Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH), amended by

2015/830/EU

CARECLEAN HD DESCALEX L
Version number: GHS 10.0 revision: 29.11.2018
Replaces version of: 18.08.2017 (GHS 9)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name Careclean HD Descalex L
Registration number (REACH) not relevant (mixture)
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses cleaning agent
1.3 Details of the supplier of the safety data sheet
Marine Care B.V.
Oude Maasweg 35, Port number 4005
3197 KJ Rotterdam-Botlek
Netherlands

Telephone: +(31) 10 29 50 342

e-mail: [email protected]
Website: www.marinecare.nl
1.4 Emergency telephone number
Emergency information service +(31) 10 29 50 342
For USA/CANADA: INFOTRAC 1-800-535-5053.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)
Section Hazard class Cat- Hazard class and Hazard
egory category state-
ment
2.16 substance or mixture corrosive to metals Cat. 1 (Met. Corr. 1) H290

3.2 skin corrosion/irritation Cat. 1B (Skin Corr. 1B) H314

3.3 serious eye damage/eye irritation Cat. 1 (Eye Dam. 1) H318

3.8R specific target organ toxicity - single exposure (respiratory tract ir- Cat. 3 (STOT SE 3) H335
ritation)

Remarks
For full text of H-phrases: see SECTION 16.

The most important adverse physicochemical, human health and environmental effects
Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epidermis and
into the dermis.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008 (CLP)
Signal word Danger
Pictograms
GHS05, GHS07

Hazard statements
H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.

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MARINECARE 152 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
2015/830/EU

CARECLEAN HD DESCALEX L
Version number: GHS 10.0 revision: 29.11.2018
Replaces version of: 18.08.2017 (GHS 9)

Precautionary statements
Precautionary statements - prevention
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statements - response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P390 Absorb spillage to prevent material damage.
Precautionary statements - storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Precautionary statements - disposal
P501 Dispose of contents/container to industrial combustion plant.
Hazardous ingredients for labelling: Hydrochloric Acid 30 %
2.3 Other hazards
There is no additional information.

SECTION 3: Composition/information on ingredients

3.1 Substances
not relevant (mixture)
3.2 Mixtures
Description of the mixture
Name of substance Identifier wt% Classification acc. to Pictograms
1272/2008/EC
Hydrochloric Acid 30 % CAS No 25 – < 50 Met. Corr. 1 / H290
7647-01-0 Skin Corr. 1B / H314
Eye Dam. 1 / H318
EC No STOT SE 3 / H335
231-595-7

For full text of abbreviations: see SECTION 16.

SECTION 4: First aid measures

4.1 Description of first aid measures
General notes
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm,
still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms per-
sist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give any-
thing by mouth.
Following inhalation
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case of
respiratory tract irritation, consult a physician. Provide fresh air.
Following skin contact
Wash with plenty of soap and water.
Following eye contact
Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water
for at least 10 minutes, holding the eyelids apart.

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MARINECARE 152 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
2015/830/EU

CARECLEAN HD DESCALEX L
Version number: GHS 10.0 revision: 29.11.2018
Replaces version of: 18.08.2017 (GHS 9)

Following ingestion
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms and effects are not known to date.
4.3 Indication of any immediate medical attention and special treatment needed
none

SECTION 5: Firefighting measures

5.1 Extinguishing media
5.1.1 Suitable extinguishing media
water spray, fire extinguishing powder, carbon dioxide (CO2)
Unsuitable extinguishing media
water jet
5.2 Special hazards arising from the substance or mixture
Substance or mixture corrosive to metals.
Hazardous combustion products
nitrogen oxides (NOx)
5.3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surround-
ings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water
separately. Fight fire with normal precautions from a reasonable distance.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Remove persons to safety.
For emergency responders
Wear breathing apparatus if exposed to vapours/dust/spray/gases.
6.2 Environmental precautions
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it.
6.3 Methods and material for containment and cleaning up
Advices on how to contain a spill
Covering of drains.
Advices on how to clean up a spill
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage (sawdust, kieselgur (diatomite), sand, uni-
versal binder).
Appropriate containment techniques
Use of adsorbent materials.
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area.
6.4 Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible
materials: see section 10. Disposal considerations: see section 13.

