ASPEROX Magic Blue
Safety Data Sheet
In accordance with the Regulation on Safety Data Sheets Regarding Hazardous Substances and Mixtures published in the
Official Journal numbered 29204 on December 13, 2014
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Product name : Asperox Magic Blue
Product group : Is detergent or cleaner
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended for general public
Main use category : Detergent
Use of the substance/mixture : Liquid cleaners
1.3. Details of the supplier of the safety data sheet
Manufacturer
Beyaz Kağıt ve Hijyenik Temizlik Ürünleri Sanayi ve Ticaret A.Ş.
Anavarza Cad. 3
Hacı Sabancı Organize Sanayii Bölgesi
P.O. Box 01350
Adana - TÜRKİYE
T +90 (322) 394 41 11 - F +90 (322) 394 40 12
[email protected] - www.beyazkagit.com.tr
1.4. Emergency telephone number
No additional information available
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Classification, Labelling and Packaging of Substances and Mixtures (SEA) Regulation published in the
Official Journal numbered 28848 on December 11, 2013.
Skin corrosion/irritation, Category 1 H314
Full text of H-statements: see section 16
Adverse physicochemical, human health and : Causes severe skin burns and eye damage. Causes serious eye damage.
environmental effects
2.2. Label elements
Classification according to Classification, Labelling and Packaging of Substances and Mixtures (SEA) Regulation published in the
Official Journal numbered 28848 on December 11, 2013. Extra labelling to displayExtra classification(s) to display
Hazard pictograms (SEA) :
GHS05
Signal word (SEA) : Danger
Hazardous ingredients : Methanesulphonic acid
Hazard statements (SEA) : H314 - Causes severe skin burns and eye damage.
Precautionary statements (SEA) : P264 - Wash hands, forearms and face with soap and water thoroughly after handling.
P280 - Wear protective gloves.
P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately dial 114 for the NATIONAL POISON CENTER or call a doctor.
2.3. Other hazards
Other hazards not contributing to the classification
No additional information available
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
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ASPEROX Magic Blue
Safety Data Sheet
In accordance with the Regulation on Safety Data Sheets Regarding Hazardous Substances and Mixtures published in the
Official Journal numbered 29204 on December 13, 2014
Name Product identifier % Classification according to
Classification, Labelling and
Packaging of Substances
and Mixtures (SEA)
Regulation published in the
Official Journal numbered
28848 on December 11,
2013.
methanesulphonic acid (CAS-No.) 75-75-2 <5 Skin Corr. 1B, H314
(EC-No.) 200-898-6
(EC Index-No.) 607-145-00-4
Chelating agent - <3 Met. Corr. 1, H290
Acute Tox. 4 (Oral), H302
Eye Dam. 1, H318
Citric Acid (CAS-No.) 5949-29-1 ≤1 Eye Irrit. 2, H319
Full text of H-statements: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Call a physician immediately.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Call a physician
immediately.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Call a physician immediately.
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting. Call a physician immediately.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after skin contact : Burns.
Symptoms/effects after eye contact : Serious damage to eyes.
Symptoms/effects after ingestion : Burns.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition products in case of : Toxic fumes may be released.
fire
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Ventilate spillage area. Avoid contact with skin and eyes. Do not breathe
dust/fume/gas/mist/vapours/spray.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Take up liquid spill into absorbent material.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 13.
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ASPEROX Magic Blue
Safety Data Sheet
In accordance with the Regulation on Safety Data Sheets Regarding Hazardous Substances and Mixtures published in the
Official Journal numbered 29204 on December 13, 2014
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Do not breathe
dust/fume/gas/mist/vapours/spray. Wear personal protective equipment.
Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store locked up. Store in a well-ventilated place. Keep cool.
7.3. Specific end use(s)
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
No additional information available
8.2. Exposure controls
Appropriate engineering controls : Ensure good ventilation of the work station.
Hand protection : Protective gloves
Eye protection : Safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment
Personal protective equipment symbol(s)
Environmental exposure controls : Avoid release to the environment.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Clear
Colour : Blue
Odour : perfumed
Odour threshold : No data available
pH : <1,5
Relative evaporation rate (butylacetate=1) : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : > 100 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Not flammable
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 1.03 g/ml
Solubility : Very soluble.
Partition coefficient n-octanol/water (Log Pow) : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
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ASPEROX Magic Blue
Safety Data Sheet
In accordance with the Regulation on Safety Data Sheets Regarding Hazardous Substances and Mixtures published in the
Official Journal numbered 29204 on December 13, 2014
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
None under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
Alkyl, C8-10, polyglucoside (68515-73-1)
LD50 oral > 2000 mg/kg bodyweight
LD50 dermal > 2000 mg/kg bodyweight
Phosphonic acid, (1-hydroxyethylidene)bis- (2809-21-4)
LD50 oral 1440 mg/kg bodyweight
LD50 dermal > 4764 mg/kg bodyweight
Skin corrosion/irritation : Causes severe skin burns.
pH: 1.5
Serious eye damage/irritation : Causes serious eye damage.
pH: 1.5
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
SECTION 12: Ecological information
12.1. Toxicity
Ecology - general : Before neutralisation, the product may represent a danger to aquatic organisms.
