Safety Data Sheet FINO GmbH

according to UK REACH Regulation

FINOCOLL V 40 Instant Adhesive

Revision date: 31.07.2024 19981 / 19983 Page 1 of 11

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

FINOCOLL V 40 Instant Adhesive

19981 / 19983

Further trade names

ETHYL CYANOACRYLATE
Product group: Carbonsäureester
CAS No: 7085-85-0
Index No: 607-236-00-9
EC No: 230-391-5
UFI: 1NAS-91HW-M00Y-CCE8
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Excellently suitable for repairs of fractured teeth, plaster and investment materials and of connecting bars in
partial dentures as well as for fixations prior to furnace soldering.
1.3. Details of the supplier of the safety data sheet
Company name: FINO GmbH
Street: Mangelsfeld 18
Place: D-97708 Bad Bocklet
Telephone: +49-97 08-90 94 20 Telefax: +49-97 08-90 94 21
E-mail: [email protected] Internet: www.fino.com
Contact person: Joachim Mahlmeister Telephone: +49-97 08-90 94 20
E-mail: [email protected]
Responsible Department: This number can only be reached during our office hours, Monday to Friday from
8 a.m. to 5 p.m.
1.4. Emergency telephone +49-89-1 92 40
number: POISON CENTER München
24 hour(s) 7 day(s)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

GB CLP Regulation
Skin Irrit. 2; H315
Eye Irrit. 2; H319
STOT SE 3; H335

Full text of hazard statements: see SECTION 16.

2.2. Label elements
GB CLP Regulation
Hazard components for labelling
ethyl 2-cyanoacrylate
Signal word: Warning

Pictograms:

Hazard statements
H335 May cause respiratory irritation.

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H319 Causes serious eye irritation.

H315 Causes skin irritation.
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear Protective gloves /Eye protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Special labelling of certain mixtures
EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of
children.
Additional advice on labelling
The product is classified and labelled according to EC directives or corresponding national laws.
Classification according to Regulation (EC) No 1272/2008 [CLP]
2.3. Other hazards
No specific if used according to specifications.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
Cyanoacrylate adhesive
Sum formula: C6H7NO2
Molecular weight: 125,13

Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification (GB CLP Regulation)
7085-85-0 ethyl 2-cyanoacrylate >80 - <100 %
230-391-5 607-236-00-9
Skin Irrit. 2, Eye Irrit. 2, STOT SE 3; H315 H319 H335
123-31-9 1,4-dihydroxybenzene; hydroquinone; quinol >=0,01-<0,1
%
204-617-8 604-005-00-4
Carc. 2, Muta. 2, Acute Tox. 4, Eye Dam. 1, Skin Sens. 1, Aquatic Acute 1; H351 H341 H302
H318 H317 H400
Full text of H and EUH statements: see section 16.
Specific Conc. Limits, M-factors and ATE
CAS No EC No Chemical name Quantity
Specific Conc. Limits, M-factors and ATE
7085-85-0 230-391-5 ethyl 2-cyanoacrylate >80 - <100 %
oral: LD50 = > 5000 mg/kg STOT SE 3; H335: >= 10 - 100
123-31-9 204-617-8 1,4-dihydroxybenzene; hydroquinone; quinol >=0,01-<0,1
%
oral: LD50 = 302 mg/kg Aquatic Acute 1; H400: M=10

SECTION 4: First aid measures

4.1. Description of first aid measures

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FINOCOLL V 40 Instant Adhesive