Netherlands Page 3 / 11
MARINECARE 152 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
2015/830/EU

CARECLEAN HD DESCALEX L
Version number: GHS 10.0 revision: 29.11.2018
Replaces version of: 18.08.2017 (GHS 9)

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Recommendations
• Measures to prevent fire as well as aerosol and dust generation
Use local and general ventilation. Use only in well-ventilated areas.
• Handling of incompatible substances or mixtures
Do not mix with alkali.
• Keep away from
caustic solutions
Advice on general occupational hygiene
Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protect-
ive equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place
chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feed-
ingstuffs.
7.2 Conditions for safe storage, including any incompatibilities
Managing of associated risks
• Corrosive conditions
Store in corrosive resistant container with a resistant inner liner.
Incompatible substances or mixtures
Observe hints for combined storage.
• Control of effects
• Protect against external exposure, such as
frost
Consideration of other advice
• Packaging compatibilities
Only packagings which are approved (e.g. acc. to ADR) may be used.
7.3 Specific end use(s)
See section 16 for a general overview.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
National limit values
Occupational exposure limit values (Workplace Exposure Limits)
Cou Name of agent CAS No Nota Iden TWA TWA STEL STEL Ceil- Ceil- Sour
ntry tion tifier [ppm] [mg/ [ppm] [mg/ ing-C ing-C ce
m³] m³] [ppm] [mg/
m³]
EU hydrogen chloride 7647-01- IOEL 5 8 10 15 2009/
0 V 161/
EU

NL hydrochloric acid 7647-01- GW 8 15 SC-

0 SZW

Notation
Ceiling-C Ceiling value is a limit value above which exposure should not occur.
STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period
(unless otherwise specified).
TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8 hours time-
weighted average (unless otherwise specified).

Netherlands Page 4 / 11
MARINECARE 152 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
2015/830/EU

CARECLEAN HD DESCALEX L
Version number: GHS 10.0 revision: 29.11.2018
Replaces version of: 18.08.2017 (GHS 9)

Relevant DNELs/DMELs/PNECs and other threshold levels

• relevant DNELs of components of the mixture
Name of sub- CAS End- Threshold Protection goal, Used in Exposure time
stance No point level route of expos-
ure
Hydrochloric Acid 30 7647-01- DNEL 8 mg/m³ human, inhalatory worker (in- chronic - local effects
% 0 dustry)

Hydrochloric Acid 30 7647-01- DNEL 15 mg/m³ human, inhalatory worker (in- acute - local effects
% 0 dustry)

• relevant PNECs of components of the mixture

Name of sub- CAS End- Threshold Organism Environ- Exposure time
stance No point level mental com-
partment
Hydrochloric Acid 30 7647-01- PNEC 36 µg/l aquatic organisms freshwater short-term (single in-
% 0 stance)

Hydrochloric Acid 30 7647-01- PNEC 36 µg/l aquatic organisms marine water short-term (single in-
% 0 stance)

Hydrochloric Acid 30 7647-01- PNEC 45 µg/l aquatic organisms water intermittent release
% 0

Hydrochloric Acid 30 7647-01- PNEC 36 µg/l aquatic organisms sewage treat- short-term (single in-
% 0 ment plant stance)
(STP)

8.2 Exposure controls

Appropriate engineering controls
General ventilation.
Individual protection measures (personal protective equipment)
Eye/face protection
Wear eye/face protection.
Skin protection
• hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check
leak-tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them before
taking off and air them well. For special purposes, it is recommended to check the resistance to chemicals of
the protective gloves mentioned above together with the supplier of these gloves.
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recom-
mended. Wash hands thoroughly after handling.
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground
water.

Netherlands Page 5 / 11
MARINECARE 152 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
2015/830/EU

CARECLEAN HD DESCALEX L
Version number: GHS 10.0 revision: 29.11.2018
Replaces version of: 18.08.2017 (GHS 9)

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state liquid
Colour light brown
Odour characteristic
Other physical and chemical parameters
pH (value) 1 (acid)
Melting point/freezing point -47 °C
Initial boiling point and boiling range 90 °C
Flash point not determined
Evaporation rate not determined
Flammability (solid, gas) not relevant (fluid)
Explosive limits not determined
Vapour pressure 2 kPa at 25 °C
Density 1,15 g/cm³
Solubility(ies) not determined
Partition coefficient
n-octanol/water (log KOW) This information is not available.
Auto-ignition temperature not determined
Viscosity not determined
Explosive properties none
Oxidising properties none
9.2 Other information There is no additional information.

