Conforms to ANSI Z400.

1-2004 Standard - US

Material Safety Data Sheet

Protective Clothing General Hazard DOT
Class 3: Flammable liquid.
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Section 1. Product identification and uses

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Product Name and/or Code : HEMPADUR MASTIC 45889

4588911150
Company name and address : HEMPEL (USA), Inc.
600 Conroe Park North Drive
Conroe, Texas 77303
Toll free: (800) 678-6641, if outside area codes 713, 281, 409, 936
Regular phone number: (936) 523-6000
Product Type : epoxy primer (base for multi-component product)
Ready for use mixture : 45880 = 45889 3 vol. / 95880 1 vol. 45881 = 45889 3 vol. / 95881 1 vol. 4588W =
45889 3 vol. / 9588W 1 vol.
TSCA : Unless otherwise noted, all ingredients are TSCA listed.
Date of issue : 6/3/2010.
Date of Previous Issue : No previous validation.
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Section 2. Hazards identification

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Physical state : Liquid.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200).
Emergency treatment : WARNING!
FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED
THROUGH SKIN OR IF SWALLOWED. CONTAINS MATERIAL THAT MAY
CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE
CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER,
BASED ON ANIMAL DATA.
Flammable liquid. May be harmful if absorbed through skin or if swallowed. Keep
away from heat, sparks and flame. Avoid exposure - obtain special instructions
before use. Do not breathe vapor or mist. Do not ingest. Do not get in eyes.
Avoid contact with skin and clothing. Contains material that may cause target
organ damage, based on animal data. Contains material which may cause cancer,
based on animal data. Risk of cancer depends on duration and level of exposure.
Use only with adequate ventilation. Keep container tightly closed and sealed until
ready for use. Wash thoroughly after handling.
Routes of entry : Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Eyes : May cause eye irritation.
Skin : Harmful in contact with skin. May cause skin irritation.
Potential chronic health effects : See section 11 for more detailed information on health effects and symptoms.
(for componet ingredients)
Medical conditions aggravated : Pre-existing disorders involving any target organs mentioned in this MSDS as being
by over-exposure at risk may be aggravated by over-exposure to this product.

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HEMPADUR MASTIC 45889
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Section 3. Composition/information on ingredients

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Product/ingredient name CAS # % Occupational exposure limits

bisphenol A-(epichlorhydrin) epoxy resin 25068-38-6 15 - 25
MW =< 700
titanium dioxide *13463-67-7 10 - 12.5 OSHA PEL (United States, 11/2006).
TWA: 15 mg/m³ 8 hour(s). Form: Total dust
ACGIH TLV (United States, 1/2008).
TWA: 10 mg/m³ 8 hour(s).
xylene 1330-20-7 5 - 10 ACGIH TLV (United States, 1/2009).
STEL: 651 mg/m³ 15 minute(s).
STEL: 150 ppm 15 minute(s).
TWA: 434 mg/m³ 8 hour(s).
TWA: 100 ppm 8 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 435 mg/m³ 8 hour(s).
TWA: 100 ppm 8 hour(s).
benzyl alcohol 100-51-6 3-5 AIHA WEEL (United States, 1/2009).
TWA: 10 ppm 8 hour(s).
cyclohexanone 108-94-1 1-3 ACGIH TLV (United States, 1/2009). Absorbed through skin.
STEL: 50 ppm 15 minute(s).
TWA: 20 ppm 8 hour(s).
NIOSH REL (United States, 6/2009). Absorbed through skin.
TWA: 100 mg/m³ 10 hour(s).
TWA: 25 ppm 10 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 200 mg/m³ 8 hour(s).
TWA: 50 ppm 8 hour(s).
ethylbenzene 100-41-4 1-3 ACGIH TLV (United States, 1/2009).
STEL: 125 ppm 15 minute(s).
TWA: 100 ppm 8 hour(s).
NIOSH REL (United States, 6/2009).
STEL: 545 mg/m³ 15 minute(s).
STEL: 125 ppm 15 minute(s).
TWA: 435 mg/m³ 10 hour(s).
TWA: 100 ppm 10 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 435 mg/m³ 8 hour(s).
TWA: 100 ppm 8 hour(s).

