ATOMIC STRUCTURE

CPP (REVISION)

1. The potential energy of the electron present in the ground state of Li2  ion is represented by
3e 2 3e 3e 2 3e 2
(A)  (B)  (C)  (D) 
4  0 r 4 0r 4  0 r 2
4  0 r

2. If the speed of electron in the Bohr’s first orbit of hydrogen atom is x, the speed of the electron in
the Bohr’s third orbit is
(A) x/9 (B) x/3 (C) 3x (D) 9x
3. According to Bohr’s theory the angular momentum for an electron of 5th orbit is
2.5h 5h 25h 6h
(A) (B) (C) (D)
   2

4. In the Bohr’s model of the hydrogen atom, the ratio of the kinetic energy to the total energy of the
electron in a quantum state n is
(A) 1 (B) 2 (C) -1 (D) -2

5. For which of the following, the radius will be same as for hydrogen atom having n = 1?
(A) He  ,n  2 (B) Li2 ,n  2 (C) Be3  ,n  2 (D) Li2 ,n  3

6. The ratio of E2  E1  to  E4  E3  for H-atom is approximately

(A) 10.2 (B) 15.4 (C) 5.6 (D) 12.4
7. The time period for revolution of electron in Bohr orbit of ground state (n1) is T1 and time period
for revolution of electron in higher orbit (n2) is T2. Which values of n1 and n2 are not correct if
T1 1
 ?
T2 8
(A) n1  1, n2  2 (B) n1  2, n2  4 (C) n1  2, n2  3 (D) n1  3, n2  6

8. The triad of nuclei that are isotones is

(A) 14 15 17
6 C, 7 N, 9 F
(B) 12 14 19
6 C, 7 N, 9 F
(C) 14
6 C, 14 17
7 N, 9 F
(D) 14
6 C, 14 19
7 N, 9 F

9. A gas absorbs a photon of 355 nm and emits two wavelengths. If one of the emission is at 680
nm, the other is at
(A) 518 nm (B) 1035 nm (C) 325 nm (D) 743 nm

10. If the ionization energy for hydrogen is 13.6 eV then the ionization energy for He+ ion should be
(A) 13.6eV (B) 6.8eV (C) 54.4eV (D) 72.2 eV
11.  
The uncertainty in position of an electron m  9.1 10 28 gm moving with a velocity

3  10 cm / s accurate upto 0.001% will be

4

(A) 3.84 cm (B) 1.92 cm (C) 7.68 cm (D) 5.76 cm

12. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is (a0 is Bohr
radius)
h2 h2 h2 h2
(A) (B) (C) (D)
4 ma0
2 2
16  ma0
2 2
32 ma0
2 2
642ma20

13. The angular momentum of an electron of H–atom is proportional to

1 1
(A) r2 (B) (C) r (D)
r r
 ATOMIC STRUCTURE
CPP (REVISION)

14. The work function () of some metals is listed below. The number of metals which will show
photoelectric effect when light of 300 nm wavelength falls on the metal is :
Metal Li Na K Mg Cu Ag Fe Pt W
(ev) 2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75

(A) 4 (B) 5 (C)6 (D) 7

15. Suppose 3.1 x 10–18 J energy is needed by the interior of the human eye to see an object. How
many photon of light of  = 400 nm will be needed to see the object ? (h = 6.64 x 10–34 Js)
(A) 4 (B) 5 (C) 8 (D) 7

16. A dye absorbs a photon of wavelength  and re–emits the same energy into two photons of
wavelengths 1 and 2 respectively. The wavelength  is related with 1 and 2 as :
1   2 1 2 1222 1 2
(A)   (B)   (C)   (D)  
1 2 1   2 1   2  1  2 2
17. If 0 and  be the threshold wavelength and the wavelength of incident light, the velocity of
photo–electrons ejected from the metal surface is :
2h 2hc 2hc  0    2h  1 1 
(A)
m
 0    (B)
m
 0    (C) 
m  0 
 (D)   
m  0  
18. The angular momentum of an electron in a Bohr’s orbit of He+ is 3.1652 x 10–34 kg– m2/ sec. What
is the wave number in terms of Rydberg constant (R) of the spectral line emitted when an
electron falls from this level to the first excited state. [Use h = 6.626 x 10–34 J.s]
5R 3R 8R
(A) 3R (B) (C) (D)
9 4 9