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General information
Damage can be caused through mechanical influence of the product (eg. sticking).
After inhalation
Provide fresh air.
Seek medical attention if problems persist.
After contact with skin
Soak affected skin areas for a long time with warm soapsuds. Subsequently grease well and thoroughly for a
couple of times. Product residues disengage from skin after a couple of hours. Damage can be caused through
mechanical influence of the product (eg. sticking). Do not tear agglutinated skin parts apart. After wetting with
warm soap water they can be carefully separated with a blunt object e.g. a spoon. In case the lips are
accidentally glued together apply warm water to the lips. Make sure of the best possible wetting with saliva and
apply intraoral pressure. Peel or roll lips until they separate. Do not try to tear the lips apart by moving them in
an opposite direction.
After contact with eyes
If the eye is so agglutinated that it cannot be opened release eyelashes with warm water through the
application of a wet cotton ball. Cyan-acrylate cured at the eye protein, which causes lacrimation. This helps to
dissolve the glue again. Keep eye covered until the glue has completely separated, which will usually take 1 to
3 days.
Do not force eyes open. Seek medical treatment if solid particles of the cyan-acrylate are trapped under the lid
and thus cause injury through friction.
After ingestion
Make sure that the air way is free. The product polymerises immediately intraorally whereby it is almost
impossible to swallow it. Saliva will slowly separate the cured product from the mouth (several hours).
4.2. Most important symptoms and effects, both acute and delayed
After eye contact: Irritant, Conjunctival oedema (chemosis).
Following skin contact: erythema (redness), Ignition
Respiratory tract: Irritant, Cough, Dyspnoea
4.3. Indication of any immediate medical attention and special treatment needed
Special First Aid training necessary.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media
Foam, Extinguishing powder, Carbon dioxide (CO2), Water mist
Unsuitable extinguishing media
Not known.
5.2. Special hazards arising from the substance or mixture
In case of fire may be liberated: Carbon dioxide (CO2), Carbon monoxide
Use water spray jet to protect personnel and to cool endangered containers.
Carbon monoxide, Nitrogen, irritating organic vapors.
5.3. Advice for firefighters
In case of fire: Wear self-contained breathing apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General advice
Ventilate affected area.
Avoid contact with eyes and skin.
Ensure good ventilation / exhaustion at the workplace.
For non-emergency personnel
Emergency procedures

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FINOCOLL V 40 Instant Adhesive

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Remove persons to safety. Remove victim out of the danger area.

The danger areas must be delimited and identified using relevant warning and safety signs.
For emergency responders
Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Wear personal protection equipment (refer to section 8).
6.2. Environmental precautions
Do not allow to enter into surface water or drains.
Do not allow to enter into soil/subsoil.
6.3. Methods and material for containment and cleaning up
For containment
Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).
Following consultation with waste management company and after biological pre-treatment, landfill together
with household waste.
For cleaning up
Do not flush with water or watery cleaning agents
For cleaning, approved industrial vacuum cleaners are recommended, dust class:
Collect in closed and suitable containers for disposal.
Other information
Collect with a cloth or cellulose and dispose. polymerises with water Take up mechanically.
6.4. Reference to other sections
See protective measures under point 7 and 8.
Treat the recovered material as prescribed in the section on waste disposal.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Provide adequate ventilation as well as local exhaustion at critical locations. Handling larger quantities Odour
threshold: approx. 1-2 ppm
Advice on protection against fire and explosion
Usual measures for fire prevention.
Advice on general occupational hygiene
The usual precautionary measures are to be adhered to when handling chemicals.
When using do not eat, drink or smoke.
Keep away from food, drink and animal feedingstuffs.
Wash hands before breaks and after work.
Further information on handling
The product is intended for professional use.
Avoid contact with eyes and skin.
Wash hands before breaks and after work.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Store only in original container.
Hints on joint storage
Suitable container/equipment material: Polyethylene
Further information on storage conditions
storage temperature: 2 - 8°C ( 35.6 - 46.4°F )
7.3. Specific end use(s)
Cyanoacrylate containing adhesive.

SECTION 8: Exposure controls/personal protection

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FINOCOLL V 40 Instant Adhesive

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8.1. Control parameters

Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

7085-85-0 Ethyl cyanoacrylate 0.3 1.5 STEL (15 min) WEL

123-31-9 Hydroquinone - 0.5 TWA (8 h) WEL

DNEL/DMEL values

CAS No Substance
DNEL type Exposure route Effect Value
7085-85-0 ethyl 2-cyanoacrylate
Worker DNEL, long-term inhalation local 9,25 mg/m³
Worker DNEL, long-term inhalation systemic 9,25 mg/m³
Consumer DNEL, long-term inhalation local 9,25 mg/m³
Consumer DNEL, long-term inhalation systemic 9,25 mg/m³
123-31-9 1,4-dihydroxybenzene; hydroquinone; quinol
Worker DNEL, long-term inhalation systemic 7,0 mg/m³
Worker DNEL, long-term inhalation local 1,0 mg/m³
Consumer DNEL, long-term dermal systemic 64,0 mg/kg
bw/day
Consumer DNEL, long-term inhalation systemic 1,74 mg/m³
Consumer DNEL, long-term inhalation local 0,5 mg/m³
PNEC values
CAS No Substance
Environmental compartment Value
123-31-9 1,4-dihydroxybenzene; hydroquinone; quinol
Freshwater 0,0000114 mg/l
Marine water 0,0000114 mg/l
Freshwater sediment 0,00098 mg/kg
Marine sediment 0,00098 mg/kg
Secondary poisoning 0,71 mg/l
Soil 0,0000129 mg/kg