Notes
See toxicological information (section 11)
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Section 4. First aid measures

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General : In all cases of doubt, or when symptoms persist, seek medical attention. Never
give anything by mouth to an unconscious person.
Inhalation : Remove to fresh air. Keep person warm and at rest. If unconscious, place in
recovery position and seek medical advice.
Eye Contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of
water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek
immediate medical attention.
Skin Contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognized skin cleanser. Do not use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this document. Keep
person warm and at rest. Do NOT induce vomiting unless directed to do so by
medical personnel. Lower the head so that the vomit will not reenter the mouth
and throat.
Notes to physician : If gasses have been inhaled, from the decomposition of the product, symptoms
may be delayed.

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HEMPADUR MASTIC 45889
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Section 5. Fire-fighting measures

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Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be
taken involving any personal risk or without suitable training. Fire will produce dense black smoke. Exposure to
decomposition products may cause a health hazard. Cool closed containers exposed to fire with water. Do not release
runoff from fire to drains or watercourses. Fire-fighters should wear appropriate protective equipment and self-
contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Flash point : Closed cup: 37°C (98.6°F)
Explosion Limits : Lower: 1%
Upper: <=13%
Fire-fighting media and : Recommended: alcohol resistant foam, CO2, powders, water spray.
instructions Not to be used: waterjet.
Promptly isolate the scene by removing all persons from the vicinity of the incident
if there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool. Fire water contaminated
with this material must be contained and prevented from being discharged to any
waterway, sewer or drain.
Flammable liquid. In a fire or if heated, a pressure increase will occur and the
container may burst, with the risk of a subsequent explosion. Runoff to sewer
may create fire or explosion hazard.
Special protective equipment : Fire-fighters should wear appropriate protective equipment and self-contained
for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Fire Degradation Products : Decomposition products may include the following materials: carbon oxides
nitrogen oxides halogenated compounds metal oxide/oxides
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Section 6. Accidental release measures

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Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid breathing vapor or mist. Refer
to protective measures listed in sections 7 and 8.
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous
earth, and place in container for disposal according to local regulations (see section 13). Do not allow to enter drains
or watercourses. Clean preferably with a detergent; avoid use of solvents. If the product contaminates lakes, rivers, or
sewers, inform the appropriate authorities in accordance with local regulation.
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Section 7. Handling and storage

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Handling
Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the
creation of flammable or explosive concentrations of vapors in air and avoid vapor concentrations higher than the
occupational exposure limits. In addition, the product should be used only in areas from which all naked lights and
other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard.
To dissipate static electricity during transfer, ground drum and connect to receiving container with bonding strap. No
sparking tools should be used. Contains epoxy constituents. Avoid all possible skin contact with epoxy and amine
containing products, they may cause allergic reactions.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should
be prohibited in area where this material is handled, stored and processed. Appropriate personal protective
equipment: see Section 8. Always keep in containers made from the same material as the original one.
Storage
Store in accordance with local regulations for flammable liquids. Store in a cool, well-ventilated area away from
incompatible materials and ignition sources. Keep out of the reach of children. Keep away from: Oxidizing agents,
strong alkalis, strong acids. No smoking. Prevent unauthorized access. Containers that are opened must be carefully
resealed and kept upright to prevent leakage.

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HEMPADUR MASTIC 45889
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Section 8. Exposure controls/personal protection