19. Which of the following statement is correct.

(A) In hydrogen atom, energy of first excited state is –3.4 eV. Then, KE of same orbit of hydrogen
atom is + 3.4 ev.
(B) The work function for a metal is 4 eV. To emit a photo electron of zero velocity from the
surface of the metal, the wavelength of incident light should be 3100 A.
9RH
(C) The first emission in the atomic spectrum of hydrogen in the Balmer series a…. at cm 1
400
(D) All of these

20. If uncertainty in position and momentum are equal then uncertainty in velocity is
h h 1 h 1 h
(A) (B) (C) (D)
2  2m  m 2
Kn 2
21. Balmer gave an equation for wavelength of visible region of H-spectrum as   . The
n2  4
x
value of K in terms of Rydberg constant R is . Then the x + y is.
yR
22. What is the ratio of time periods  T1 / T2  in second orbit of hydrogen atom to fourth orbit of Be3
ion?
Difference between nth and  n  1 Bohr’s radius of H atom is equal to it’s  n  1
th th
23. Bohr’s
radius. The value of ‘n’ is
 ATOMIC STRUCTURE
CPP (REVISION)

24. A light source of wavelength  illuminates a metal and ejects photo-electrons with
K.E.max  1eV .

Another light source of wavelength , ejects photo-electrons from same metal with
2
K.E.max  4eV
Find the value of work function in eV?

25. How many of the following statements are correct

n3
(1) T 
z2
(2) According to plank’s quantum theory energy will be continuously emitted.
(3) If H–atom is exposed to radiation having 10.4 eV then the electron excites.
(4) According to Bohr’s theory radius, energy, velocity are quantized.

SOLUTIONS

1. D
kze2 3e2
Sol: P.E.  
r 4 0 r
2. B
v1  x
Sol:  1 x
v3  x   
3 3
3. A
nh
Sol: mvr 
2
5h 2.5h
 
2 
4. C
 [Link] 2 
 
KE  2r 
Sol:   1
TE  kze2 
 
 2r 
5. C
4
Sol: r2 Be3  0.529   0.529  r1H
  4
6. B
 z2 
Sol: En  13.6   2  eV / atom
n 
E2  E1 
  15.4
 E 4  E3 
7. C
 ATOMIC STRUCTURE
CPP (REVISION)

 n3 
Sol: T   2   T  n3
z 
T1 n13

T2 n32
8. A

9. D
1 1 1
Sol:  
 1  2
10. C
Sol: E  13.6  4  54.4 eV
 IE  54.4 eV

11. B
h
x 
4.mV
12. C
n2 h2  h2 ao
Sol: r  2 2 

z  4 mke  z
hz
 vn 
2a0n
1 h2 z 2
 KE  mv 2  2 2 2
2 8  ma0 n
h2
 KE 
322ma02
13. C

14. A

15. C
16. B
1 1 1 1   2
    1
 1  2  1 2
1 2

1   2
17. C
hv = hv0 + K.E
hc hc 1 1 1 1 
  mv 2  mv 2  hc   
 0 2 2   0 
2hc  0   
V  
m  0 

18. B
nh
mvr =  3.1652  1034  n  3
2
 ATOMIC STRUCTURE
CPP (REVISION)

1  1 1 1 5 5R
n2  3, n1 = 2 ;  4RH      4R 
  4 9   36 9

19. D
20. C

21. 5
22. 2

23. 4
24. 2
25. 2