CHEMISTRY Designed & Developed by DAV Centre for Academic Excellence in a workshop held at DAV College Managing Committee Chitragupta Road, New Delhi-110055 EyCLASS-XI CHEMISTRY (THEORY) Time Allowed : 3 Hrs. Maximum Marks : 70 General Instructions : (@ The paper consists of two parts : Part A and Part B (ii) Part A is objective type and Part B is subjective type and both carry equal weightage. (ii) In Part AQ. No. 1 to 19 carry 1 mark each. Q. No. 20 to 24 carry 2 marks each and Q. No. 25 and 26 are of 3 marks each. (iv) In Part BQ. No. 27 to 30 carry 2 marks each, Q. No. 31 to 34 carry 3 marks each and Q. No. 35 to 37 carry 5 marks each. () Internal choice has been provided in Part B. (vi) Log tables may be used wherever required. Part-A 1. C,H,, can be represented by formula CH,OC,H, and C,H,OC,H,. This phenomenon is called (a) Metamerism (b) Functional group Isomerism (c) Stereoisomerism (@)_ Chain Isomerism @ 2. Given that critical temperatures for NH, Hy, O, and CO, are 405.5, 33.2, 154.3 and 304.1 K respectively. Which of the these gases will liquify first if we start cooling from 500 K? (a) NH, ) H, ) 0, (@ CO, a 81The statement that is not correct for periodic classification of elements is: (a) The properties of elements are periodic function of their atomic numbers. (b) Non-metallic elements are less in number than metallic elements. (©) For transition elements, the 3d-orbitals are filled with electrons after 3p-orbitals and before 4s-orbitals. (a) The first ionization enthalpies of elements generally increase with increase in atomic number as we go along a period. a Arrange the following ions in the decreasing order of their hydration enthalpy Be? , Mg?*, Ca’, Sr?*, Ba’* a For the reaction 2CI(g) —> Cl,(g), the signs of AH and AS respectively are: @ +- ) + © -- @ —+ a Select the correct statement about the boiling point of isomeric pentanes: (a) Neopentane has maximum boiling point due to maximum branching in chain, (b) Branching does not affect the boiling point of isomer pentanes. (c) _n-pentane has maximum boiling point due to maximum surface area. (d)_Isopentane has minimum boiling point due to two methyl groups on same carbon. qa) The electron gain enthalpy of chlorine is more negative than that of fluorine due to : (a) high reactivity of chlorine (b) bigger size of chlorine (©) different electronic configuration than flourine (@ smaller nuclear charge of chlorine a 828. 10. iL. 12, In an isothermal expansion of an ideal gas into vacuum, the work involved is: (a) zero (b) maximum © minimum (@_ none of these @ Conjugate base of HCO,” is (a) H,CO, (b) OF (© Ht (a) cO,? wo For the reaction CO (g) + Cl, (g) > COCI,(g), Kp/Ke is equal to (a) JRT ) RT © VRT @ 10 @ Find the molecule with the maximum dipole moment (@) CH, (b) NH, @ C0, @ NF, a The solubility product of BaSO, is 1.0 x 10°, its solubility will be moIL"?. (a) 10% (b) 1x 10% @ 1x10? (ad) 10° @ In the following questions a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose the correct option out of the choices given below each question. 13. Assertion (A) : Though the central atom of both NH, and H,O molecules are sp’ hybridised, yet H-N-H bond angle is greater than that of H-O-H, Reason (R) : This is because nitrogen atom has one lone pair and oxygen atom has two lone pairs which render a greater repulsion. (a) A and R both are correct, and R is the correct explanation of A. (b) Aand R both are correct, but R is not the correct explanation of A. (© Ais true but R is false. (d@) A and R both are false. wD ES14. Assertion (A) : In the reaction Zn(s) + CuSO,(aq) > ZnSO,{aq) + Cu(s), Zn is a reductant but itself get oxidized. Reason (R) : In a redox reaction, oxidant is reduced by increase in the oxidation number of element by accepting electrons and reductant is oxidized by losing electrons. (a) A and R both are correct, and R is the correct explanation of A. (b) A and R both are correct, but R is not the correct explanation of A. (©) Ais true but R is false. (d) A and R both are false. @ 15. Assertion (A) : Nitration of benzene is done using nitrating mixture which is a mixture of conc. HCl and conc. HNO, Reason (R) : The mixture of concentrated Sulphuric acid and concentrated Nitric acid produces the electrophile, NO,*. (a) Both A and R are correct and R is the correct explanation of A. (b) Both A and R are correct but R is not the correet explanation of A. (©) Both A and R is false. (a) Ais false but R is true @ 16. Assertion (A) : Combustion of 16 g of methane gives 36 g of water. Reason (R) : In the combustion of methane, CO, is one of the products. (a) A and R both are correct, and R is