DEV Institute, Gandhinagar

Chapters : 1 to 5 Std 12 : Chemistry Date : 20/02/25

Total Marks : 50 one shot Time : 1 Hour
//X Section A
• Write the answer of the following questions. [Each carries 1 Mark] [65]
1. Write and explain Henry’s law. Also write its application.
2. Derive an equation for solution which shows relation between total pressure and mole fraction of
volatile solute and volatile solvent and explain it by plotting graph.
3. What is azeotropes ? Explain their types.
4. What is osmotic pressure ? Explain and derive equation.
5. Explain reverse osmosis and purification of water.
6. How many mL of 0.1 M HCl are required to react completely with 1 g mixture of Na2CO3 and
NaHCO3 containing equimolar amounts of both ?
7. An antifreeze solution is prepared from 222.6 g of ethylene glycol (C2H6O2) and 200 g of water.
Calculate the molality of the solution. If the density of the solution is 1.072 g mL–1, then what shall
be the molarity of the solution ?
8. A sample of drinking water was found to be severely contaminated with chloroform (CHCl3 )
supposed to be a carcinogen. The level of contamination was 15 ppm (by mass) :
(i) Express this in percent by mass.
(ii) Determine the molality of chloroform in the water sample.
9. Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid
components are 105.2 kPa and 46.8 kPa respectively. What will be the vapour pressure of a mixture
of 26.0 g of heptane and 35 g of octane ?
10. Two elements A and B form compounds having formula AB2 and AB4 . When dissolved in 20 g of
benzene (C6H6), 1 g of AB2 lowers the freezing point by 2.3 K whereas 1.0 g of AB4 lowers it by 1.3 K.
The molar depression constant for benzene is 5.1 K kg mol–1. Calculate atomic masses of A and B.
11. Calculate the depression in the freezing point of water when 10g of CH3CH2CHCl COOH is added
to 250g of water. Ka = 1.4 ´ 10–3, Kf = 1.86 K kg mol–1.
12. 100 g of liquid A (molar mass 140 g mol–1 ) was dissolved in 1000 g of liquid B (molar mass
180 g mol–1). The vapour pressure of pure liquid B was found to be 500 torr. Calculate the vapour
pressure of pure liquid A and its vapour pressure in the solution if the total vapour pressure of the
solution is 475 Torr.
13. Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure
of pure benzene and toluene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. Calculate
the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of toluene.
14. Give chemical reaction and its potential by drawing labelled diagram of Daniell cell. Also give
primary information indicating which type of cell it is ?
15. Write a note on standard hydrogen electrode.
16. Derive Nernst equation for calculating Ecell of Nernst equation and write the effect on Ecell when
there is change in concentration of Zn2+ and Cu2+.
17. Write a note on Kohlrausch law of independent migration of ions and limiting molar conductivity
(Lºm ) of strong electrolyte.
18. ) Give note on dry cell.
19. Write a note on mercury cell (Zn – Hg).
20. Write a note on lead storage cell (battery).
21. Write a note on Ni – Cd cell.

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22. Write a note on hydrogen - oxygen fuel cell.
23. Write a note on corrosion of iron.
24. Write the Nernst equation and emf of the following cells at 298 K :
(i) Mg(s) | Mg2+ (0.001 M) || Cu2+ (0.0001 M) | Cu(s)
(ii) Fe(s) | Fe2+ (0.001 M) || H+ (1 M) | H2(g)(1 bar) | Pt(s)
(iii) Sn(s) | Sn2+ (0.050 M) || H+ (0.020 M) | H2(g) (1 bar) | Pt(s)
(iv) Pt(s) | Br– (0.010 M) | Br2(l) || H+ (0.030 M) | H2(g) (1 bar) | Pt(s)
25. The resistance of a conductivity cell containing 0.001 M KCl solution at 298 K is 1500 W. What is the
cell constant if conductivity of 0.001 M KCl solution at 298 K is 0.146 ´ 10–3 S cm–1.
26. Conductivity of 0.00241 M acetic acid is 7.896 ´ 10–5 S cm–1. Calculate its molar conductivity and if Lom
for acetic acid is 390.5 S cm2 mol–1, what is its dissociation constant ?
27. A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for
20 minutes. What mass of Ni is deposited at the cathode ?
28. Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4 respectively are
connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver
deposited at the cathode of cell B. How long did the current flow ? What mass of copper and zinc
were deposited ?
29. What is zero order reaction ? Determine the integrated rate equations for zero order reaction R ® P.
30. What is first order reaction ? Determine the integrated rate equation for first order reaction R ® P.
31. Explain pseudo first order reaction by giving example.
æN ö
32. The relation between mole fraction ç E ÷ and temperature is explain by Boltzmann and Maxwell
è NT ø
graph.
33. Explain : How the value of activation energy is dermine on the base of Arrhenius equation ?
34. The following results have been obtained during the kinetic studies of the reaction :
2A + B ® C + D
Experiment [A]/ [B]/ Initial rate of
mol L–1 mol L–1 formation of
D/mol L–1 min–1
I 0.1 0.1 6.0 × 10–3
II 0.3 0.2 7.2 × 10–2
III 0.3 0.4 2.88 × 10–1
IV 0.4 0.1 2.40 × 10–2
Determine the rate law and the rate constant for the reaction.
35. The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had
only 80% of the 14C found in a living tree. Estimate the age of the sample.
36. The rate constant for a first order reaction is 60 s–1. How much time will it take to reduce the initial
1 th
concentration of the reactant to its value ?
16
37. During nuclear explosion, one of the products is 90Sr with half-life of 28.1 years. If 1 mg of 90Sr was
absorbed in the bones of a newly born baby instead of calcium, how much of it will remain after
10 years and 60 years if it is not lost metabolically.
38. For a first order reaction, show that time required for 99% completion is twice the time required for
the completion of 90% of reaction.
39. The following data were obtained during the first order thermal decomposition of SO2Cl2 at a
constant volume. SO2Cl2(g) ® SO2(g) + Cl2(g)