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Engineering measures : Arrange sufficient ventilation by local exhaust ventilation and good general
ventilation to keep the airborne concentrations of vapors or dust lowest possible
and below their respective threshold limit value. Ensure that eyewash stations and
safety showers are proximal to the work-station location.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling the product and before
eating, smoking, using lavatory, and at the end of day.
TLV : Occupational Exposure Limit(s), if available, are listed in section 3
Personal protective equipment
General : Gloves must be worn for all work that may result in soiling.
Apron/coveralls/protective clothing must be worn when soiling is so great that
regular work clothes do not adequately protect skin against contact with the
product. Safety eyewear should be used when there is a likelihood of exposure.
Respiratory system : If working areas have insufficient ventilation, wear half or totally covering mask
equipped with gas filter of type Organic Vapor, when grinding use particle filter of
type P95, P99 or P100. When spraying use a combined filter (organic vapor /
HEPA or organic vapor / P100 type). Be sure to use approved/certified respirator
or equivalent. Always wear an air-fed respirator when spraying in a continuous and
prolonged work situation (e.g. hood with supply of fresh or compressed air or a full
face, powered air purifying filter).
Skin and body : Wear suitable protective clothing. Always wear protective clothing when spraying.
Hands : Wear suitable gloves. For prolonged or repeated handling, use gloves. Barrier
creams may help to protect the exposed areas of the skin, but should not be
applied once exposure has occurred. Barrier creams may not be used under or
instead of gloves.
Since the actual work situation is unknown. Supplier of gloves should be
contacted in order to find the appropriate type.
Eyes : Use safety eyewear designed to protect against splash of liquids. Safety glasses
with side shields.
Protective clothing (pictograms) :

Note: Application of paint products by spraying requires additional safety

precautions: Full body suit, Full face respirator with air supplied.
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Section 9. Physical and chemical properties

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Physical state : Liquid.

Density : 1.66 g/cm3
Solubility : Partially soluble in the following materials: cold water, hot water and n-octanol.
% Solvent by Weight : Weighted average: 13 %
% Water by Weight : Weighted average: 0 %
VOC Content : 220 g/l (Measured)
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Section 10. Stability and reactivity

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Stability : Stable under recommended storage and handling conditions (see section 7).
Hazardous decomp. products : Decomposition products may include the following materials: carbon oxides
nitrogen oxides halogenated compounds metal oxide/oxides
Products of degradation : Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
Reactivity : Highly reactive or incompatible with the following materials: oxidizing materials and
metals.
Reactive or incompatible with the following materials: reducing materials.

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HEMPADUR MASTIC 45889
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Section 11. Toxicological information

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Effects and symptoms

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane
and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may
cause some of the above effects by absorption through the skin. Symptoms and signs include headaches, dizziness,
fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or prolonged contact
with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and
absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible damage. Accidental
swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Epoxy and amine containing products can cause skin disorders such as allergic eczema. The allergy may arise after
only a short exposure period.
.
Acute toxicity
Product/ingredient name Result Dose Species
cyclohexanone LD50 Dermal 1 mL/kg Rabbit
LD50 Oral 1800 mg/kg Rat
LDLo Intravenous 568 mg/kg Rat
LDLo Oral 1600 mg/kg Rabbit
LC50 Inhalation Gas. 8000 ppm Rat
benzyl alcohol LD50 Dermal 2000 mg/kg Rabbit
LD50 Oral 1230 mg/kg Rat
ethylbenzene LD50 Dermal >5000 mg/kg Rabbit
LD50 Dermal 17800 uL/kg Rabbit
LD50 Oral 3500 mg/kg Rat
LC50 Inhalation Vapor 55000 mg/m3 Rat
xylene LD50 Dermal >1700 mg/kg Rabbit
LD50 Oral 4300 mg/kg Rat
LC50 Inhalation Gas. 5000 ppm Rat
.
Specific effects
.
Carcinogen Classification
Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHA
titanium dioxide A4 2B - None. - -
xylene A4 3 - None. - -
benzyl alcohol - - - None. - -
cyclohexanone A3 3 - None. - -
ethylbenzene A3 2B - None. - -
.
Sensitization : Contains bisphenol A-(epichlorhydrin) epoxy resin MW =< 700. May produce an
allergic reaction.
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Section 12. Ecological information

