Class – Dropper
Chemistry
Thermodynamics
DPP
1. Choose the correct option for free expansion of an 5. Five moles of an ideal gas at 1 bar and 298 K is
ideal gas under adiabatic condition from the expanded into vacuum to double the volume . The
following : work done is :
(a) q 0, T 0, w 0 (a) CV (T2 T1 ) (b) RT (V2 V1 )
(b) q 0, T 0, w 0 (c) RT 1nV2 / V1 (d) zero
(c) q 0, T 0, w 0 6. The true statement amongst the following is :
(d) q 0, T 0, w 0 (a) Both S and S are functions of temperature .
2. Which of the following is not correct ? (b) Both S and S are not functions of
temperature.
(a) G is zero for a reversible reaction
(c) S is not a function of temperature but S is
(b) G is negative for a spontaneous reaction not a function of temperature .
(c) G is positive for a spontaneous reaction (d) S is a function temperature but S is not a
(d) G is positive for a non- spontaneous reaction function of temperature .
3. Which of the following relations are correct ? 7. Among the following , the set of parameters that
represents path functions is :
(A) U q pV
(A) q W (B) q (C) w (D) H-TS
(B) G H T S
(a) (B) and (C) (b) (B) , (C) and (D)
q
(C) S rev (c) (A) and (D) (d) (A) , (B) and (C)
T
8. 5 moles of an ideal gas at 100 K are allowed to
(D) H U nRT undergo reversible compressions till its
Choose the most appropriate answer from the options temperature becomes 200 K. If
given below : CV 28 J K 1mol 1 , calculate U and PV for
(a) C and D only (b) B and C only this process . (R= 8.0 J K 1mol 1 )
(c) A and B only (d) B and D only (a) U 14kJ ; ( PV ) 18kJ
4. Which of the following relation is not correct ? (b) U 14kJ ; ( PV ) 0.8kJ
(a) H U PV (c) U 14kJ ; ( PV ) 4kJ
(b) U q W
(d) U 14kJ ; ( PV ) 8.0kJ
(c) S sys S surr 0
(d) G H T S
9. At 320 K, a gas A2 is 20 % dissociated to A (g) . 12. If 100 mole of H 2O2 decomposes at 1 bar and
The standard free energy change at 320 K and 1 300 K , the work done (kJ) by one mole of O2
atm in J mol 1 is approximately : (g) as it expands against 1 bar pressure is :
(R = 8.314 J K 1 mol 1 ; In 2 = 0.693 ; In 3 = 1.098) 2 H 2O2 ( I ) 2 H 2O( I ) O2 ( g )
(a) 1844 (b) 2068 ( R 83 JK 1 mol 1 )
(c) 4281 (d) 4763
(a) 124. 50 (b) 249.00
10. A gas undergoes change from state A to state B .
(c) 498.00 (d) 62.25
In this process , the heat absorbed and work done
by the gas is 5 J and 8 J , respectively . Now gas is 13. One mole of an ideal gas at 300 K in thermal
brought back to A by another process during contact with surroundings expands isothermally
which 3 J of heat is evolved . In this reverse from 1.0 L to 2.0 L against a constant pressure
process of B and A : of 3.0 atm . In this process , the change in entropy
(a) 10 J of the work will be done by the gas . of surroundings S surr in JK 1 is (1 L atm =
101.3 J)
(b) 6 J of the work will be done by the gas .
(a) 5.763 (b) 1.013
(c) 10 J of the work will be done by the
surroundings on gas . (c) -1.013 (d) -5.763
(d) 6 J of the work will be done by the
surroundings on gas .
14. The S of the following substances are :
11. The standard state Gibbs free energies of CH 4 ( g )186.2 JK 1mol 1 ; O2 ( g )205.2 JK 1mol 1
formation of C(graphite ) and C(diamond) at T=
298 K are Co2 ( g )213.6 JK 1mol 1 ; H 2O ( I )69.9. JK 1mol 1
f G 0 [C(graphite)] = 0 kJ mol 1 The entropy change S for the reaction
f G 0 [C(diamond)] = 2.9 kJ mol 1 CH 4 ( g ) 2O2 ( g ) Co2 ( g ) 2 H 2O ( I )is :
The standard state means that the pressure should be 1 (a) 312.5 JK 1mol 1
bar , and substance should be pure at a given
temperature . The conversion of graphite (b) 242.8 JK 1mol 1
[C(graphite)] to diamond [C(diamond)] reduces
its volume by 2 106 m 3 mol 1 . If C(graphite) (c) 108.1JK 1mol 1
is converted to C(diamond) isothermally at T=
298 K, the pressure at which C(graphite) is in (d) 37.6JK 1mol 1
equilibrium with C(diamond) , is
15. For the process H 2O ( I ) H 2O( g ) at T = 100
[Useful information : 1 J = 1 kg m 2 s 2 : Pa = C and 1 atmosphere pressure, the correct choice is
1 2
1 kg m s ;1bar 10 Pa] 5
(a) S system 0 and S surroundings 0
(a) 14501 bar (b) 58001 bar
(b) S system 0 and S surroundings 0
(c) 1450 bar (d) 29001 bar
(c) S system 0 and S surroundings 0
(d) S system 0 and S surroundings 0
16. Which of the following statements / relationship 20. When one mole of monoatomic ideal gas at T K
is not correct in thermodynamics changes ? undergoes adiabatic change under a constant
external pressure of 1 atm , volume changes form
(a) U 0 (isothermal reversible expansion of a 1 litre to 2 litre . The final temperature in Kelvin
gas would be
V2 T 2
(b) w nRT In (isothermal reversible (a) (b) T 0.0821
V1 2 2/3 3
expansion of an ideal gas )
2
V (c) T (d) T 0.0821
(c) w nRT In 2 (isothermal reversible 3
V1
21.The enthalpy of vapourization of liquid is 30
expansion of an ideal gas )
kJ mol 1 and entropy of vapourization is 75
(d) For a system of constant volume , heat
J mol 1 K . The boiling point of the liquid at 1
involved directly changes to internal energy .
atm is
17. For the process H 2O(1) (1 bar, 373), the correct
(a) 250 K (b) 400 K
set of thermodynamic parameters is
(c) 450 K (d) 600 K
(a) G 0, S ve
22. Two moles of an ideal gas is expanded
(b) G 0, S ve isothermally and reversibly from 1 litre to 10
litres at 300 K . The enthalpy change (in kJ ) for
(c) G ve, S 0 the process is
(d) G ve, S ve (a) 11.4 kJ (b) -11.4 kJ
18. The value of log10 K for a reaction A B is (c) 0 kJ (d) 4.8 kJ
23. One mole of a non-ideal gas undergoes a change
1
(Given : r H 298 K 54.07 kJ mol , r S 298 K = of state (2.0 atm, 3.0L , 95K)
10 JK 1mol 1 and R 8.314 JK 1mol 1 ; 4.0 atm,5.0 L, 245 K with a change in
2.303 8.314 298 5705 ) internal energy , U 30.0 L atm. The change in
enthalpy (H ) of the process in L atm is
(a) 5 (b) 10
(a) 40.0
(c) 95 (d) 100 (b) 42.3
19. A mono-atomic ideal gas undergoes a process in (c) 44.0
which the ratio of P to V at any instant is
constant and equals to (d) not defined, because pressure is not constant
1. What is the molar heat capacity of the gas
3R
(a) (b) 2 R
2
5R
(c) 0 (d)
2