Hazardous to the aquatic environment, short- : Not classified
term (acute)
Hazardous to the aquatic environment, long- : Not classified
term (chronic)
Alkyl, C8-10, polyglucoside (68515-73-1)
LC50 fish 1 126 mg/l
EC50 other aquatic organisms 1 > 100 mg/l waterflea
EC50 other aquatic organisms 2 27.2 mg/l
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ASPEROX Magic Blue
Safety Data Sheet
In accordance with the Regulation on Safety Data Sheets Regarding Hazardous Substances and Mixtures published in the
Official Journal numbered 29204 on December 13, 2014
Phosphonic acid, (1-hydroxyethylidene)bis- (2809-21-4)
LC50 fish 1 195 mg/l
EC50 other aquatic organisms 1 527 mg/l waterflea
EC50 other aquatic organisms 2 7.2 mg/l
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
Bioaccumulative potential No additional information available
Phosphonic acid, (1-hydroxyethylidene)bis- (2809-21-4)
Partition coefficient n-octanol/water (Log -3.5
Pow)
12.4. Mobility in soil
Mobility in soil No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
Ozone : Not classified
Other adverse effects : No additional information available
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
ADR IMDG IATA ADN RID
14.1. UN number
3265 3265 Not applicable 3265 3265
14.2. UN proper shipping name
CORROSIVE LIQUID, CORROSIVE LIQUID, Not applicable CORROSIVE LIQUID, CORROSIVE LIQUID,
ACIDIC, ORGANIC, ACIDIC, ORGANIC, ACIDIC, ORGANIC, ACIDIC, ORGANIC,
N.O.S. N.O.S. N.O.S. N.O.S.
Transport document description
UN 3265 CORROSIVE UN 3265 CORROSIVE Not applicable UN 3265 CORROSIVE UN 3265 CORROSIVE
LIQUID, ACIDIC, LIQUID, ACIDIC, LIQUID, ACIDIC, LIQUID, ACIDIC,
ORGANIC, N.O.S., 8, I, ORGANIC, N.O.S., 8, I ORGANIC, N.O.S., 8, I ORGANIC, N.O.S., 8, I
(E)
14.3. Transport hazard class(es)
8 8 Not applicable 8 8
Not applicable
14.4. Packing group
I I Not applicable I I
14.5. Environmental hazards
Dangerous for the Dangerous for the Dangerous for the Dangerous for the Dangerous for the
environment : No environment : No environment : No environment : No environment : No
Marine pollutant : No
No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C3
Special provisions (ADR) : 274
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ASPEROX Magic Blue
Safety Data Sheet
In accordance with the Regulation on Safety Data Sheets Regarding Hazardous Substances and Mixtures published in the
Official Journal numbered 29204 on December 13, 2014
Limited quantities (ADR) : 0
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P001
Mixed packing provisions (ADR) : MP8, MP17
Portable tank and bulk container instructions : T14
(ADR)
Portable tank and bulk container special : TP2, TP27
provisions (ADR)
Tank code (ADR) : L10BH
Vehicle for tank carriage : AT
Transport category (ADR) : 1
Special provisions for carriage - Operation : S20
(ADR)
Hazard identification number (Kemler No.) : 88
Orange plates :
Tunnel restriction code (ADR) : E
- Transport by sea
Special provisions (IMDG) : 274
Packing instructions (IMDG) : P001
Tank instructions (IMDG) : T14
Tank special provisions (IMDG) : TP2, TP27
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : B
Stowage and handling (IMDG) : SW2
Properties and observations (IMDG) : Causes burns to skin, eyes and mucous membranes.
- Air transport
No data available
- Inland waterway transport
Classification code (ADN) : C3
Special provisions (ADN) : 274
Limited quantities (ADN) : 0
Excepted quantities (ADN) : E0
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C3
Special provisions (RID) : 274
Limited quantities (RID) : 0
Excepted quantities (RID) : E0
Packing instructions (RID) : P001
Mixed packing provisions (RID) : MP8, MP17
Portable tank and bulk container instructions : T14
(RID)
Portable tank and bulk container special : TP2, TP27
provisions (RID)
Tank codes for RID tanks (RID) : L10BH
Special provisions for RID tanks (RID) : TU38, TE22
Transport category (RID) : 1
Hazard identification number (RID) : 88
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
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ASPEROX Magic Blue
Safety Data Sheet
In accordance with the Regulation on Safety Data Sheets Regarding Hazardous Substances and Mixtures published in the
Official Journal numbered 29204 on December 13, 2014
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. National regulations
This product doesn’t contain any substances that is controlled or prohibited for use according to the Regulation on Ozone Depleting Substances
published in the Official Journal numbered 30031 on April 7, 2017.
SECTION 16: Other information
Full text of H-statements
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Met. Corr. 1 Corrosive to metals, Category 1
Skin Corr. 1B Skin corrosion/irritation, Category 1B
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
Safety Data Sheet author's
Name : Simay ÖNEN
Certificate number : GBF 01.25.02
Certificate valid until : 22/12/2021
Contact information :
[email protected]SDS Turkey
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied,
regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we
do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS
was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. It is also not legally binding and does not
create a contractual relationship.
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