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The product must not be drained into water courses or drainage system.
Product/ingredient name Result Species Exposure
cyclohexanone Acute LC50 527000 - 578000 ug/L Fresh water Fish - Pimephales promelas 96 hours
benzyl alcohol Acute LC50 10000 ug/L Fresh water Fish - Lepomis macrochirus 96 hours
titanium dioxide Acute EC50 >1000000 ug/L Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 5.5 ppm Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 >1000000 ug/L Marine water Fish - Fundulus heteroclitus 96 hours
Chronic NOEC 500 ppm Fresh water Daphnia - Daphnia magna 48 hours
ethylbenzene Acute EC50 6530 - 9460 ug/L Fresh water Crustaceans - Artemia sp. 48 hours
Acute EC50 2930 - 4400 ug/L Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 280 - 290 ppm Marine water Fish - Cyprinodon variegatus 96 hours
Acute LC50 13900 - 17200 ug/L Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 >5200 ug/L Marine water Crustaceans - Americamysis bahia 48 hours
Chronic NOEC 3300 ug/L Marine water Fish - Menidia menidia 96 hours
xylene Acute LC50 8500 ug/L Marine water Crustaceans - Palaemonetes pugio 48 hours
Acute LC50 8200 - 10032 ug/L Fresh water Fish - Oncorhynchus mykiss 96 hours

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HEMPADUR MASTIC 45889
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Section 13. Disposal considerations

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Waste disposal : The generation of waste should be avoided or minimized wherever possible.
Empty containers or liners may retain some product residues. This material and its
container must be disposed of in a safe way. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Disposal of this
product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Avoid dispersal of spilled material and runoff
and contact with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws
and regulations. Local regulations may be more stringent than regional or national
requirements.

The information presented below only applies to the material as supplied. The
identification based on characteristic(s) or listing may not apply if the material has
been used or otherwise contaminated. It is the responsibility of the waste generator
to determine the toxicity and physical properties of the material generated to
determine the proper waste identification and disposal methods in compliance with
applicable regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE

CONTROLS/PERSONAL PROTECTION for additional handling information and
protection of employees.
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Section 14. Transport information

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Transport may take place according to national regulation or DOT for transport by road and by train, IMDG for
transport by sea. Air shipment: Refer to specific Danerous Goods Transport requirements under 49CFR, ICAO and
IATA.
UN-no. Proper shipping name Class PG* Label Additional information

DOT UN1263 PAINT. (bisphenol A-(epichlorhydrin) 3 III

Class. epoxy resin MW =< 700) ERG
128

TDG UN1263 PAINT. (bisphenol A-(epichlorhydrin) 3 III

Class. epoxy resin MW =< 700)

Mexico UN1263 PAINT. (bisphenol A-(epichlorhydrin) 3 III

Class. epoxy resin MW =< 700)

IMDG UN1263 PAINT. (bisphenol A-(epichlorhydrin) 3 III Emergency schedules

Class epoxy resin MW =< 700) (EmS)
F-E, S-E P

Marine pollutant
PG* : Packing group
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Section 15. Regulatory information

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HCS Classification : Flammable liquid.

Carcinogen
Target organ effects
U.S. Federal regulations : All components are listed or exempted.
TSCA 8(a) PAIR: benzaldehyde
TSCA 8(a) IUR: bisphenol A-(epichlorhydrin) epoxy resin MW =< 700; lecithin;
carbonblack
United States inventory (TSCA 8b): All components are listed or exempted.
TSCA 8(d) H and S data reporting: epichlorohydrin: 1982; ethylbenzene: 1987;
phenol: 1987; 2-phenylpropene: 1987; benzaldehyde: 1991; cyclohexanone: 1982

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HEMPADUR MASTIC 45889
SARA 302/304/311/312 extremely hazardous substances: No products were
found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: bisphenol A-(epichlorhydrin) epoxy
resin MW =< 700; xylene; ethylbenzene; titanium dioxide; nepheline syenite; benzyl
alcohol; cyclohexanone
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
bisphenol A-(epichlorhydrin) epoxy resin MW =< 700: Immediate (acute) health
hazard, Delayed (chronic) health hazard; xylene: Fire hazard, Immediate (acute)
health hazard, Delayed (chronic) health hazard; ethylbenzene: Fire hazard,
Immediate (acute) health hazard, Delayed (chronic) health hazard; alpha'-(1,3-
xylenediyl)bis(12-hydroxyoctadecanamide): Immediate (acute) health hazard,
Delayed (chronic) health hazard; titanium dioxide: Immediate (acute) health hazard;
nepheline syenite: Immediate (acute) health hazard, Delayed (chronic) health
hazard; benzyl alcohol: Immediate (acute) health hazard, Delayed (chronic) health
hazard; cyclohexanone: Fire hazard, Immediate (acute) health hazard, Delayed
(chronic) health hazard

