Set-I 10.

(c) Among the given options, ROT is the strongest

(a) The specific sequence in which various amino base as its conjugate acid, i.e. ROHis the weakest
acids are linked with each other to form a acid as compare to other conjugate acid
polypeptide, is called its primary structure.
(a) The correct name of the given reaction is
Sandmeyers reaction.
i.e. CeHOH HOH and
Oon
a () Among the given alkenes, (CH,),C=CH, will
produce tertiary butyl alcohol on acid catalysed 11. (d) On dilution, conductivity decreases whereas
hydration. molar conductivity increases on dilution. This can
be explained as follows.
ÇH3 ÇH,
On dilution, generally the number of ions present
(CH),C=CH 1cH--CH,HCHyCH, per unit volume carrying the current tends to
decrease, which results in a decrease in the
H H conductivity of the electrolytic solution.
Whereas, on dilution the total numnber of ions
ÇH3 increases due to increase in the degree of
-HCH--CH,
OH
dissociation. Hence, molar conductance increases.
12. (b) van't Hoff factor for Na,SO,-10H,0solution
4. (c) Auto-oxidation of chloroform in air and light is 3.
produces a poisonous gas known as phosgene. Na,SO4-10H,02Na+ sO+10H,0
The reaction involved is given as
Light, 2COCl, + 2 HCI .:. Total number of ions =2 + 1=3
2CHCl3 + Oz Air 13. (a) Both (A) and (R) are true and (R) is the correct
Chloroform Oxygen Phosgene Hydrochloric
acid
explanation of the (A).
5. (a) Formationof interstitial compound makes the 14. (a) Both (A) and (R) are true and (R) is the correct
transition metal more hard. explanation of the (A).
6. (c) Isotonic solutions are those solutions which 15. (c) SNl reaction proceeds with the formation of
have the same osmotic pressure across a carbocation, while SE2 reaction proceeds through
semipermeable membrane at a given temperature. the transition state formation.
7. (6) H,-O, fuel cellwas used in Apollospace Hence, Assertion (A) is true, but Reason (R) is
programme. false.
8. (b) As, rate (r) =k [a]" ...(i) 16. (d) pnitrophenol is more acidic than
According to question, pmethoxyphenol. This is because the nitro group
16 r= k [4a]" ...(ii) is an electron-withdrawing group, which stabilises
From Eqs. (i) and (ii), the phenoxide ion formed after loosing a protor,
thereby, making it easier for the phenol to donate
a proton and thus increasing its acidity.
Hence, Assertion (A) is false but Reason (R) is
16 =4" true.
n =2 17. (a) The Kohlrausch law of independent
9. (a) A chiralatom is acarbon atom that is attached migration of ions state that "limiting molar
to four differernt types of atoms or group of atoms. conductivity of an electrode isthe sum of the
Ihus, carbon atom in case of I, II and III are chiral individual contribution of the cation and the
in nature. anion of the electrolyte.
 (b) The Faraday's first law states that "the (b) Benzene diazonium chloride when
amount of chemical reaction occuring at any with KI form iodobenzene. The
involved is as follows
treate
reaction
electrode by passing current is directly
proportional to the quantity of electricity N=NCI
passed through the electrolyte".
KI
18. Monosaccharides carbohydrate are those which + KCI+ N,t
are composed of single unit of saccharide and
Benzene diazoniom lodobenzene
cannot be hydrolysed further to give simple unit of chloride
polyhydroxy aldehyde or ketone. Among the
given compounds, galactose and glucose are 20. For a first order reaction, we have
monosaccharides. 2.303 [Alo
Disaccharides are those which on hydrolysis with t= log [AJ
k
dilute acids or enzymes give twomolecules of
monosaccharides. When reaction is 99% complete,
99a
Thus, among the given compounds, lactose and [A]= a- 100 =0.01a
maltose are disaccharides.
2303 2303
19. (a) Nitrobenzene to aniline x 2
k log 0.01a k
NO; NH2 When reaction is 90%% complete,
90a
Sn HCI [A] = a 0.1a
+3H2 or Fe +HCI +2H,0 100
Aniline 2303
Nitrobenzene
t9o =
k log 0.1a
(b) Aniline to phenol 2303
t9Í = K
NH,
By dividing equations (i) by (ii), we get
273-278 K
{O]-NaNO,+2HCI -NaCl
-H,0 too
=2 tgg 2t9o
Aniline Benzene
diazonium
chloride
21. Given, for 0.2 mol L' KCI solution,
Conductivity, K =0.0248 S cm
OH
Resistance, R =200 2

H,O,O)+NT+HCI
Phenol
Cellconstant Conductivity xResistance
=0.0248 × 2000 = 4.96 cm

