1.
Low concentration of oxygen in the blood and tissues of people living at high altitudes is due
to : (A) Low temperature (B) Low atmospheric pressure (C) High atmospheric pressure (D)
High temperature
2. Calculate the boiling point of the solution when 4 g of MgSO4 (M = 120 g mol 1 ) was
dissolved in 100 g of water, assuming MgSO4 undergoes complete ionization. (Kb for water
= 0·52 K kg mol 1
3. Assertion (A) : When NaCl is added in water, elevation in boiling point is observed. Reason
(R) : Elevation in boiling point is a colligative property.
4. (a) (i) At the same temperature, CO2 gas is more soluble in water than O2 gas. Which one of
them will have higher value of KH and why ? (ii) How does the size of blood cells change
when placed in an aqueous solution containing more than 0·9% (mass/volume) sodium
chloride ? (iii) 1 molal aqueous solution of an electrolyte A2B3 is 60% ionized. Calculate the
boiling point of the solution. (Given : Kb for H2O = 0·52 K kg mol 1 )
5. (i) The vapour pressures of A and B at 25ºC are 75 mm Hg and 25 mm Hg, respectively. If A
and B are mixed such that the mole fraction of A in the mixture is 0·4, then calculate the
mole fraction of B in vapour phase. (ii) Define colligative property. Which colligative property
is preferred for the molar mass determination of macromolecules ?
6. The system that forms maximum boiling azeotrope is : (A) CS2 and acetone (B) Benzene and
toluene (C) Ethanol and acetone (D) Chloroform and acetone
7. Assertion (A) : mixH for an ideal solution is not equal to zero. Reason (R) : A B interactions in
an ideal solution are same as between A A and B B interactions.
8. Why are equimolar solutions of sodium chloride and glucose not isotonic ?
9. A 6% solution of glucose (molar mass = 180 g mol 1 ) is isotonic with 25% solution of an
unknown organic substance. Calculate the molecular weight of the unknown organic
substance.
10. The vapour pressure of a solvent at 283 K is 100 mm Hg. Calculate the vapour pressure of a
dilute solution containing 1 mole of a strong electrolyte AB in 50 moles of the solvent at 283
K (assuming complete dissociation of solute AB).
11. The relative lowering of vapour pressure of an aqueous solution containing non-volatile
solute is 0·0225. The mole fraction of the non-volatile solute is : (A) 0·80 (B) 0·725 (C) 0·15
(D) 0·0225
12. A 4% solution of urea (molar mass = 60 g mol 1 ) is isotonic with 52% solution of an unknown
organic substance. Calculate the molecular weight of the unknown organic substance.
13. On mixing 10 mL of acetone with 50 mL of chloroform, the total volume of the solution will
be : (A) < 60 mL (B) > 60 mL (C) = 60 mL (D) = 100 mL
14. A 1% mass = 342 g mol 1 (A) 34·2 g mol 1 (B) 57 g mol 1 (C) 114 g mol 1 (D) 3·42 g mol 1
15. (a) Define molal depression constant. How is it related to enthalpy of fusion ? OR (b) What
type of deviation is shown by ethanol and acetone mixture ? Give reason. What type of
azeotropic mixture is formed by that deviation ?
16. A solution is prepared by dissolving 5 g of a non-volatile solute in 200 g of water. It has a
vapour pressure of 31·84 mm Hg at 300 K. Calculate the molar mass of the solute. 3(Vapour
pressure of pure water at 300 K = 32 mm Hg)
17. A 1percent solution of solute X is isotonic with a 6 percent solution of sucrose (molarmass =
342 g mol 1 ). The molar mass of solute (A) 34·2 g mol 1 (B) 57 g mol 1 (C) 114 g mol 1 (D)
3·42 g mol 1
18. Assertion (A) : mixH and mixV are zero for non-ideal solutions. Reason (R) : Solute-solvent
interactions are not same as pure solute-solute and pure solvent-solvent interactions in non-
ideal solutions.
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