the correct explanation of A. (b) A and R both are correct, but R is not the correct explanation of A. (@) Ais true but R is false. (@) Ais false but R is true. a 17. The stability of carbocations is of the order (a) primary > secondary > tertiary (b) secondary > primary > tertiary (©) tertiary > primary > secondary (d)_ tertiary > secondary > primary @ 8418. Identify whether the following statement is True or False Isobutyl alcohol is an example of a secondary alcohol. @ 19. Write the IUPAC name for the following compound (CH3—CH,~CH-CH,-CH)-CH-CH, CH bu ba @ 20. Match the followiong quantum numbers with their statements : Quantum numbers Statements (a) Spin quantum number i) orientation of atomic orbitals () Principal quantum number | (ii) number of subshells (©) Magnetic quantum number | (iii) number of shells (@) Azimuthal quantum number | (iv) direction of spin (a) (a)-(iii), (b)(ii), ()-G), (d)-fiv) (b) (a)iv), (b}Gii), (©)-@, (iv)-Gii) (©) (a)-(i), (b)-(iii), (€)-(ii), (d)-Civ) (d) (a)iv), (bi), (¢)-(), (iv)-Gii) (2) 21. Comprehension given below is followed by multiple choice questions. Each question has one correct option. Choose the correct option In the modern periodic table, elements are arranged in order of increasing atomic numbers which is related to the electronic configuration. Depending upon the type of orbitals receiving the last electron, the elements in the periodie table have been divided into four blocks, viz s, p, d and f. The modern periodic table consists of 7 periods and 18 groups. Each period begins with the filling of a new energy shell. In accordance with the Aufbau principle, the seven periods have 2, 8, 8, 18, 18, 32 and 32 elements respectively. 8522. 23. The seventh period is still incomplete. To avoid the periodic table being too long, the two series of f-block elements, called lanthanoids and actinoids are placed at the bottom of the main body of the periodic table. (a) The electronic configuration of the element which is just above the clement with atomic number 43 in the same group and same block is (i) 1s? 28? 2p% 38? 3p8 3d° 4s” (ii) 1s? 2s? 2p® 3s? 3p® 3d° 45° 4s° (iii) 1s? 2s? 2p® 3s 3p% 3d8 4s” (iv) 1s? 2s? 2p% 3s? 3p$ 3d7 4s” (b) The elements with atomic numbers 35, 53 and 85 are all (i) noble gases (i) halogens (iii) heavy metals (iv) light metals (@) ai), bi) (b) a-tiii), b-Gii) (©) adliii), b-Gii) (a) acti), (ii) @) The value of Ke for the reaction 2A ——» B + C is 2 x 10%. Ata given time the composition of reaction mixture is [A] = [B] = [C] = 3 x 10 M. Predict the direction in which the reaction will proceed. (a) it will remain at equilibrium ——(h)__ reverse direction (©) forward direction (a) reaction stops (2 Match the following characteristics with the element : Characteristic Element (i) Does not impart any characteristic colour to the flame (a) K Gi) Used in photoelectric cells ) Li Gii) Forms a superoxide © Mg (iv) Strongest reducing agent @ Cs (a) (©), iia), iii-(@), iv-(b) (b) i), ii-(0), iti-(a), iva) (©) (0), ii-(d), ifi-(a), iv-(b) (@) ib), ii-(@), iii-(a), iv-(o) (2) 624. Carbocations are one of the reactive intermediates formed during 26. particular chemical reactions. (a) Name the effet which determines the stability of a carbocation. (b) Name the type of fission that produces carbocation. (2) Dihydrogen, under certain conditions, combines with almost all the elements except noble gases to form binary compounds called hydrides, The hydrides are classified into ionic hydrides, covalent hydrides and metallic hydrides. @ Among LiH, NaH, KH, RbH and CsH the correct order of ionic character : (a) LiH > NaH > KH > RbH > CsH (b) LiH > NaH > CsH > KH > RbH (©) CsH > RbH > KH > NaH > Li (a) NaH > CsH > RbH > LiH > KH (ii) Which of the following hydrides is electron precise hydrides ? (a) BH, (b) NH, H,0 (@) CH, ii) Which of the following hydride reacts violently with water ? (a) KH () NH, @ CH, @ BAH, (a) 10), H-@), iii-(@) (b) ia), ii-(), itia) (©) ib), iia), iii-(0) (@) (a), 1-0), ii-(b) (3) Alkanes contain carbon-carbon sigma bonds. The rotation around the carbon-carbon single bond results into different spatial arrangements which can change into one another. These spatial arrangements are called conformations and the structures so formed are called conformers or rotamers. Alkanes thus have an infinite a727. 28. 