CENTRAL KERALA SAHODAYA

MODEL EXAMINATION 2023-2024

CLASS XII

CHEMISTRY [043]

ANSWER KEY

SECTION A

1
1 (b)1-methyl cyclohexene

1
2 (a) [Fe(C2O4)3]3¯

1
3 (c) Mostly amino acids have D-Configuration

1
4 (c) 6F

1
5 (b) phenol

6 (d) t = 4.606
1
K

(c) CoCl3.6NH3 1
7

8 (d) CH3CH2NH2 1

9 (a) P - (II) Q – (III) R – (IV) S – (I) 1

10 (b)IV > III > I > II 1

11 (d) 5.92 BM 1

12 (b) Etard reaction 1

1
13 A)
14 A) 1

15 D) 1

16 B) 1

+ p
17 (i) (Ti4 ) because of the losing 4 electron there is no unpaired

electrons [3d°4S°] 1+1

+ 2+
(ii) Cu gets oxidized to Cu which is more stable due to higher

H enthalpy hydration.

18 4-
(a) [Fe(CN)6] does not have unpaired electrons whereas
+ 1+1
[Fe(H2O)6]2 are of has unpaired electrons and absorb light

from visible region and radiates complementary colour.

(b) K2[Ni(CN)4]

19 Give reason
(a) Aniline is strong acidic medium changes in to anilium ion
+
NH3
O
Which is metadirecting ammonium salt.

1+1
(b) Ammonolysis has the disadvantage of yielding a mixture of
primary, secondary and tertiary amines and a quaternary
OR
+
N2 Cl¯
(a)
CH3CH2OH O +CH3CHO+N2+HCl
O

+
N2 Cl¯ F
(b)
O
HBF O +BF3+N2
20 K = 60/S
. [ ]
K= log
[ ]

Ro
.
60 = log Ro 16 2
.
60 = log16
.
t = X 1.2042

= 0.046 sec

21 (a) n-Butane < methoxymethane < propanal < Acetone < 1-propanol
2
(b) propanone < Acetone < propanal < Acetaldehyde

22 (a) A+2B → pdt

[ ] [ ]
= d

(b) Concentration of B three times 1+1+1

rate = K[A][B]²
rate = K[A][3B]²
rate = 9 times
(c) Both A and B doubled
rate = K[2A][2B]²
= 8 times

23 w2 x 1000
Tb = iKb 3
M2 x wi
Tb = Tb - T°b
2+
Mg SO4 Mg + SO42-
l = 2 (kb = 0.52 kkg/mol)
w2 = 4g w1 = 100g
M2 = 24+2x35.5
= 24+71 = 95g/mol
2x0.52x4x1000
Tb =
95x100
 4160
= = 0.437K
9500
Tb = Tb - T°b
0.437k = Tb-373.15
Tb = 373.15+0.437=373.587k

24 (a) Ionization Isomerism

i) [Co(NH3)5Co3]u pentaamminecarbanato cobalt-III
chloride
ii) [Co(NH3)5Cl]Co3 pentaammine chlorido cobalt-III
carbonate
2+1
(b) Double salt. No: of ions = 5
2+ 2- + 2-
FeSO4(NH4)2SO46H2O  Fe +SO4 +2NH4 +SO4 +6H2O

OR

(a) d5 configuration eg 0 < p

+2g

E-C +2g3eg2
(b) Fe(CN)63¯ because Fe is in +3 oxidation state. Higher the
oxidation state more will be the stability
(c)
Cl 2-
Cl 2-

Cl
OX Cr OX
OX Cr

Cl
OX

Trans
Cis
25 A aq feCl3 Characteristic violet colour
CO2+NaOH acidification C acetyl
A B D
400 K Chloride
3
A is Phenol Fe
0 3
OH
Neutral FeCl3 O
O

ONa OH COCH3
OH
+ COOH
CO2+NaOH COOH H COOH O
O O O
400 K

26 i) a) It is due to smaller size, higher charge and availability of d-

orbitals of suitable energy
b) Chromium consist of 6 unpaired electrons, more 1+1+1
interatomic metallic bonding. While Hg only paired electrons
ii) 2MnO4¯ + 16H+ +10I¯ 2Mn2+ + 8H2O +5I2

27 (a) A – strong electrolyte

B – Weak electrolyte
(b) A on extrapolations gives limitimg molar conductivity (Λ°m)
Whereas extrapolation of B is not possible due to step curve.
(Refer text)
(c) Anode  O2 gas
1+1+1
Cathode  H2 gas
(Refer text)