SECTION 10: Stability and reactivity

10.1 Reactivity
Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials". substance or mix-
ture corrosive to metals
10.2 Chemical stability
See below "Conditions to avoid".
10.3 Possibility of hazardous reactions
No known hazardous reactions.
10.4 Conditions to avoid
There are no specific conditions known which have to be avoided.
Physical stresses which might result in a hazardous situation and have to be avoided
strong shocks
10.5 Incompatible materials
oxidisers
Release of flammable materials with
light metals (due to the release of hydrogen in an acid/alkaline medium)
10.6 Hazardous decomposition products
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and
heating are not known. Hazardous combustion products: see section 5.

Netherlands Page 6 / 11
MARINECARE 152 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
2015/830/EU

CARECLEAN HD DESCALEX L
Version number: GHS 10.0 revision: 29.11.2018
Replaces version of: 18.08.2017 (GHS 9)

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Classification procedure
The method for classification of the mixture is based on ingredients of the mixture (additivity formula)

Classification according to GHS (1272/2008/EC, CLP)

Acute toxicity
Shall not be classified as acutely toxic.
Skin corrosion/irritation
Causes severe skin burns and eye damage.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Summary of evaluation of the CMR properties
Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant.
Specific target organ toxicity (STOT)
• Specific target organ toxicity - single exposure
May cause respiratory irritation.
• Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

SECTION 12: Ecological information

12.1 Toxicity
Shall not be classified as hazardous to the aquatic environment.
Biodegradation
The relevant substances of the mixture are readily biodegradable.
12.2 Persistence and degradability
Data are not available.
12.3 Bioaccumulative potential
Data are not available.
12.4 Mobility in soil
Data are not available.
12.5 Results of PBT and vPvB assessment
Data are not available.
12.6 Other adverse effects
Data are not available.

Netherlands Page 7 / 11
MARINECARE 152 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
2015/830/EU

CARECLEAN HD DESCALEX L
Version number: GHS 10.0 revision: 29.11.2018
Replaces version of: 18.08.2017 (GHS 9)

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used. Completely
emptied packages can be recycled. Handle contaminated packages in the same way as the substance itself.
Remarks
Please consider the relevant national or regional provisions. Waste shall be separated into the categories that
can be handled separately by the local or national waste management facilities.

SECTION 14: Transport information

14.1 UN number 1789
14.2 UN proper shipping name HYDROCHLORIC ACID
14.3 Transport hazard class(es)
Class 8 (corrosive substances)
14.4 Packing group II (substance presenting medium danger)
14.5 Environmental hazards none (non-environmentally hazardous acc. to the dangerous
goods regulations)
14.6 Special precautions for user
Provisions for dangerous goods (ADR) should be complied within the premises.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
The cargo is not intended to be carried in bulk.
• Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN)
UN number 1789
Proper shipping name HYDROCHLORIC ACID
Particulars in the transport document UN1789, HYDROCHLORIC ACID, (contains: Hydro-
chloric Acid 30 %), 8, II, (E)
Class 8
Classification code C1
Packing group II
Danger label(s) 8

Special provisions (SP) 520

Excepted quantities (EQ) E2
Limited quantities (LQ) 1L
Transport category (TC) 2
Tunnel restriction code (TRC) E
Hazard identification No 80

Netherlands Page 8 / 11
MARINECARE 152 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
2015/830/EU

CARECLEAN HD DESCALEX L
Version number: GHS 10.0 revision: 29.11.2018
Replaces version of: 18.08.2017 (GHS 9)

• International Maritime Dangerous Goods Code (IMDG)

UN number 1789
Proper shipping name HYDROCHLORIC ACID
Particulars in the shipper's declaration UN1789, HYDROCHLORIC ACID, (contains: Hydro-
chloric Acid 30 %), 8, II
Class 8
Packing group II
Danger label(s) 8

