GPAT Physical Chemistry Syllabus
1. Composition & physical states of matter
Intermolecular forces & their impact on the state of the matter. Various physical
properties of matter, dipole moment, dielectric constant, Van Der Waal’s equation &
critical phenomenon, liquefaction of gases, aerosols.
2. Colligative Properties
The liquid state, vapor pressure, ideal & real solutions. Raoult’s law, elevation of boiling
point, depression of freezing point, osmotic pressure, determination of molecular weight
based on colligative properties.
3. Colligative Properties
First, second & third law of thermodynamics. Thermochemical laws, isothermic &
adiabatic processes, reversible processes, work of expansion, heat content, enthalpy, heat
capacity. Gibb’s & Helmholtz equation & chemical potential.
4. Refractive index
Refractive index, specific refractivity, molar refractivity, refractometers.
5. Solutions
Solubility, factors affecting solubility, solubility curves. Types of solutions, effect of co-
solvency, pH & other factors on solubility. Solubility of gases in liquids, liquids in
liquids, & solids in liquids, critical solution temperature, law of partitioning & its
applications. Solute-solvent interactions. Expression of the concentration of
pharmaceutical solutions & calculations. Molarity, molality, mole fraction & percentage
expressions.
6. Electrochemistry
Properties of electrolyte solutions, electrolysis. Faraday’s law of electrolysis, electron
transport, electrical cell, single electrode potential, concentration cells, half-cells & half-
cell potential, types of half cells, sign convention, Nernst equation, salt bridge,
electromotive series, standard potential, SHE. Measuring the relative voltage of half cells,
Calculation of standard potential. Reference & indicator electrodes. Standard oxidation-
reduction potential.
7. Ionic equilibrium
Theory of conductivity, equivalent conductance, mobility of ions, specific conductance.
8. Kinetics,
Order of reactions, derivation & internal form of rate laws, molarities of reaction,
derivation of rate constants.