<br>
DPP-1
Conc. Term like % Composition, Molarity, Molality, Mole fraction etc.,Henry
Law
1 The effect of increase in the temperature of
an aqueous
.2 Molar concentration of a solution in water is :
solution of a substance is (1)Always equal to normality
(1) Decrease in its molality (2) More than molality of the solution
(2) Increase in its molality
(3) Equal to molality of the solution
(3) Increase in its mole fraction
(4) Decrease in its molarity (4) Less than the molality of the solution
<br>
Solution and Colligative Property
0.7 Mole fraction of
171gofcane sugar (CipH0,u) is dissolved litre
1
in
Q.3 CH(0H), 1n asolution of 36ea
of water. The molarity of the solution is water and 46 g of glycerine is:
M
(1)2.0 M (2) 1.0 (1) 0.46 (2)0.36 (3)0.20 (4)0.40
(3) 0.5 M (4) 0.25 M
Q.8 25 mL of3 M HCIl were added to 75 mL
N of0.05 MHOL
Q.4 With 63 gm of oxalic acid how many litres of The molarity of HCI in the resulting solution
10 i
solution can be prepared approximately
(1) 100 itre (2) 10 litre ()0.055 M (2) 0.35 M
(3) 1 litre (4) 1000 litre (3) 0.787M (4)3.05 M
Q.5 200ml ofa solution contains 5.85g dissolved sodium Q.9 Which of
the following gas will have most solubility in
chloride. The concentration of NaCI in the solution water?
will be (1) NH, (2) H, (3)0, (4) He
(Na=23; Cl=35.5)
(1) Imolar (2) 2 molar Q.10 The order of K, values of A, B and gases is C
(3) 0.5 molar (4) 0.25 molar Ku, >KH >KH,. Then, the correct order of their
Q.6 4.0 gm of NaOH are contained in one decilitre of solubility in a liquid at given temperature is
solution. Its molarity would be (1)A>C>B (2) B>A>C
(1)4 M
(2) 2 M (3) 1M (4) 1.5 M
(3) B>C>A (4) A>B>C
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DPP-2 J
Liguid-Liguid Soluion,ldeal and nonldeal
Vapour Pressure, Rdoult Law, Vapour Pressure of
Solution, Possitive and Negative deviation, Colligative Property
lower
Q.1 Among the following that forms an ideal solution:
Q.7 An azeotropic mixture of two liquids has b.p.
(1)water and methanol (2) acetone and ethanol than either of them when it:
Raoult's law
(3) benzene and toluene (4) water and HCI (1) shows a (+ve)deviation from
Raoult's law
(2)shows no deviation from
Q.2 Among the following, that does not form an ideal (3) shows (+ve) deviation from Henry's law
solution is: (4) shows (-ve) deviation from Henry's law
(1)CH, and CH,CH, (2) C,H,Cland CH,OH
having solid as solute
(3) CH,Cl and CH,Br (4) C,H,Brand C,HI Q.8 The vapour pressure ofa solution
:
and liquid as solvent is
solvent
(1) Directly proportional to mole fraction the
Which condition is not satisfied by an ideal solution? of
Q.3
(1) Hmixing=0
A
(2) A V mixing=0 (2) Inversely proportional to mole fraction of the
(3) ASmixing=0 (4) Obeyance ofRaoult's law solvent
(3) Directly proportional to mole fraction of the solute
A mixture of liquid showing positive deviation in (4) Inversely propartional to mole fraction of the solute
Q.4
Raoult's law is:
(1)(CH), CO+C,H,OH (2) (CH),CO+CHCI,
The relative lowering of the vapour pressure is equal
Q.9
(3) (C,H),0+CHCI, (4) (CH),C0+C,H,NH, to the ratio between the number of
(1) Solute moleules and solvent molecules
Q.5 Which of the following plots does not represent the (2) Solute molecules and the total molecules in the
behaviour of an ideal binary liquid solution : solution
(1) Plot of P, versus X, (mole fraction ofA in liquid
A A (3) Solvent molecules and the total molecules in the
phase) is linear solution
(2) Plot of P, versus is linear (4) Solvent molecules and the total number of ions of
(3) Plot of p,on Versus X, (or X) is linear the solute
(4) Plot of p.., versus X, is non lincar
A
Q.10 The vapour pressure lowering caused by the addition
Q.6 Azeotropic mixture are: of 100 g of sucrose(molecularmass =342) to 1000 g of
(1) Mixture of two solids water if the vapour pressure of pure water at
(2) Those which boil at different temperatures
25°C
1s
23.8 mn Hg
(3) Those which can be fractionally distilled (1) 1.25 nmn Hg (2) 0.125 mm Hg
(4) Constant boiling mixtures (3) 1.15 mm Hg (4) 00.12 1mm Hg
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DPP-3
(4T), Osmosis & Osmotic
Elevation in Boiling point (4T), Depression in freezing point
pressure : Type of solutions on the basis of Osmotic Pressure
Which inorganic precipitate acts as semipermcable Q.5 Iftheclevation in boiling point ofa solution of 10gof
Q.1
solute (molwt. = 100) in 100gofwater is DT,, then the
membrane?
