AR Rahman school Grade 12 chemistry MCQ

[Link] is camphor in N2 gas an example of?

a) Solid in liquid solution. b) Liquid in gas solution

c) Solid in gas solution. d) Gas in gas solution

2. What is the observation on adding a solute crystal to a supersaturated solution?

a) It becomes a colloidal solution. b) The solute dissolves in the solution

c) The solution desaturates. d) The solute precipitates out of the solution

[Link] is the mole fraction of glycerin C3H5(OH)3 in a solution containing 33g of glycerin, 60g isopropyl
alcohol and rest water?

a) 0.359. b) 0.258. c) 0.205. d) 0.480

[Link] is the molarity of a 15 ml, 2 M aqueous solution when 285 ml of water is added to it?

a) 0.400 M. b) 0.100 M. c) 0.111 M. d) 0.105 M

[Link] of the following concentration determine techniques gives a more accurate value?

a) Molarity. b) Molality. c) Formality. d) Normality

6. In a saturated solution with endothermic dissolution, how does the concentration of dissolved solute
change with increasing then decreasing temperature?

a) Keeps increasing. b) Keeps decreasing

c) Increases and decreases. d)Decreases and increases

[Link] symbol is used to denote ‘molality’?

a) M. b) m c) M. d) n

8. What is the molality of a solution formed when 58.5g of NaCl is dissolved in 2000 mL of water?

a) 29.2500 m. b) 0.5000 m

c) 0.0005 m. d) 0.2925 m

9.. What is the molarity of 20% (w/v) H2SO4 solution?

a) 0.51 M. b) 1.02 M. c) 4.08 M. d) 2.04 M

10. What is a solution called when the concentration of the solute equals its solubility in the solvent?

a) Dilute. b) Saturated. c) Unsaturated. d) Supersaturated

[Link] of the following may be the most appropriate unit of expressing lead concentrations in
drinking water?

a) mg. b) mmole. c) ppm. d) ppb

[Link] a saturated solution with endothermic dissolution, how does the concentration of dissolved solute
change with increasing then decreasing temperature?

a) Keeps increasing. b) Keeps decreasing

c) Increases and decreases. d) Decreases and increases

[Link] of the following best describes the difficulty in breathing as one climbs to higher altitudes?

a) Henry’s law. b) Raoult’s law

c) Osmotic pressure. d) Relative lowering of atmospheric pressure

[Link], at 298 K water is the solvent, and Henry’s law constant for CO2 is 1.67 kbar and the constant of
argon is 40.3 kbar, which of the following statements is true?

a) Argon is more soluble than CO2. b) Argon is less soluble than CO2

c) Argon is insoluble in water. d) Argon and CO2 are equally soluble

[Link] of the following is not an example of an Ideal solution?

a) Benzene + Toluene. b) n-Hexane + n-Heptane

c) Ethyl alcohol + Water d) Ethyl bromide + Ethyl chloride

16. A solution which does not obey Raoult’s law is called a non-ideal solution.

a) True. b) False

[Link] of the following is false regarding Non-Ideal solutions?

a) They do not obey Raoult’s law. b) ΔVmixing ≠ 0

c) ΔHmixing = 0. d) They form azeotropes

18 . Which of the following is an example of a non-ideal solution showing positive deviation?

a) Acetone + Carbon disulphide. b) Chlorobenzene + Bromobenzene

c) Chloroform + Benzene. d) Acetone + Aniline

[Link] solutions do not form azeotropes.

a) True. b) False

20. Which of the following is not an example of a non-ideal solution showing negative deviation?

a) HNO3 + Water. b) HCl + Water

c) Acetic acid + Pyridine. d) Carbon tetrachloride + Toluene

[Link] are the properties arising due to varying concentrations of solute in a given solvent,
irrespective of the nature of solute with respect to the solvent?

a) Colligative properties. b) Intensive properties

c) Extensive properties. d) Solute properties

[Link] of the following is a colligative property?

a) Relative lowering of fluid pressure

b) Decrease in boiling point

c) Decrease in freezing point

d) Change in volume after mixing

23. Which law specifically governs the relative lowering of vapor pressures in solutions?

a) van’t Hoff law. b) Boyle’s law c) Raoult’s law. d) Amagat’s law

[Link] a non-volatile solute is added to a solvent what is the difference in vapor pressure expressed
as a faction of original vapor pressure equal to?

a) Mole fraction of solute in vapor phase

b) Mole fraction of solvent in vapor phase

c) Mole fraction of solute in liquid phase

d) Mole fraction of solvent in liquid phase

25 Considering the formation, breaking and strength of hydrogen bond, predict which
of the following mixtures will show a positive deviation from Raoult’s law?
(i) Methanol and acetone. (ii) Chloroform and acetone.
(iii) Nitric acid and water. (iv) Phenol and aniline.

26. Colligative properties depend on ____________.

(i) the nature of the solute particles dissolved in solution.
(ii) the number of solute particles in solution.
(iii) the physical properties of the solute particles dissolved in solution.
(iv) the nature of solvent particles.

27. Which of the following aqueous solutions should have the highest boiling point?
(i) 1.0 M NaOH (ii) 1.0 M Na2SO4. (iii) 1.0 M NH4NO3. (iv) 1.0 M KNO3

28.. The unit of ebulioscopic constant is _______________.

(i) K kg mol–1 or K(molality)-1. (ii) mol kg K–1 or K–1(molality)
(iii) kg mol–1 K–1 or K–1(molality)–1. (iv) K mol kg–1 or K(molality)

[Link] comparison to a 0.01 M solution of glucose, the depression in freezing point of a

0.01 M MgCl2 solution is _____________.

(i) the same (ii) about twice
(iii) about three times (iv) about six times

30.. An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels
because _____________.
(i) it gains water due to osmosis.
(ii) it loses water due to reverse osmosis.
(iii) it gains water due to reverse osmosis.
(iv) it loses water due to osmosis.

31. At a given temperature, osmotic pressure of a concentrated solution of a substance

_____________.
(i) is higher than that at a dilute solution.
(ii) is lower than that of a dilute solution.
(iii) is same as that of a dilute solution.
(iv) cannot be compared with osmotic pressure of dilute solution.

32. Which of the following statements is false?

(i) Two different solutions of sucrose of same molality prepared in different solvents will
have the same depression in freezing point.
(ii) The osmotic pressure of a solution is given by the equation π = CRT (where C is the molarity of the
solution).
(iii) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of barium
chloride, potassium chloride, acetic acid and sucrose is BaCl2>KCl> CH3COOH >
sucrose.

(iv) According to Raoult’s law, the vapour pressure exerted by a volatile component of a
solution is directly proportional to its mole fraction in the solution.

[Link] values of van’t Hoff factors for KCl, NaCl and K2SO4, respectively, are _____________.
(i) 2, 2 and 2 (ii) 2, 2 and 3 (iii) 1, 1 and 2 iv 1,1,4

34.