Experiment Time/s–1 Total pressure/atm

1 0 Wish You - All The Best
0.5
2 100 0.6
 The following data were obtained during the first order thermal decomposition of SO2Cl2 at a
constant volume. SO2Cl2(g) ® SO2(g) + Cl2(g)

Experiment Time/s–1 Total pressure/atm

1 0 0.5
2 100 0.6

Calculate the rate of the reaction when total pressure is 0.65 atm.
40. Write a note on interstitial compounds.
41. Write a note on alloys.
42. Give preparation of potassium dichromate and state its uses.
43. Give the structures of chromate and dichromate ions. How chromates and dichromates can be inter
converted ?
44. Give the chemical reactions showing oxidizing nature of potassium dichromate.
45. Give preparation of potassium permanganate.
46. State physical properties of potassium permanganate and state its uses.
47. Explain structures of manganate and permanganate ions.
48. Discuss chemical properties of potassium permanganate.
49. Give chemical reactions showing oxidizing character of KMnO4.
50. Explain the lanthanoid contraction.
51. Enlist the main postulates of Werner’s theory.
52. What are isomers ? State the types of isomerism.
53. Explain different types of structural isomerism.
54. Explain geometrical isomerism in four coordinated compounds.
55. Explain geometrical isomerism in six coordinated complex compounds.
56. Explain optical isomerism in six-coordinated complex compounds.
57. State the limitations of Werner’s coordination theory.
58. On the basis on valence bond theory discuss the geometrical shapes and magnetic properties of the
following 4-coordinated complexes :
(i) [NiCl 4 ]2– (ii) [Ni(CN)4]2–
(iii) [Ni(CO)4 ] (iv) MnO–4
59. On the basis of valence bond theory, discuss the geometrical shapes and magnetic properties of
following six coordinated complex compounds :
(i) [Fe(CN)6]3– (iv) [Co(NH3)6]3+
(ii) [Fe(CN)6]4– (v) [CoF6]3–
(iii) [Fe(H2O)6]3+
60. State the limitations of valence bond theory.
61. Explain crystal field splitting in octahedral complexes.

L
L L
M M M
L L
Energy L

z dx2–y2 dz2 eg
y 3/5Do
x Do
2/5Do
Metal dxydxzdyz t2g
d-orbitals

dx2–y2 dz2 dxydxzdyz Average energy

of the d-orbitals in
Free metal ion spherical crystal field

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62. Explain crystal field splitting in tetrahedral complexes.
dxy dyz dxz
t2
Energy 2D
t
5
Dt
3D
5 t
e
dx2–y2 dz2
d-orbitals Average energy
free ion of the d-orbitals in
spherical crystal field
63. Explain colour in coordination compounds.
64. State the limitations of crystal field theory (CFT).
65. What are metal carbonyls ? Give examples.

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 DEV Institute, Gandhinagar
Chapters : 1 to 5 Std 12 : Chemistry Date : 20/02/25
Total Marks : 50 one shot Time : 1 Hour
//X Section A
• Write the answer of the following questions. [Each carries 1 Mark] [65]
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