Clean Water Act (CWA) 307: ethylbenzene; phenol

Clean Water Act (CWA) 311: xylene; ethylbenzene; phenol
Clean Air Act (CAA) 112 accidental release prevention: epichlorohydrin
Clean Air Act (CAA) 112 regulated flammable substances: No products were
found.
Clean Air Act (CAA) 112 regulated toxic substances: epichlorohydrin
SARA 313
Product/ingredient name CAS number Concentration
Form R - Reporting : xylene 1330-20-7 5 - 10
requirements ethylbenzene 100-41-4 1-3

Supplier notification : xylene 1330-20-7 5 - 10

ethylbenzene 100-41-4 1-3
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and
redistribution of the notice attached to copies of the MSDS subsequently redistributed.

State regulations
Connecticut Carcinogen Reporting: None of the components are listed.
Connecticut Hazardous Material Survey: None of the components are listed.
Florida substances: None of the components are listed.
Illinois Chemical Safety Act: None of the components are listed.
Illinois Toxic Substances Disclosure to Employee Act: None of the components are listed.
Louisiana Reporting: None of the components are listed.
Louisiana Spill: None of the components are listed.
Massachusetts Spill: None of the components are listed.
Massachusetts Substances: The following components are listed: CYCLOHEXANONE; BENZYL ALCOHOL;
TITANIUM DIOXIDE; ETHYL BENZENE; XYLENE
Michigan Critical Material: None of the components are listed.
Minnesota Hazardous Substances: None of the components are listed.
New Jersey Hazardous Substances: The following components are listed: CYCLOHEXANONE; TITANIUM
DIOXIDE; ETHYL BENZENE; BENZENE, ETHYL-; XYLENES; BENZENE, DIMETHYL-
New Jersey Spill: None of the components are listed.
New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.
New York Acutely Hazardous Substances: The following components are listed: Cyclohexanone; Ethylbenzene;
Xylene (mixed)
New York Toxic Chemical Release Reporting: None of the components are listed.
Pennsylvania RTK Hazardous Substances: The following components are listed: CYCLOHEXANONE;
BENZENEMETHANOL; TITANIUM OXIDE (TIO2); BENZENE, ETHYL-; BENZENE, DIMETHYL-
Rhode Island Hazardous Substances: None of the components are listed.

WARNING: This product contains a chemical known to the State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or
other reproductive harm.
California Prop. 65 PFF
Product/ingredient name Cancer Reproductive No significant risk level Maximum acceptable
dosage level

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HEMPADUR MASTIC 45889
ethylbenzene Yes. No. No. No.
respirable quartz Yes. No. No. No.
carbonblack Yes. No. No. No.
epichlorohydrin Yes. Yes. Yes. No.
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Section 16. Other information

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Label requirements : FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED

THROUGH SKIN OR IF SWALLOWED. CONTAINS MATERIAL THAT MAY
CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. POSSIBLE
CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE CANCER,
BASED ON ANIMAL DATA.
Hazardous Material Information National Fire Protection
System (U.S.A.) Association (U.S.A.)
Health * 2
3 Flammability
Fire hazard 3
Health 2 0 Instability
Physical hazards 0
H Special
Personal protection

Remarks : Note: In USA, consult Code of Federal Regulations, Title 29, Labor, Parts 1910
and 1915 concerning occupational safety and health standards and regulations, as
well as any other applicable Federal, State or local regulations that apply to safe
practices in coating operations.
Warning! If you scrape, sand, or remove old paint, you may release lead dust.
LEAD is TOXIC.
Emergency telephone number : For Transportation Emergencies, call CHEMTREC: (800) 424-9300.
If outside USA/Canada, call: (703) 527-3887.
For all other information call Hempel (USA), Inc. (936) 523-6000.
Toll free: (800) 678-6641, if outside area codes 713, 281, 409, 936
Validation : Validated by US - Al Pliodzinskas on 6/3/2010.
Verified by US - Al Pliodzinskas.
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries
assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any
material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards
are described herein, we cannot guarantee that these are the only hazards that exist.

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