29. number of conformations. The rotation is hindered by a small energy barrier due to weak repulsive interaction between the adjacent bonds which is called torsional strain. The conformations can be represented by Sawhorse and Newman projections, On the basis of the above information (a) Identify the conformation of ethane having maximum torsional strain, (b) Which conformation of ethane is the most stable ? (©) How many conformers are possible for ethane by rotation around the C-C bond ? (3) Part-B The reactant which is entirely consumed in reaction is known as limiting reagent. In the reaction 2A + 4B — 3C + 4D, when 5 moles of A reacts with 6 moles of B, then- (i) Identify the limiting reagent. Gi) Calculate the amount of product C formed. (2) Balance the equation by ion electron method Dichlorineheptaoxide (C1,0,) in gaseous state combines with an aqueous solution of hydrogen peroxide in acidic medium to give chlorite ion (ClO-,) and oxygen gas. @ Aluminium dissolves in mineral acids and aqueous alkalies and thus shows an amphoteric character. A piece of aluminium metal is treated with dil. Hydrochloric acid or dil. Sodium hydroxide solution in a test tube and on bringing burning match stick near the mouth of the test tube, a pop sound indicates the evolution of hydrogen gas. The same activity when performed with concentrated nitric acid does not produce any pop sound. (a) Write the reaction of Aluminium with dil. Hydrochloric acid. (b) Why Aluminium does not show any reaction with cone. Nitric acid ? (2) OR Describe the bonding in B,H,. 8830. 31. 32. 33. 34, 35. Draw and compare the resonating structures of CH,=CHCHO in terms of their stability and choose the most stable resonating structure. 2) A compound contains 4.07% hydrogen, 24.27% carbon and 71.65% of chlorine. Its molar mass is 98.96 g. Derive its empirical and molecular formula. (Given atomic mass of H = lu; C = 12u; Cl = 35.5u) (3) Emission transitions in the Paschen Series end at orbit n = 3 and start 3.29 x 10" (HZ)[1/3? - V/n?], Calculate the value of n if the transition is observed at 1285 nm. Find the region of spectrum for the transition. (3) OR Neon gas is generally used in the signboards. If it emits strongly at 616 nm, caleulate- from orbit n represented as (a) the frequency of emission (b) distance travelled by this radiation in 30 s (c) the energy of quantum Find the bond order and compare the relative stabilities of the following species and indicate their magnetic properties : - 92 0,, 0,7, 0; (3) Calculate AG? for the following = CO(g) + 40,(g) > CO,(g), AH? = Given : AS' 282.84 kJ/mol "cog = 213.8 JK mol , AS*oq = 197.9 JK7 mol , AS%o, = 205.0 JK mol (3) Boiling point of HF, HCl, HBr and HI are 293 K, 189 K, 206 K and 238 K respectively. Using the above information and data, answer the following questions : (a) Which type of intermolecular forces are present in the molecules HF, HCI, HBr and HI? Ey36. (b) (c) (a) (b) (©) Why is boiling point of hydrogen fluoride the highest while that of hydrogen chloride the lowest ? 34.05 ml of phosphorus vapour weighs 0.0625 g at 546°C and 1.0 bar pressure. What is the molar mass of phosphorus ? 6) OR A gas that follows Boyle's law, Charle’s law and Avogadro's law is called an ideal gas. Under what conditions a real gas would behave ideally? ‘The size of weather balloon becomes larger and larger as it ascends into higher altitudes. Explain. A 34.0 dm? cylinder contains 212 g of oxygen gas at 21°C. What mass of oxygen must be released to reduce the pressure in the cylinder to 1.24 bar ? Explain the following (a) (b) (©) (d@) (e) (a) (b) Gallium has higher ionization enthalpy than aluminium Stability of dihalides of group 14 increases down the group. Carbon shows catenation but other members of the group do not. BCI, when treated with water, hydrolyses and forms [B(OH),|" whereas AICI, forms [A/(H,0),|** ion. TINO. ), acts as oxidizing agent. ) oR Write balanced equations for : () SiCl, + H,O > + Gi) C+0,+N,o_ + fat 1273 Give reasons (i) Excessive content of CO, is responsible for global warming. ii) Heavier members of carbon family do not form pr-pr multiple bonds. (iii) Boric acid is considered as a weak acid. 10037. (a) (by (a) (b) A hydrocarbon X decolourises bromine water and produces Propan- 2one and Methanal on reductive ozonolysis. Analyse the given information carefully and give structure and IUPAC name of X. Formation of Arenium ion (sigma complex) is a very important step in the Electrophilic substitution reaction of benzene. Organize all the steps involved to explain the mechanism of Friedel Crafts acylation of benzene. ) OR Compare the following compounds and identify which of the two is aromatic in nature and what criteria does it satisfy. Cyclopentadiene Cycloheptatriene cation Analyze the role of benzoyl peroxide in the reaction of Propene and HBr in the presence of this peroxide and give stepwise mechanism for the reaction. 101