (d)
OH (c)
O
(e) O
HO
6. O
N N
Me
OH H
(a) (b)
(i) Total number of different types of functional groups in this compound are
(A) 5 (B) 6 (C) 7 (D) 8

"Let your mind lead you and let your heart guide you."
 IUPAC & NOMENCLATURE
BY VINEET KHATRI SIR
CLASS-XI TIME : 35 MIN. DPP. NO.7

1. Find - D.B.E. of the following

(Write your answer in box)

(1) C4 H10 (2) C4H8

(3) C4H6 (4) C5H12O

(5) C5H10O (6) C5H8O

IR
(7) C6H12 (8) C4H8Cl2

IS
(9) C4H8Br2 (10) C4H10O

(11) C10H20 (12) CNH5

R
(13) C3H6O (14)

O
AT
(15) (16)
H
O
K

(17) (18)
T
EE

(19) (20)
N
VI

CH2 CH2
O

(21) (22)

CH2 CH2 O

O
O
C–O–H
(23) (24) CH –C–O–H
3

(25) CH3 – NH2 (26) C2H3N

[6]
2. Match the column :
Column I Column II
(Compound) (Double bond equivalent)

(A) (P) 4
H
CH3
C—N S
O
O N
COOH
(penicillin)

IR
(B) (Q) 5

IS
(Hexahelicene)
(C) (R) 7

R
(Prismane)
O
C OH
AT
(D) C (S) 19
C OH
H
O
(Ninhydrin)
K

3. Match the column :

Column I Column II
(Compound) (Double bond equivalent)
T
EE

(A) (P) 5
N

(Limonene)
VI

(B) (Q) 4

(Zingiberene)

(C) (R) 3

(Pyrene)

(D) (S) 12

(Cubane)
 ANSWER KEY
DPP No.-1
1. D 2. D 3. A 4. A 5. C 6. CD
7. ABCD 8. (a) 1°, (b) 2°, (c) 3°, (d) 3°, (e) 2°
9. (a) 2°, (b) 1°, (c) 3°, (d) 2°, (e) 2°, (f) 3°
DPP No.-2
1. a-9, b-12, c-1, d-5, e-9, f-1, g-1, h-4, i-6 2. a-9, b-11, c-3, d-5, e-9, f-3, g-0, h-7, i-5
1°
2° 1° 3° 2°
3° 4° 3° 4° 3° 3° 1° 3° 3° 1°
2° 1° 1°
2° 3° 3° 2° 2° 2° 3° 3°
3. 2° 1° 2° 3° 2°

IR
2° 3° 3° 4° 1° 3° 2° 2° 3° 1°
2° 3° 3° 2°
1°
(I) (II) (III) (IV)

IS
4. (A) P; (B) P, Q; (C) P, Q, R, S; (D) Q,R

DPP No.- 3

R
1. 4 2. 2.5 3. 7 4. 10 5. 10 6. 2 7. 7
8. 2 9. 10 10. 3 11. 3 12. 3 13. 4 14. 6
15. 0 16. 4 17. 3 18.
AT 5 19. 4 20. 4 21. 2

DPP No.- 4
1. 5 2. 0 3. 1.5 4. 2 5. 11 6. 21 7. 5
H
8. 16 9. 5

DPP No.- 5
K

1. C 2. A 3. C 4. B 5. B 6. B 7. C
8. D
T

DPP No.- 6
EE

1. Function group DBE

(i) ene, yne, ketone 5
(ii) aldehyde, 2° amine, 3° Amine, Amide, ene, ketone 6
(iii) ene, yne, anhydride, ketone and aldehyde 8
N

(iv) alcohol, naphthol, acid chloride, aldehyde 9

(v) ketone, alkene, anhydride 5
VI

(vi) ketone, aldehyde, ene, yne, alcohol, amide, 1° amine, ester 11

2. C 3. (i) B, (ii) D, (iii) B, (iv) B, (v) A, (vi) B

4. (i) B, (ii) D, (iii) B, (iv) B, (v) B, (vi) B 5. (i) A, (ii) D, (iii) C, (iv) C, (v) B, (vi) B 6. (i) C

DPP No.- 7
1.
(1) 0 (2) 1 (3) 2 (4) 0 (5) 1 (6) 2 (7) 1
(8) 0 (9 0 (10) 0 (11) 1 (12) 0 (13) 1 (14) 4
(15) 2 (16) 5 (17) 2 (18) 3 (19) 7 (20) 7 (21) 17
(22) 4 (23) 5 (24) 1 (25) 0 (26) 2
2. A  Q ; B  S ; C  P ; D R 3. A  R ; B  Q ; C  S ; D P