Or For 0.05 mol L KCIsolution,

Resistance =620 2,
(a) Test for dimethyl amine and ethanamine
Ethanamine, being primary amine, on heating Cellconstant =496 cm1
with chloroform and ethanolic potassium Cell constant
Conductivity =
hydroxide form isocyanide which have foul Resistance
Smell whereas dimethyl does not give this 4.96 =0.008Qcm-1
kind of foul smell. 620
CH,CH,NH,+ CHCH +3KOH-4 Conductivityx 1000
Molar conductivity =
Ethanamine Molarity
CH,CH,NC + 3KCl+ 3H,o 0.008 W-x 1000 cmL
Ethyl isocyanide
0.05 mmol L!
(CH,hNH + CHCl, +3KOH4 No foul snell
Dimethylamine =160 Q1 cm2 mol
2. (a) [Co(NH),CI(NO,)JCl
Tetraamninechloridonitro cobalt(II) chloride 25. Given, E-105 V., log 10 1
(b) [Ni(NH,)%JCl, = Hexaaminenickel(I) chloride Cell reaction,
() Ki[Cr(C;0)3] Potassiumtrioxalatochromate Ni(s) + 2Ag (001 M) ’NI (01 M)+ 2Ag(s)
(II) We know that,
(d)[Co(en), Br, ] Dibromidobis (ethylene 0.0591 (NI?]
Eell E° log
diamine)cobalt (II)ion 2

OMgBr 105
o0591 1og (o91?
2
(0.1)
3. (a) CH,--C CH, H 105
Ethanal 00295 log (1000)
CH, 105 -0.089 0961 V 096 V
26. (a) As Ag--CN is mainly covalent in nature and
OH only electron pair of nitrogen is availablefor
Br
bond formation. As a resuít of which, alkyl
HO,CH,-C-H+ Mg isocyanides are the chief products formed
CH,
Propan -2-ol
OH when haloalkanes react with AgCN.
(b) Allyi chloride compounds are nore reactive
towards Syi reaction because they form stable
(b) CH;CH,CH = CH,+ H,0
But-1ene
H,so, carbocation which is resonance stabilised.
(c) Haloarenes are chemically less reactive
CHyCHaçH-CH, OH
towards nucleophilic substitution reactions as
in haloarenes, the lone pair of electron on
halogen atom are in conjugation with
Butan-2-o1 T-electrons of the ring. As a result of which,
(c) OH OH
C-X bond acquire partial double bond
Br Br character. Thus, the bond cleavage is difficult.
+3Br2{aq) +3HBr Also, the sp² hybridised C-atom being more
Phenol
electronegative, hold the electron pair of the
Br
bondmore tightly. As a result of which, the
bond become shorter and difficult to break.
2,4,6-tribromophenol
(white Ppt) 27. Given, T, =300 K, T, -320 K kz/ k1 =4
24. (ao R=8.314 JK mol, og 4 =060

2{Ag(NH,)l'OH + 2Agl +H,0+4NH;