Special provisions (SP) -

Excepted quantities (EQ) E2
Limited quantities (LQ) 1L
EmS F-A, S-B
Stowage category C
Segregation group 1 - Acids
• International Civil Aviation Organization (ICAO-IATA/DGR)
UN number 1789
Proper shipping name Hydrochloric acid
Particulars in the shipper's declaration UN1789, Hydrochloric acid, (contains: Hydrochloric
Acid 30 %), 8, II
Class 8
Packing group II
Danger label(s) 8

Special provisions (SP) A3

Excepted quantities (EQ) E2
Limited quantities (LQ) 0,5 L

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
• Limitation of emissions of volatile organic compounds due to the use of organic solvents in
certain paints and varnishes and vehicle refinishing products (2004/42/EC, Deco-Paint Directive)
VOC content 0%
• Directive on industrial emissions (VOCs, 2010/75/EU)
VOC content 0%

Netherlands Page 9 / 11
MARINECARE 152 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
2015/830/EU

CARECLEAN HD DESCALEX L
Version number: GHS 10.0 revision: 29.11.2018
Replaces version of: 18.08.2017 (GHS 9)

National regulations (Netherlands)

• Algemene Beoordelingsmethodiek, ABM 2016 (general assessment methodology, GAM)
Water hazard and decontamination effort
11 slightly harmful to aquatic organisms
Abatement effort: B (Abatement effort B: approach as for relatively hazardous substances)
15.2 Chemical Safety Assessment
Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Abbreviations and acronyms
Abbr. Descriptions of used abbreviations

2009/161/EU Comission Directive establishing a third list of indicative occupational exposure limit values in implementation of
Council Directive 98/24/EC and amending Commission Directive 2000/39/EC

ADN Accord européen relatif au transport international des marchandises dangereuses par voies de navigation
intérieures (European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways)

ADR Accord européen relatif au transport international des marchandises dangereuses par route (European Agreement
concerning the International Carriage of Dangerous Goods by Road)

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

Ceiling-C Ceiling value

CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

CMR Carcinogenic, Mutagenic or toxic for Reproduction

DGR Dangerous Goods Regulations (see IATA/DGR)

DMEL Derived Minimal Effect Level

DNEL Derived No-Effect Level

EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identifier of
substances commercially available within the EU (European Union)

EINECS European Inventory of Existing Commercial Chemical Substances

ELINCS European List of Notified Chemical Substances

EmS Emergency Schedule

Eye Dam. Seriously damaging to the eye

Eye Irrit. Irritant to the eye

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations

IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

IMDG International Maritime Dangerous Goods Code

IOELV Indicative occupational exposure limit value

MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant")

Met. Corr. Substance or mixture corrosive to metals

NLP No-Longer Polymer

PBT Persistent, Bioaccumulative and Toxic

Netherlands Page 10 / 11
MARINECARE 152 SDS-01
 Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by
2015/830/EU

CARECLEAN HD DESCALEX L
Version number: GHS 10.0 revision: 29.11.2018
Replaces version of: 18.08.2017 (GHS 9)

Abbr. Descriptions of used abbreviations

PNEC Predicted No-Effect Concentration

ppm Parts per million

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regulations concern-
ing the International carriage of Dangerous goods by Rail)

SC-SZW Staatscourant: Regeling van de Minister van Sociale Zaken en Werkgelegenheid tot wijziging van de Arbeidsom-
standighedenregeling

Skin Corr. Corrosive to skin

Skin Irrit. Irritant to skin

STEL Short-term exposure limit

STOT SE Specific target organ toxicity - single exposure

TWA Time-weighted average

VOC Volatile Organic Compounds

vPvB Very Persistent and very Bioaccumulative

Key literature references and sources for data

- Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
- Regulation (EC) No. 1272/2008 (CLP, EU GHS)

Classification procedure
Physical and chemical properties: The classification is based on tested mixture.
Health hazards/environmental hazards: The method for classification of the mixture is based on ingredients of
the mixture (additivity formula).

List of relevant phrases (code and full text as stated in chapter 2 and 3)
Code Text

H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

H335 May cause respiratory irritation.

Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and is solely
intended for this product.

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MARINECARE 152 SDS-01