Additional advice on limit values

Long-term occupational exposure limit value : 9,25 mg/m³
8.2. Exposure controls

Appropriate engineering controls

Ensure good ventilation / exhaustion at the workplace.
Use appropriate respiratory protection. If technical exhaust or ventilation measures are not possible or
insufficient, respiratory protection must be worn. Filtering device with filter or ventilator filtering device of type: A
Individual protection measures, such as personal protective equipment
Eye/face protection
Eye glasses

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Hand protection
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves. EN ISO 374
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. NBR
(Nitrile rubber) EN ISO 374 Thickness of the glove material = 0,4 mm
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves. Selection of the glove material on consideration of
the penetration times, rates of diffusion and the degradation. Handling larger quantities PE (polyethylene)
Recommended material: NR (natural rubber, Natural latex) Use chemicals-resistant protective gloves made
from neoprene. Regularly change protective gloves.

not applicable PVC (polyvinyl chloride) Pull-over gloves of rubber.

Skin protection
Wear suitable protective clothing.
Respiratory protection
If local exhaust ventilation is not possible or not sufficient, the entire working area should be ventilated by
technical means.
type 5 particle-tight (method A) Combination filtering device

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state: Liquid
Colour: colourless / gel formation
Odour: stinging
Test method
Changes in the physical state
Melting point/freezing point: -25 °C
Boiling point or initial boiling point and > 149 °C
boiling range:
Softening point: not applicable
Flash point: 80-93,4 °C ASTM D 3278
Flammability
Solid/liquid: not applicable
Explosive properties
not explosive according to EU A.14
Lower explosion limits: --
Upper explosion limits: --
Auto-ignition temperature: Not applicable.
Self-ignition temperature
Solid: not determined
Decomposition temperature: not applicable
pH-Value: not determined
Viscosity / dynamic: not applicable
Viscosity / kinematic: not applicable
Solubility in other solvents
The polymer component is soluble in: Humidity
Acetone: miscible
Partition coefficient n-octanol/water: not applicable

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FINOCOLL V 40 Instant Adhesive

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Vapour pressure: < 0,3 hPa

(at 25 °C)
Vapour pressure: < 0,5 hPa
Density (at 23,9 °C): 1,10 g/cm³
Relative vapour density: not determined
9.2. Other information
Information with regard to physical hazard classes
Sustaining combustion: No data available
Other safety characteristics
Solvent content: not determined
Solid content: not determined
Evaporation rate: not determined
Further Information

SECTION 10: Stability and reactivity

10.1. Reactivity
Polymerisation Exothermic reaction with: Water, Amines, Alcohols, alkaline Avoid contact with the substance.
10.2. Chemical stability
The product is chemically stable under recommended conditions of storage, use and temperature.
10.3. Possibility of hazardous reactions
See section Reactivity.
10.4. Conditions to avoid
The product is stable under storage at normal ambient temperatures.
10.5. Incompatible materials
No specific if used according to specifications.
10.6. Hazardous decomposition products
No decomposition if used according to specifications.

SECTION 11: Toxicological information

11.1. Information on hazard classes as defined in GB CLP Regulation

Acute toxicity
Based on available data, the classification criteria are not met.
The product polymerises immediately intraorally whereby it is almost impossible to swallow it.
ATEmix calculated
ATE (oral) > 2000 mg/kg; ATE (dermal) > 2000 mg/kg; ATE (inhalation vapour) > 20 mg/l; ATE (inhalation
dust/mist) > 5 mg/l
CAS No Chemical name
Exposure route Dose Species Source Method
7085-85-0 ethyl 2-cyanoacrylate
oral LD50 > 5000 GESTIS
mg/kg
123-31-9 1,4-dihydroxybenzene; hydroquinone; quinol
oral LD50 302 Rat IUCLID
mg/kg

Irritation and corrosivity

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Skin corrosion/irritation: Causes skin irritation.

Serious eye damage/eye irritation: Causes serious eye irritation.
Agglutinates skin within seconds. Is classified as low-toxic. Due to the fact that the product cures on the skin
surface, allergic reactions are unlikely.
Sensitising effects
Based on available data, the classification criteria are not met.
May cause sensitization by inhalation.
Carcinogenic/mutagenic/toxic effects for reproduction
Germ cell mutagenicity: Based on available data, the classification criteria are not met.
Carcinogenicity: Based on available data, the classification criteria are not met.
Reproductive toxicity: Based on available data, the classification criteria are not met.
STOT-single exposure
May cause respiratory irritation. (ethyl 2-cyanoacrylate)
STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
Specific effects in experiment on an animal
No data available.
Additional information on tests
No data available.
Practical experience
No special references.
11.2. Information on other hazards
Other information
No special precautionary measures.