cb ullioscopic constant of water is
(1) Calcium sulphate
AT,
(2) Barium oxalate (2) AT, (4) 10 AT,
(I) 100 AT, (3)
10
(3) Nickelphosphate
(4) Copper ferrocyanide
The temperature, at which the vapour pressure of
a
Q.6
liquid becomes cqual to the atmospheric pressure is
Q.2 Inthe case of osmosis, solvent molecules move from
(1) Higher vapour pressure to lower vapour pressure known as
(2) Higher concentration to lower concentration () Freezing point (2) Boiling point
(3)Lower vapour pressure to higher vapour pressure (3) Absolute temperature (4) None of these
(4) Higher osmotic pressure to lower osmotic pressure
Q.7 Osmotie pressure of a solution containing 0. 1l
mole of
Q.3 An aqucous solution freezes at
- solute pcr litre at 273K is (in atm)
0.186°C(K,=1.86°;K=0.512°). What is the clevation 0.1 x 0.1 x
(1) x0,08205 273 (2) 1x 8.314 x 273
in boiling point?
0.512
1
0.1 273
(1)0.186 (2)0.512 (3) (4) 0.0512 (3) x0.08205x 273 (4)
1.86 0.1 1 0.08205
Q.8 The molal elevation constant for water is 0.56° K kg
Q.4
A
solution containing 500 g ofa protein per litre is isotonic mol". Calculate the boiling of the solution made by
with a solutioncontaining 3.42 gof sucrose per litre. The dissolving 6.0 gm ofurea in 200 gm ofwater
molecular mass ofprotein is: () 100.28° C
(2) 100° C
(1)5 (2) 146 (3) 34200 (4) 50000) (3) 0.28°C (4) 200,28°C
CHEMISTRY 60
<br>
Solution and Colllgative Property
Osmotic pressure of 30% solution are mixed.
0.9 of glucose is 1.20
atm and that of 3.42% solution of canesugar Q.10 Equal volume of0.IM urca and 0.1 M glucose
is 2.5 atm. The mixturc will lhave:
The osmotic pressure of the mixture
containing cqual (1) Lower osmotic pressure
volumes of the two solutions will be
(2) Same osmotic pressure
(1)2.5 atn (2) 3.7 atm
(3) Highcr osmotic pressure
(3) 1.85 atm (4) 1.3 atm. (4) None of these
Abnormal Colligative Properties :
Vant-Hoff correction A_B, (aq.) XAy* + yB*
For electrolytic solutes the No. of particles would t=0C
be
different then the No. of particles actually added, due teq C(l-a) xCa yCa.
to dissociation or association
of solute. conccntration=C-C txCa+yCa
Net
The actual extent of dissociation/association can be =C[|+(x+y-1) a].
= C[l+(n-) a].
eXpressed as a correction factor known as vant Haff
factor (i). n=x+y
Vant-Hoff factor: = no.ofparticles in which l
molecules of clectrolyte
moles of particles in solution after dissociation /association
dissociates
= moles of solute dissolved j=
C[1+(n-1)a]
If solute gets associated or dissociated in solution i=1+(n-1) a
then experimcntable / observed / actual value for e.g. NaCl(100% ionised), BaCI, (100% ionised),
i-2.;
colligative property willbe different from theoretically i=3.; K,[Fe(CN),J (75% ionised), i
=4.
predicted value so it is also known as abnormal
colligative property. Case -l: Electrolyte associates
This abnormality can be calculated in terms of Vant Relation between degree of association B & i.
Hoff factor.
nA An.
exp/ observed/actual / abnormal value of colligative property t=0 C
j=
Theoretical value of colligative property
exp./observed no. of particles or concentration teq C(1-B)
Theoritical no. of particles or concentration
Theoretical mass of subs tan ce
exp erimental molar mass of the subs tan ce
i>l dissociation i<l association
Texp.
i=
Ttheor.
.. dimerisen=2;trimerise n =3; tetramerise n
=4.