Silver
: log k1 E
2303 R TËT2 T;-T1
HO
(Mirror)
E |320- 300
log 4 - 19.15
=

300 × 320
0.60= E 20
(b) CHs CH, 191.596000

NaOICHcCc_oNa
+CHI3
Yellow 0.60× 1915 ×96000
H C-CH3 H
PPt. 20
=55152 J mol or 55.15 kj mol
(c) CN 28. As it is given that compound X on reacting witn
-OH CGH,SO2Ci give a solid product which is insoluble
NaCN/HCI in alkali, this shows that there is pohCrogen
H
COOH
attached to N in the product
Thus, the compound X is ascparndary amine. The
reaction involved is as follog
 CH-NC,Hs+ CH,SO,CI neighbouring d-block elemernts
H
due to
stability of half-filled orbitals of Mn+
(X) () Greater is the number of unpaired
CH,-NSO,CHs
,Hs
stronger is the resultant bonding and electron
greater is the enthalpy of atomisation. hena
Nethyl-N-methylbenzene sulphonamide In 3d series elements, Zn has the lowest
29. (a) When a ligand is bonded through a two enthalpy of atomisation, it is due to the
of unpaired electrons in ns and (n-1) dab
(d) When sodium chromateofis acidified thanshei
different atoms, it is said to be ambidendate
ligand, eg. NO,.SCN,CN.
orange colour solution sodium
(b) (Co(NH;);Cl|SO, and [Co(NH;),SO, 1Cl shows
ionisation isomerism.
is formed. dichrom
This tvpe of isomerism arises when 2Na,CrO,+2H* Na,Cr,O,
Sodium dichromate +2Na' +R
compounds give different ions in the (Orange)
solution although they have same Zn, Hg and Cd have completely filled
(e) d-orbitals
composition. in the ground state as well as in A
(c) Chelate effect signify the stabilisation of
common oxidation states. Thus, formation.
coordination compounds due to the formation strong metallic bond is not possible.
of metal chelates. () Permanganate titration is not carried out in
The chelating ligands form more stable presence of HCIbecause if HCl is used, the
complexes than the unidentate analogs oxygen produced from the reaction of KMo
because when chelation occurs, entropy and HCl is partly utilised in oxidising HC
Clb, which itself acts as an oxidising agent &
decreases and the process becomes more partially oxidises the reducing agent.
favourable and form a ring complexes which
is known as chelate ring. (g) In lower oxidation states, transition metals
behave like metals and metal oxides are bas
Or
in nature. Thus, in lower oxidation states,
() In complex Nas[Cr(C,O)%] the coordination transition metal oxides are basic.
number of Cr is6 as oxalate isa bidentate As the oxidation state increases, its
metallic
character decreases due to decrease in size,
ligand. or more
metallic
Let, the oxidåtion number ofCr be x. thus, it becomes less
3+x+3(-2) =0 non-metallic. Oxides of a non-metal may be
X=+3 acidic or neutral.
transition
Thus, oxidation state of Cr
be +3. Thus, in higher oxidation states,
vitamin B, is pyridoxine. metal oxides are amphoteric or acidic.
30. (a) Another name of = 1.0kg
(b) Vitamin K 32. (a) Given, Amountof waterglycol 62 g mol
A cause xerophthalmia. Molar mass of ethylene
(c) Deficiency of vitamin
of vitamin A are Fish
liver oil K, for water = 1.86 K kg mol
The twO sOurces Lowering of freezing point of the solution
andarrots. -2.8°C
Or
Mass of solute (w) =?
soluble vitaminand is
(c) Vitamin C isa water
urine. Thus, it can't be AT, =0 -(-28) - 2.8°C =2.8
K
readily excreted in Molality,
stored in our body. Weight of solute
is caused by x 1000
Scurvy (bleeding gumn) disease m= Molecular mass of solute
vitámin.
the deficiency of this Mass of solvent (g)
the outer electronic
31. (a) Ce(III) ion have 5d'6s which can easily lose
configuration 4fl w/62 x 1000
acquire the
the electron from 4f orbital to
m=
1000 62
and fornm
configuration, i.e. 4f°5d'6s
stable Now, AT, = Kf x m
Ce(IV) ion. 2.8 = 186 x
value is -1.18 V, which is 62
(b)The E (Mn / Mn)compared to other
highly negative as
 62 x 28 the
93.3 93g group is directly attached totnIHErseg
186
copund is ortho dinstatituted benEre
(b) A mixture of ethanol and acetone shows (a) Therefore accordirg to atne intomaticn the
positive deviation because in this case conpound (A) is 2-ethy ltTZaidet1yde
ethanol-acetone interactions are weaker than (b) (i) CHÌ 2Adirsttni
pure ethanol-ethanol andacetone-acetone hydrazre
interactions.
Due to this, vapour pressure increases whih CHCH
results in positive deviation. 2 ethryitenzaidetyde
Or
(a) Given,
Boiling point of pure water - 99 68 C
Elevation in boiling point, (AT,)- 100 -968 CHCH
-0.32C 24 P detivatfi ve
-0.32 K (i1) CHO Toien s
K 0.52 K kg moi
Molar mass of sucrose -342 g mol CHCH, CHCH,
A
Amount of water (WA) = 500 g 2-ethryhzte
We know that, AT, = Ky x molality 2Agi 4H, 2HO
Molality (c)
Mass of solute x1 000 CHO CHOH
Molar mass of solutex Mass of solvent (g) "Conc. NaOH A,
Let, x g of suCrose to be added, CHCH, CHCHy
Ix 1O00
.Molality = 342 x 500 171

Putting the value in Eq. (1), we get CHCH,

0.32 -0.52 x Or

0.32 171
171
(a) (i) The a-hydrogens of aldehydes and ketones
-10523 g are acidic in nature, this is because of the
0.52 strong electron withdrawing nature of the
Therefore, 105.23 g of sucrose must be added. carbonyl groups and resonarnce stabilisation of
(b) Henry's law states that, at a constant the conjugate base in respectíve case.
temperature, the solubility of a gas in a liquid
is directly proportional to the partial pressure
of the gas present above the surface of iquid
or solution. Aldehyde Ktone
One of the application of Henry's law is in (ii) Oxidation of aldehydes is easier thar ketones
the production of carbonated beverage: because of the presence of the hydrogen atom
To increase the solubility of CO, in soft drinks attached to the C=0double bond in the
and soda water, the bottle is sealed under hígh aidehyde, which is not present in ketone.
pressure. Thus, the presence of that hydrogen atom
a3. Accordingto given information, the organic makes the aldehydes very easy to oxidise.
compound (A) with moiecular formula CgH (b) (i)The decreasing order of reactivity towards
form 2-4 DNP derivative and also reduces tollen's nucleophílic addition reaction is
reagent. Hence, the compound (A) is an aldehyde. propanal >acetone > benzaldehyde.
Also, the compound (A) undergo Cannizzaro (ii)The increasing order of boiling point ís
reaction hence, it does not contains an a-H-atom. propane < dimethyiether < propanal <
On vigorous oxidation, it gives ethanol.
1,2-benzenedicarboxylic acid. That means, --CIO
28
2
distinguish between benzoicacid and
(c) Test to
benzaldehyde
NaHCO3
Benzoic acid being an acid reacts with
effervescence due to the
solution toproduce brisk
does not
evolution of CO, while benzaldehyde
give this test.
CGH;COOH+ NaHCO,-C&HCOO Nat
+CO,T+ H ,
NaHCO, solution
CeHsCHO ’ No effervescence

Set-I|