Central Academy,
Indira Nagar
Holiday Assignment
Choose and write the correct answer for each of the following.
1. The value of van’t Hoff factor for eithanoic acid in benzene is
(a) 1.5 (b) 1.5
(c) 0.5 (d) 2
2. Which of the following aqueous solutions should have the highest boiling point?
(a) 1.0 M NaOH (b) 1.0 M Na2SO4
(c) 1.0 M NH4NO3 (d) 1.0 M KNO3
3. An unknown gas ‘X’ id Dissolved in water at 2.5 bar pressure and has mole fraction 0.04
in solution. The mole fraction of ‘x’ gas when the pressure of gas is doubled at the same
temperature is
(a) 0.08 (b) 0.04
(c) 0.02 (d) 0.92
4. An azeoteropic solution of two liquids has a boling point lower than either of the two
when it
(a) Shows a positive deviation from Raoult’s law.
(b) Shows a negative deviation from Rault’s law.
(c) Shows no deviation from Raoult’s law.
(d) Is saturated.
5. Which one of the following pairs will from an ideal solution?
(a) Chloroform and acetone
(b) Ethanol and acetone
(c) n- hexane and n-heptane
(d) Phenol and aniline
6. Assertion (A) : Molarity of a solution in liquid sate changes with temperature.
Reason (R) : The volume of a solution changes with change in temperature.
7. Assertion (A) : Osmotic pressure is a colligative property.
Reason (R) : Osmotic pressure is proportional to the molality.
8. Assrtion : (A) : if more volatile liquid is added to another liquid, vapor pressure of solution will
be greater than that of pure solvent .
Reason (R) : Vapour pressure of solution is entirely due to solvent molecule
9.Assertion (A) : The bolling point of pure solvent is always higher than the boiling point of
solution.
Reason (R) : The Vapur pressure of the solvent decreases in the presence of non-volatile solute.
10.Assertion (A) : THE boiling point 0of 0.1 M UREA SOLUTION is less than that of 0.1 M
KCI Solution.
Resound (R ) : Elevation of bolling point is direction proportional to the number of species
present in the solution.
Answer the folling questions :
11. What type of deviation is shown by a mixture of ethanol and acetone? What type of azeotrope
is formed by mixing ethanol and acetone?
12. Derive the relationship between relative lowering of vapour pressure and molar mass of the
solute.
13. Give reasons:.
(i) Cooking is faster in pressure cooker than in cooking pan.
(ii) Red Blood Cells (RBC) Shrink when placed in sline water but swell in distilled water.
14. Calculate the mass of non-volatile solute (molar mass 40 g mol-1) which should be dissolved
in 114 g octane to reduce its vapoure pressure to 80%.
15. Hennery’s law constant for the molality of methane in benzene at 298 k is 4.27 x 105 mm Hg.
Calculate the solubility of methane in benzene at 298 k under 760 mm Hg.
16. At 25o C the saturated vapour pressure of water is 3.165 kPa (23.75 mm Hg ). Find the
saturated vapoure pressure of a 5% aqueous solution of urea (carbamide) at the same temperature.
(Molar mass of urea = 60.05 g mol-1)
17. Calculate the freezing poin of a solution when 3 g of CaCl2 (M = 111 g mol-1) was dissolved
in 100 g of water , assuming CaCl2 undergoes complete ionisation. (Kf for water = 1.86 K kg mol-1).
18. Calculate the mass of NaCl (molar mass = 58.5 g of mol-1) to be dissolved in 37.2 g of water
to lower the freezing point by 2oC, assuming that NaCl undergoes complete dissociation.
(Kf for water = 1.86 K kg mol-1)
19. (i) When 2.56 g sulphur was dissolved in 100 g of CS2, the freezing point lowered by 0.383
K. Calculate the formula of sulphur (Sx).
[Kf for CS2 = 3.83 K kg mol-1, Atomic mass of salphur = 32 g mol-1]
(ii) Blood cells are isotonic with 0.9 % sodium chloride solution. What happens if we place
blood cells in a solution containing
(a) 1.2 % sodium chloride solution?
(b) 0.4 % sodium chloride solution?
20. (i) Why is boiling point of 1M NaCl solution more than that of 1M glucose solution?
(ii) A non-volatile solute ‘X’ (molar mass = 32g mol-1) when dissolved in 78 g of benzene reduced
its vapoure pressure to 90% . Calculate the mass of X dissolved in the solution.