Modified formula =iCRT
1=4,C, +i,C, +i,C,...) RT 1
e.g. CH,COOH 100% dimerise in benzene, i=
Case -I : Electrolyte dissociates 2
Relation betweeni& a (degree of dissociation): 1
Let the electrolyte be AxBy CH,COOH 100% dimerise in benzene, i= 2
DPP-4
Abnormal Colligative Properties, Molecular Mass, Vant-Hoff factor, Dissociation and
Association of Electrolyte
Q.1 Van't Hoff factor is : Q.2 The cxperimental molecular weight of an
(1) Less than once in case of dissociation clectrolyte willalways be less than its calculated value
because the value of vant Hoff factor, 'i' is
:
(2) More than one in case of association
(1) Less than 1
(3) Always less than one (2) Grcater than
1
(4) Less than one in case of association (3)One
(4) Zero
61 CHEMISTRY
<br>
Soution and Colligatve Property
Q3 The value of observed and calcutated molecular weight Q.7 Inwhich case van't Hoff factor is maximum
ofsilver nitrate are 92.64 and 70 respectively. The degree (1)KCI, 0% ioniscd (2) K,SO4 40% ionised
1
of dissociation of silver nitrate is
:
(3) FeCl,. 30% ioniscd (4) SnCl,. 20% ionised
(1) 60% (2) 83.5e (3)46.7% (4)60.239%
Q.8 Which has the cqual boiling point ?
Q.4 The freczing point of equimolal aqucous solution will (A)0.IM Na,sO,
be highest for : (C)0.IMCU,,0,(glucosc)
(1)CH,NHi,CI
(3) La(NO , (2)Ca(NO,),
(4)CU,0,Glucose)
(B)0.1 M MgCI,
(D)0.1MAl(NO),
(D(A) and(B) (2) (B) and (C)
Q.5 Among 0.IM solutions ofurca,Na, P0, and Al,(S0,),: (3)(C) and (D) (4) Nonc of these
(a) The vapour pressure and freczing point are tlhe
lowest tfor urca Q.9 Assuming cach salt to be 90% dissociatcd, which of
(b) The vapour pressure and freczing point are the the following will have highest boiling point?
highest tor urea ()Decimolar Al,(SO),
(c) The clevation in boiling point is the highest for (2)Decimolar BaC1,
Al(S0), (3) Decimolar Na,SO,
(d) The depression in freczing point is the highest for (4) A solution obtaincd by mixing cqual volumes of(B)
Al,(SO), and (C)
()Only a (2) b &e both
(3) b, c and d (4) a, b, c and d Q.10 The ratio of
thevalue of anycolligative property for KCI
solution to that for sugar solution is nearly ...
Q.6 The substance when dissolved in water would decrease time:
the vapour pressure of water to the greatest extent is : (1)1 (2)0.5
(1)0.1MKCI (2)0.1 Murea
(3)0.1 M BaCl, (3)2 (4) 2.5
(4) 0.I NaCI M1
EXAMPLE 27
SOLVED EXAMPLE
If6gmofCH, COOH is dissolved inbenzencto make
EXAMPLE I litre at 300 K. Osmotic pressure of solutionsis found
25 to be I.64 atm. Ifit is known that CH,COOH in benzene
Calculate osmoticpressure of a solutions having 0.1 forms a dimer.Caleulate degree ofassociation of acetic
M NaCl&0.2 M Na,SO, and 0.5 MHA.(Given:Weak
acid in benzene ?
acid is 20% dissociated at 300 K). Sol. CH,-C C-CH,
Sol. 'o-H-.0?
=0.1RTx 2 +0.2 RT×3+0.5 RT × 1.2
=0.0821 x 300(0.2 +0.6+0.6)
=34.482 atm.
1.64 =0.0821 x 300 x [
+-1]x
1
EXAMPLE
26
If0.04 M Na,SO, solutions at 300 K is found to be l.64=0.0821 x
300 [I-]0.1
isotonic with 0.05 M NaCl (100 % disscociation)
1.64 2-ß
solutions. Calculate degrec of disscociation of
sodium 00.821x 30 2
sulphate ? 1.64 2-9
Sol. i,C, RT = i,C, RT 2.46 2 4-6-3ß
i,C,= i,C, 3ß-2
2
0.04(1+2a)=0.05 x2 3
= 75%.
(2) When reaction is taking place:
a=0.75
CHEMISTRY
62
<br>
Solution and Colligative Property
ANSWER KEY
DPP-1
Q1(4) Q.2 (4) Q.3(3) Q.4 (2) Q.5 (3) Q.10 (3)
Q.6 (3) Q.7(3) Q.8 (3) Q.9(1)
Q.1(3) Q.2(2) Q.3(3) Q.4(1) Q.5(4)
DPP-2
Q.6(4)
J
Q.7(1) Q.8(1) Q.9(2) Q.10(2)
DPP-3
Q.1(4) Q.2(1) Q.3(4) Q.4(4) Q.5 (2) Q.6 (2) Q.9 (3) Q.10 (2)
Q.7() Q.8 (1)
DPP-4
Q1(4) Q.2(2) Q.3(2) Q.4 (4) Q.5(3) Q.10 (3)
Q.6(3) Q.7(3) Q.8(1) Q.9(1)
