ARMY PUBLIC SCHOOL NO 1

WORKSHEET NO 1
CLASS : XII
SUBJECT: CHEMISTRY

[Link] the correct option for the following questions

[Link] fraction of glycerine C3H5(OH)3 in solution containing 36 g of water and
46 g of glycerine is
(a) 0.46
(b) 0.40
(c) 0.20
(d) 0.36
[Link] of the following condition is not satisfied by an ideal solution?
(a) ΔHmixing = 0
(b) ΔVmixing = 0
(c) Raoult’s Law is obeyed
(d) Formation of an azeotropic mixture
[Link] boiling point of an azeotropic mixture of water and ethanol is less than
that of water and ethanol. The mixture shows
(a) no deviation from Raoult’s Law.
(b) positive deviation from Raoult’s Law.
(c) negative deviation from Raoult’s Law.
(d) that the solution is unsaturated
[Link] has the lowest boiling point at 1 atm pressure?
(a) 0.1 M KCl
(b) 0.1 M Urea
(c) 0.1 M CaCl2
(d) 0.1 M A1Cl3
5. Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The
concentration in moles/litre will be
(a) 0.33
(b) 0.666
(c) 0.3 × 10-2
(d) 3
[Link] add sodium chloride to water while boiling eggs. This is to
(a) decrease the boiling point.
(b) increase the boiling point.
(c) prevent the breaking of eggs.
(d) make eggs tasty.
[Link] relationship is not correct?
[Link] van’t Hoff factor (i) accounts for
(a) degree of solubilisation of solute.
(b) the extent of dissociation of solute.
(c) the extent of dissolution of solute.
(d) the degree of decomposition of solution.
[Link] molal elevation constant depends upon
(a) nature of solute.
(b) nature of the solvent.
(c) vapour pressure of the solution.
(d) enthalpy change.
[Link] molality of dilute solution is doubled, the value of molal depression
constant (Kf) will be
(a) halved
(b) tripled
(c) unchanged
(d) doubled
[Link] increase of temperature, which of these Changes
(a) Molality (b) Weight fraction of solute
(c) Fraction of solute present in water (d) Mole fraction
12. Which one of the following is not the example of gaseous solutions?
(A) Air
(B) Humidity
(C) Carbonated drink
(D) Dust in air
13. Value of Henry’s constant KH is
(A) Increases with increase in temperature.
(B) Decreases with increase in temperature
(C) Remains constant
(D) First increases then decreases.
[Link] the formation, breaking and strength of hydrogen bond, predict
which of the following mixtures
will show a positive deviation from Raoult’s law?
(A) Methanol and acetone.
(B) Chloroform and acetone.
(C) Nitric acid and water.
(D) Phenol and aniline.
[Link] two liquids A and B form minimum boiling azeotrope at some specific
composition, then.
(A) A–B interactions are stronger than those between A–A or B–B.
(B) vapour pressure of solution increases because more number of molecules
of liquids A and B can escape
from the solution.
(C) vapour pressure of solution decreases because less number of molecules of
only one of the liquids escape
from the solution.
(D) A–B interactions are weaker than those between A–A or B–B
16. People taking lot of salt experience puffiness or swelling of the body due
to
a. water retention in tissue cells and intercellular spaces because of osmosis
b. water loss from cells through skin tissue
c. capillary action of water through skin pores
d. excessive thrust and drinking more water
[Link] to Henry’s law the partial pressure of gas in vapour phase is
proportional to the mole fraction of the gas in the solution. For different gases
the correct statement about Henry’s constant is
(a)higher the value of KH at a given pressure higher is the solubility of the gas
(b).higher the value of KH at a given pressure lower is the solubility of the gas
(c) KH is not a function of nature of the gas
(d)KH value for all gasses is same at a given pressure
[Link] a solution of CHCl3 is mixed with a solution of acetone Δ___ is
(a) Positive
(b)Negative
(c) zero
(d) cannot be predicted
[Link] of the following mixture will form maximum boiling azetrope ?
(a) conc Nitric acid and water
(b)acetone and benzene
(c) Ethanol and water
(d)acetone and Carbondisulphide
20. Which of the following statements is not correct?
(a) Osmotic pressure is directly proportional to molar concentration.
(b) A hypertonic solution will be less concentrated with respect to other
solution.
(c) Isotonic solutions have same molar concentration.
(d) Osmotic pressure depends upon temperature
In the following questions an Assertion (A) is followed by a corresponding
Reason (R) use the following keys to choose the appropriate answer.
(a) Both A and R are true and R is the correct explanation of A.
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A is false but R is true.
1. A: Molality is preferred to molarity for expressing the concentration of
the solution.
R: Molality can be determined more easily than molarity.
2. A: Van't Hoff factor for benzoic acid is less than 1 in benzene.
R. Benzoic acid associates in benzene.
3. A:Isotonic solutions do not show any osmosis when placed side by side
R:Isotonic solutions have same solute concentration.
4. A: Ethyl alcohol and water for maximum boiling azeotrope.
R : Attractive forces in solution tend to increase.
5. A:In an ideal solution, AH mixing is zero.
R: A........ B interactions are the same as A........ A and B........ B
interactions.
6. A:Addition of ethyl alcohol lowers the freezing point of water.
R:Impurities always lower the freezing point of a solvent.
7. A: Out of various colligative properties, only osmotic pressure is used to
determine the molecular masses of polymers.
R : Polymer solutions donot possess a constant boiling point or freezing
point.
8. A: A solution which contains one gram mole of the solute dissolved per
litre of the solution is called molar solution.
R: A normal solution represents a solution in which the solute either
does not associate or dissociate.
9. A : Cooking time is reduced in pressure cooker.
R: Boiling point of water inside the pressure cooker is lowered.
10.A: Van't Hoff factor for benzoic acid in benzene solvent is less than 1.
R : Benzoic acid gets associated in benzene which is non-polar solvent.