TUBALL MATRIX 201

Safety Data Sheet

according to Regulation (EC) No. 453/2010
Date of issue: 08/04/2016 Revision date: 25/04/2016 Version: 2.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Trade name : TUBALL MATRIX 201
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Use of the substance/mixture : The plasticizer is to be used for thermoset compounds to add electrical conductivity

1.2.2. Uses advised against

No additional information available
1.3. Details of the supplier of the safety data sheet
Europe: Asia: USA:
OCSiAl Europe S.a.r.l. OCSiAl Asia Pacific Co., Ltd. OCSiAl LLC
L-3364, Leudelange, Office 208, Pilot Plant Bldg., 500 S Front St., Suite 860
1, rue de la Poudrerie, Incheon Technopark Columbus, OH 43215, USA
Grand Duchy of Luxembourg 12 Gaetbeol-ro, Yeonsu-gu, Incheon T +1 415 906 5271
T +352 27 99 03 73 406-840 Republic of Korea usa@[Link]
europe@[Link] T +82 32 260 0407
asiapacific@[Link]
1.4. Emergency telephone number
Europe: Asia: USA:
+352 27 99 03 73 +82 32 260 0407 +1 415 906 5271
09.00-17.00 GMT 01.00-09.00 GMT 09.00-17.00 GMT

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Show CLP information + DPD classification in section 2.1
Skin Sens. 1 H317
Eye Irrit. 2 H319
Toxic to aquatic life with long lasting effects. H411

Full text of H-phrases: see section 16

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Xi; R36
R43
N; R51/53
Full text of R-phrases: see section 16

Adverse physicochemical, human health and environmental effects

No additional information available
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :

GHS07 GHS09
Signal word (CLP) : Warning
Hazard statements (CLP) : H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H411 - Toxic to aquatic life with long lasting effects
Precautionary statements (CLP) : P264 - Wash with plenty of water and soap thoroughly after handling
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P272 - Contaminated work clothing should not be allowed out of the workplace
P273 - Avoid release to the environment

P333+P313 If skin irritation or rash occurs: Get medical advice/attention

25/04/2016 EN (English) 1/7
TUBALL MATRIX 201
Safety Data Sheet
according to Regulation (EC) No. 453/2010

P337+P313 If eye irritation persists: Get medical advice/attention

P363 - Wash contaminated clothing before reuse

P302+P352 IF ON SKIN: Wash with plenty of soap and water

P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing

P501 - Dispose of contents/container to hazardous or special waste collection point

2.3. Other hazards
No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification according to
Directive 67/548/EEC
Fatty acid glycidyl ester (CAS No) 26761-45-5 90 N; R51/53, R43
Carbon Nanotube Single-walled below (CAS No) 308068-56-6 10 Xi; R36/37
2 nm (diameter), > 1 micron (length) (REACH-no) Not yet available

Name Product identifier % Classification according to

Regulation (EC) No.
1272/2008 [CLP]
Fatty acid glycidyl ester (CAS No) 26761-45-5 90 Skin Sens. 1, H317
Toxic to aquatic life with long
lasting effects, H411
Carbon Nanotube Single-walled below (CAS No) 308068-56-6 10 Eye Irrit. 2, H319
2 nm (diameter), > 1 micron (length) (REACH-no) Not yet available STOT SE 3, H335

Full text of R- and H-phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures after inhalation : Keep patient calm, remove to fresh air, seek medical attention.
First-aid measures after skin contact : Wash thoroughly with soap and water.
First-aid measures after eye contact : Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult
an eye specialist.
First-aid measures after ingestion : Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
mouth with water. Consult a physician.
4.2. Most important symptoms and effects, both acute and delayed
No additional information available
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Water spray, dry powder, foam
Unsuitable extinguishing media : Water jet
5.2. Special hazards arising from the substance or mixture
Fire hazard : None known
Explosion hazard : None known
Hazardous decomposition products in case of : Carbon dioxide. Carbon monoxide.
fire
5.3. Advice for firefighters
Protective equipment for firefighters : Wear self-contained breathing apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Wear suitable protective clothing.
Emergency procedures : Ensure adequate ventilation.

25/04/2016 EN (English) 2/7

TUBALL MATRIX 201
Safety Data Sheet
according to Regulation (EC) No. 453/2010

6.1.2. For emergency responders

Protective equipment : Wear suitable protective clothing.
Emergency procedures : Provide adequate ventilation.
6.2. Environmental precautions
Do not allow to enter into surface water or drains. Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Dispose of absorbed material in accordance
with regulations.
6.4. Reference to other sections
No additional information available

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Additional hazards when processed : None known.
Precautions for safe handling : Do not get in eyes or on skin. Use personal protective equipment (see section 8).
Hygiene measures : Do not eat, drink or smoke when using this product.
7.2. Conditions for safe storage, including any incompatibilities
Storage duration : 6 monthes.
Storage conditions : Keep container tightly closed at temperature from 5 to 60 °C.
7.3. Specific end use(s)
No additional information available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
No occupational exposure limits known
8.2. Exposure controls
Personal protective equipment : Gloves. Glasses. Protective clothing.
Materials for protective clothing : Wear suitable protective clothing. Wear chemical resistant protective clothing (EN 14605) and
protective shoes (S1P or S3)
Hand protection : Wear suitable gloves tested to EN 374.
Skin and body protection : Safety glasses with side-shields.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance : Viscous paste
Colour : Black
Odour : Slight
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : <-60 °C
Freezing point : No data available
Boiling point : 278 °С
Flash point : 1260С
Auto-ignition temperature : > 280 °С
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 2290 Pa 150 °С
11690 Pa 200 °С
Relative vapour density at 25 °C : No data available
Relative density : No data available
Solubility in water : 90 mg/l 20 °С
Log Pow : No data available

