SOLUTIONS:2
Date: 3rd Jan 2025
1. The increase in boiling point of a solution containing 0.6 g urea in 200 g water is Find
the molal elevation constant.
a) 10 K kg b) 10 K g c) 10 K kg mol d) 1.0 K kg
2. Which is correct representation of phase rule?
a)
b)
c)
d) None of these
3. 40% by weight solution will contain how much mass of the solute in 1L solution, density
of the solution is 1.2 g/mL?
a) 480 g b) 48 g c) 38 g d) 380 g
4. 20 g of binary electrolyte (mol. wt. =100) are dissolved in 500 g of water. The depression
in freezing point of the solution is ( the degree of ionisation of the
electrolyte is
a) 0% b) 100% c) 75% d) 50%
5. What is the molality of pure water?
a) 1 b) 18 c) 55.5 d) None of these
6. Iodine was added to a system of water and . The concentrations of iodine in water and
were found to be respectively. The ratio will not change only if :
a) More iodine is added
b) More water is added
c) More is added
d) The temperature is changed
7. Which of the following associated with isotonic solutions is not correct?
a) They will have the same osmotic pressure
b) They will have the same vapour pressure
c) They have same weight concentrations
d) Osmosis does not take place when the two solutions are separated by a semipermeable
membrane
8. The freezing point (in of a solution containing 0.1 g of (mol.wt.329) in 100 g
of water is : ( )
a) b) c) d)
9. The Henry’s law constant for the solubility of gas in water at 298 K is . The mole
fraction of In air is 0.8 The number of moles of from air dissolved in 10 moles of
water of 298 K and 5 atm pressure is
a) b) c) d)
10. Van’t Hoff factor more than unity indicates that the solute in solution has
a) Dissociated b) Associated c) Both (a) and (b) d) Cannot say
anything
Assertion - Reasoning Type
This section contain(s) 0 questions numbered 1 to 0. Each question contains STATEMENT
1(Assertion) and STATEMENT 2(Reason). Each question has the 4 choices (a), (b), (c) and (d)
out of which ONLY ONE is correct.
a) Statement 1 is True, Statement 2 is True; Statement 2 is correct explanation for Statement
1
b) Statement 1 is True, Statement 2 is True; Statement 2 is not correct explanation for
Statement 1
c) Statement 1 is True, Statement 2 is False
d) Statement 1 is False, Statement 2 is True
11
Statement 1: If a liquid solute more volatile than the solvent is added to the solvent the
vapour pressure of the solution may increase ie Ps>P0.
Statement 2: In presence of a more volatile liquid solute only the solute will form the
vapour and solvent will not.
12
Statement 1: The molecular weight of acetic acid determined by depression in freezing
point method in benzene and water was found to be different.
Statement 2: Water is polar and benzene is non polar.
13. Statement - I. Addition of a non-volatile solute causes a depression in vapour pressure.
Statement - II. Vapour pressure of a solution is directly proportional to mole fraction of
solvent.
14. Statement - I. 0.02 M solutions of urea and sucrose will freeze at same temperature.
Statement - II. Freezing point of a solution is inversely proportional to the concentration
of solution.
15. Statement - I. For isotonic solutions C1 = C2
Statement - II. For isotonic solutions p1 = p2
16. Statement - I. Benzene-toluene mixture forms ideal solution at low concentrations.
Statement - II. Components with structural similarity forms ideal solution in general.
17. Statement - I. Dissolution of sulphuric acid in water gives a solution which shows
negative deviation.
Statement - II. The solutions which have same vapour pressure at a given temperature are
called isotonic solutions.
18. Statement - I. Greater the molal depression constant of the solvent used less is the
freezing point of the solution.
Statement - II. Depression in freezing point depends upon the nature of the solvent.
19. Statement - I. Vant Hoff factor for electrolytes is always greater than unity.
Statement - II. The no. of particles increases in solution due to electrolytic dissociation.
20. Statement - I. The vapour pressure of 0.1 M sugar solution is more than that of 0.1 M
potassium chloride solution.
Statement - II. Lowering of vapour pressure is directly proportional to the no. of species
present in the solution.
KEYS AND SOLUTIONS
1. (a)
no. of moles of solute
Molality, m
weight of solution in kg
=
= 0.05
[ ]
Given,
Or 0.05 =
2. (b)
This relation is equation for Gibbs phase rule for heterogeneous systems.
3. (a)
Molarity =
where, M = molecular weight of the solute
Molarity = …(i)
Molarity = …(ii)
From Eqs. (i)and(ii)
Weight of solute = 480 g
4. (a)
0.74=
m=100
Actual molecular mass =100
The degree of ionisation of the electrolyte is 0% .
5. (c)
Molality is defined as the number of moles per 1000 g of solvent. Molality of water =
= 55.5m
6. (a)
For a given amount of solute in two solvents,
7. (c)
The solutions having the same osmatic pressure are called isotonic solution. They have
same weight concentrations
8. (a)
Total no. of particles furnished by
,
Now
9. a)
mole-fraction
In 10 mole solubility is
10. (a)
van’t Hoff factor greater than 1 means observed value is greater than calculated value
which is so when the solute dissociates.
11. (c)
Both solute and solvent will from the vapour but vapour phase will become richer in
more volatile component.
12. (a)
In benzene acetic dimerises but in water it does not this is because benzene is non polar
where as water is polar. Hence, moleculard mass determined by depression in freezing
point method comes out to be different.
13.[A]
14.[B]
15.[D]
16.[A]
17.[C]
18.[A]
19.[A]
20.[D]