SECTION 12: Ecological information

12.1. Toxicity
Do not allow to enter into surface water or drains.
12.2. Persistence and degradability
none Evidence exists for biodegradation processes.
12.3. Bioaccumulative potential
No indication of bioaccumulation potential.
12.4. Mobility in soil
This information is not available.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to UK REACH.
12.6. Endocrine disrupting properties
This product does not contain a substance that has endocrine disrupting properties with respect to non-target
organisms as no components meets the criteria.
12.7. Other adverse effects
No specific information.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal recommendations
Following consultation with waste management company and after physico-chemical pre-treatment, landfill
together with household waste. Send to a hazardous waste incinerator facility under observation of official
regulations. Dispose of waste according to applicable legislation.

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FINOCOLL V 40 Instant Adhesive

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List of Wastes Code - residues/unused products

080409 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF
COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND
PRINTING INKS; wastes from MFSU of adhesives and sealants (including waterproofing products);
waste adhesives and sealants containing organic solvents or other hazardous substances;
hazardous waste
List of Wastes Code - used product
080409 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF
COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND
PRINTING INKS; wastes from MFSU of adhesives and sealants (including waterproofing products);
waste adhesives and sealants containing organic solvents or other hazardous substances;
hazardous waste
List of Wastes Code - contaminated packaging
150102 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND
PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately
collected municipal packaging waste); plastic packaging
Contaminated packaging
Dispose of waste according to applicable legislation.

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number or ID number: No dangerous good in sense of this transport regulation.
14.2. UN proper shipping name: No dangerous good in sense of this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
14.4. Packing group: No dangerous good in sense of this transport regulation.
Inland waterways transport (ADN)
14.1. UN number or ID number: No dangerous good in sense of this transport regulation.
14.2. UN proper shipping name: No dangerous good in sense of this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
14.4. Packing group: No dangerous good in sense of this transport regulation.
Marine transport (IMDG)
14.1. UN number or ID number: No dangerous good in sense of this transport regulation.
14.2. UN proper shipping name: No dangerous good in sense of this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
14.4. Packing group: No dangerous good in sense of this transport regulation.
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number or ID number: No dangerous good in sense of this transport regulation.
14.2. UN proper shipping name: No dangerous good in sense of this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
14.4. Packing group: No dangerous good in sense of this transport regulation.
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: No
14.6. Special precautions for user
not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
Restrictions on use (REACH, annex XVII):
Entry 3, Entry 75

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Directive 2004/42/EC on VOC in < 3,0 %

paints and varnishes:
Information according to Directive Not subject to 2012/18/EU (SEVESO III)
2012/18/EU (SEVESO III):
Additional information: 0
Additional information
The product is classified and labelled according to EC directives or corresponding national laws.
Classification according to Regulation (EC) No 1272/2008 [CLP]
National regulatory information
Water hazard class (D): 1 - slightly hazardous to water
Additional information
"Accident Prevention Regulation VBG 81 ""Processing of Adhesives"""
Betriebssicherheitsverordnung (BetrSichV) ---
15.2. Chemical safety assessment
Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Changes
This data sheet contains changes from the previous version in section(s): 1,7,8,9,10,11,12,15.
Abbreviations and acronyms
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
"IATA-DGR: Dangerous Goods Regulations by the ""International Air Transport Association"" (IATA)"
ICAO: International Civil Aviation Organization
"ICAO-TI: Technical Instructions by the ""International Civil Aviation Organization"" (ICAO)"
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
STOT SE 1
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
Skin Irrit. 2

Relevant H and EUH statements (number and full text)

H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H341 Suspected of causing genetic defects.
H351 Suspected of causing cancer.
H400 Very toxic to aquatic life.
EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of
children.
Further Information
The above information describes exclusively the safety requirements of the product and is based on our
present-day knowledge. The information is intended to give you advice about the safe handling of the product

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named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be
transferred to other products. In the case of mixing the product with other products or in the case of
processing, the information on this safety data sheet is not necessarily valid for the new made-up material.
The information is based on the present level of our knowledge. It does not, however, give assurance of
product properties and establishes no contract legal rights.
Identified uses
No Short title LCS SU PC PROC ERC AC TF Specification
1 Adhesives - - - - - - - 7085-85-0
LCS: Life cycle stages SU: Sectors of use
PC: Product categories PROC: Process categories
ERC: Environmental release categories AC: Article categories
TF: Technical functions

(The data for the relevant ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

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