25/04/2016 EN (English) 3/7

TUBALL MATRIX 201
Safety Data Sheet
according to Regulation (EC) No. 453/2010

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
None known
10.4. Conditions to avoid
Exposure to sunlight.
10.5. Incompatible materials
Amines, mercaptans and Lewis acids
10.6. Hazardous decomposition products
Polymerises exothermically with amines, mercaptans and Lewis acids.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity :
Fatty acid glycidyl ester (CAS No) 26761-45-5
LD50 oral rat >2000 mg/kg
LD50 derm. >2000 mg/kg
LD50 inhalat. >5 mg/kg
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : May causes eye irritation
Respiratory or skin sensitisation : May causes skin sensitisation
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified

SECTION 12: Ecological information

12.1. Toxicity
Fatty acid glycidyl ester (CAS No) 26761-45-5
Toxicity to fish 1< LC/ЕС/IC 50 <=10 mg/l
Aquatic invertebrates: EC50 (48 h) 1< LC/ЕС/IC 50 <=10 mg/
Aquatic plants: EC50 (72 h) 1< LC/ЕС/IC 50 <=10 mg/l
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
Component
Carbon Nanotube Single-walled below PBT: not yet assessed
2 nm (diam.), >1 micro m (length) vPvB: not yet assessed
Carbon Nanotubes (308068-56-6)

25/04/2016 EN (English) 4/7

TUBALL MATRIX 201
Safety Data Sheet
according to Regulation (EC) No. 453/2010

12.6. Other adverse effects

No additional information available

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Regional legislation (waste) : Dispose of this material and its container to hazardous or special waste collection point.
Waste treatment methods : Disposal through controlled incineration or authorised waste dump.
Sewage disposal recommendations : Prevent entry to sewers and public waters.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3082
UN-No. (IMDG) : 3082
UN-No.(IATA) : 3082
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Proper Shipping Name (IMDG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Proper Shipping Name (IATA) : Environmentally hazardous substance, liquid, n.o.s.
Transport document description (ADR) : UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III, (E)
Transport document description (ADR) (IMDG) : UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III, MARINE
POLLUTANT/ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : 9
Danger labels (ADR) : 9

IMDG
Transport hazard class(es) (IMDG) : 9
Danger labels (IMDG) : 9

IATA
Transport hazard class(es) (IATA) : 9
Hazard labels (IATA) : 9

14.4. Packing group

Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available

25/04/2016 EN (English) 5/7

TUBALL MATRIX 201
Safety Data Sheet
according to Regulation (EC) No. 453/2010

14.6. Special precautions for user

14.6.1. Overland transport
Classification code (ADR) : M6
Special provisions (ADR) : 274, 335, 601
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Special packing provisions (ADR) : PP1
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container instructions : T4
(ADR)
Portable tank and bulk container special : TP1, TP29
provisions (ADR)
Tank code (ADR) : LGBV
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Packages : V12
(ADR)
Special provisions for carriage - Loading, : CV13
unloading and handling (ADR)
Hazard identification number (Kemler No.) : 90
Orange plates :

Tunnel restriction code (ADR) : E

EAC code : •3Z

14.6.2. Transport by sea

Special provisions (IMDG) : 274, 335
Limited quantities (IMDG) : 5L
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P001, LP01
Special packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP2, TP29
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-F
Stowage category (IMDG) : A
MFAG-No : 171

14.6.3. Air transport

PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y964
PCA limited quantity max net quantity (IATA) : 30kgG
PCA packing instructions (IATA) : 964
PCA max net quantity (IATA) : 450L
CAO packing instructions (IATA) : 964
CAO max net quantity (IATA) : 450L
Special provisions (IATA) : A97, A158
ERG code (IATA) : 9L

14.6.4. Inland waterway transport

Not subject to ADN : No

14.6.5. Rail transport

Carriage prohibited (RID) : No
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
25/04/2016 EN (English) 6/7
TUBALL MATRIX 201
Safety Data Sheet
according to Regulation (EC) No. 453/2010

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no substances with Annex XVII restrictions
POWERED BY TUBALL EPX is not on the REACH Candidate List
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulations
No additional information available
15.2. Chemical safety assessment
CSA has not been established

SECTION 16: Other information

Other information : This information is based on our current knowledge and is intended to describe the product for
the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product. It is the user's responsibility to
take the mentioned precautionary measures and to ensure that this information is complete and
sufficient for the use of this product.
Full text of R-, H- and EUH-phrases:
N Dangerous for the environment
Xi Irritant
R36 Irritating to eyes
R43 Irritating skin
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
H317 Causes skin sensitisation
H319 Causes serious eye irritation
H411 Toxic to aquatic life with long lasting effects

SDS EU (REACH Annex II)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product

25/04/2016 EN (English) 7/7