28
(a) A O CONH2

1.5+1.5
[B] O NH2

[C] O NH(CH3)
 (b) [A] CH3CH2CN

[B] CH3-CH2 NH2

[C] CH3-CH2CH2OH

29 (a) Exothermic because force of attraction between gas and

solvent increases on dissolution
(b) kH value increases with increase in temperature. Helium is
least soluble because its kH is highest
(c) p = kH XN2
pN2 .
XN2 = =
kH .
¯5
= 1.29 x 10
nN2
XN2 =
nN2 +nH2 O
nN2
XN2 =
nN2 + 55.5
nN2
XN2 =
nH2 O
1+1+2
¯5
XN2 = XN2 x NH2O = 1.29 x 10 x 55.5

= 7.16x10¯4moles
= 0.716 millimole
OR

0.195mmeans 0.195 moles of H2S is dissolved in 1kg of H2O.

nH2 S
XH2S =
nH2 S+nH2 O
0.195
= = 0.0035
0.195+55.55
PH2S at STP = 0.987bar
PH2S = KH x YH2S
PH2 S 0.987
KH = = = 282bar
xH2 S 0.0035
30 (a) Br MgBr

O dyether
+ Mg O

(b)
i) CH2 = CH – CH2 Cl (Allyl carbocation is stabilized by
resonance)
ii) (CH3)3 C – Cl (3° carbocation is more stable)
(c)
Acetone
i) CH3 CH2 – CH2 – CH2 Cl + NaI

Peroxide
ii) CH3- CH2 – CH= CH2 + HBr CH3 CH2 – CH2 – CH2Br

Acetone
CH3 - CH2 – CH2 - CH2Br+NaI CH3 - CH2 – CH2I
OR

Ethanol
i) CH3 – CH – CH3 + KOH CH3 – CH = CH2 + KBr+H2O
Propene
ii) Cl Cl
anyAlCl3 1+1+2
O + CH3COCl O + HCl

CoCH3

31
(a) CH3 - CH2 – C - CH2 – CH2 – CH3 + 2CH3CH2OH
CH2 - CH2

CH3 – CH2 C CH2 – CH2 – CH3

(b) Compound A is CH3 - CH2 – C – CH2 – CH3 (PENTAN -3-ONE)

clemmensen reduction
zn−Hg
CH3 - CH2 – C – CH2 – CH3 1+2+2
HCl
CH3 - CH2 – CH2 – CH2 - CH3 + H2O
 CH3 - CH2 – C – CH2 – CH3 + NaOI  No reaction

+
CH3 - CH2 – C – CH2 – CH3 +[Ag(NH3)2]  No reaction
(c) Convert the following
i) Benzene to p-nitrobenzoic acid

CH3 CH3 COOH

CH3Cl Cen HNO3 KNno4
O O O O
anlyAlCl3 Cen H2SO4 KoH/
NO2 NO2

ii) Propanoic acid to acetic acid

NH3
CH3 – CH2 – CO2OH CH3-CH2-CONH2 KOH Br2

[ ]
NaNO2/HCl
CH3 – COOH< CH3 – CH2OH CH3-CH2 NH2
0°C

OR
d) Illustrate the following
CHO
i) CH3 CH(OCrOHCl2)2 + H3O
CS2 O
+ CrO2 Cl2 O
O

CHO
Co/HCl
ii) O O
anhyAlCl3.CuCl2

iii) HCHO + Con NaoH  HCOONa + CH3OH

e) Assign the reason for the following

i) The lone pair of electrons on NH2 attached to carbonyl
gip is involved in resonance and hence not available
 for the reaction

oo
H2N-NH C NH2
ii) Benzoic acid do not undergo friedel crafts reaction
because the carboxyl group is deactivating and the
catalyst aluminium chloride [Lewis acid] gets bonded
to the carboxyl group

32 .
(a) Ecell = E°cell – log
[Al3+]
.
Ecell = 2 – log
[Cu2+]3

[0.01]2
.
Ecell = 2 – log
3
[0.01]
2
. 1x10¯ 3+1+1
=2– log 6
1x10¯

.
2– log10+4
.
2– 4 log 10
.
=2– x4
.
x4
.
x 4 2 = 7.96V

(b) Mercury will always potential remains constant because the

overall reaction does not involve any ion in solution whose
concentration can change during its life time.

(c) 38% solution of sulphuric acid is used as electrolyte

OR
 (d) When direct current is passed, it changes the composition of
the solution .
(e) Amount of nickel deposited
W = ZIt
2+
Ni(NO3)2  Ni + 2NO3¯
.
W= x 5x20x60

= = 1.82g

(f) Reactivity decreases as electrode potential increase

Decreasing order of reactivity
-1.66V > -0.14V > + 0.34V > + 0.80V

33 (a) Saccharic acid

(b) Sugar, base and phosphate
(c) Guanine and cytosine
(d) Hydrogen bond, disulphide linkages Van der Waals and
electrostatic forces of attraction
(e) RNA helps in protein synthesis
5x1=5
(f) It indicate the absence of free CHO group
(g) During denaturation secondary and tertiary structures are
destroyed